Citation: Ningfang Li, Qingfang Lin, Yemin Han, Zeyu Du, Yan Xu. The chain-shaped coordination polymers based on the bowl-like Ln₁₈Ni_24(23.5) clusters exhibiting favorable low-field magnetocaloric effect[J]. Chinese Chemical Letters, ;2021, 32(12): 3803-3806. doi: 10.1016/j.cclet.2021.04.042 shu

The chain-shaped coordination polymers based on the bowl-like Ln₁₈Ni_24(23.5) clusters exhibiting favorable low-field magnetocaloric effect

Ningfang Li ^a ,
Qingfang Lin ^b ,
Yemin Han ^a ,
Zeyu Du ^a ,
Yan Xu ^{a, *,}

a.
College of Chemical Engineering, State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 210093, China
b.
Department of Chemistry, Bengbu Medical College, Bengbu 233030, China

yanxu@njtech.edu.cn

Received Date: 22 March 2021
Revised Date: 20 April 2021
Accepted Date: 22 April 2021
Available Online: 1 May 2021

Figures(6)

The design of assembling high-nuclearity transition-lanthanide (3d-4f) clusters along with excellent magnetocaloric effect (MCE) is one of the most prominent fields but is extremely challenging. Herein, two heterometallic metal coordination polymers are constructed via the "carbonate-template" method, formulated as {[Gd₁₈Ni₂₄(IDA)₂₂(CO₃)₇(μ₃-OH)₃₂(μ₂-OH)₃(H₂O)₅Cl]·Cl₈·(H₂O)₁₄}_n and {[Eu₁₈Ni_23.5(IDA)₂₂(CO₃)₇(μ₃-OH)₃₂(H₂O)₅(IN)(CH₃COO)₂(NH₂CH₂COO)Cl]·Cl₆·(H₂O)₁₇}_n [abbreviated as 1-(Gd₁₈Ni₂₄)_n and 2-(Eu₁₈Ni_23.5)_n respectively; H₂IDA = iminodiacetic acid; HIN = isonicotinic acid]. Concerning the structures, compounds 1-(Gd₁₈Ni₂₄)_n and 2-(Eu₁₈Ni_23.5)_n both feature the one-dimensional (1D) chain-like structure which is rarely reported in high-nuclearity metal complexes. Meanwhile, the large presences of Gd³⁺ ions in compound 1-(Gd₁₈Ni₂₄)_n are conducive to the fantastic MCE, and the value of -∆S_m is 35.30 J kg^-1 K^-1 at 3.0 K and ∆H = 7.0 T. And more significantly, compound 1-(Gd₁₈Ni₂₄)_n shows the large low-field magnetic entropy change (-∆S_m = 20.95 J kg^-1 K^-1 at 2.0 K and ∆H = 2.0 T) among the published 3d-4f mixed metal clusters.
- 3d-4f,
- Anionic templets,
- Chain-like structure,
- High-nuclearity clusters,
- Magnetic refrigeration,
- Mixed-ligand method
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The chain-shaped coordination polymers based on the bowl-like Ln18Ni24(23.5) clusters exhibiting favorable low-field magnetocaloric effect

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通讯作者: 陈斌, bchen63@163.com

The chain-shaped coordination polymers based on the bowl-like Ln₁₈Ni_24(23.5) clusters exhibiting favorable low-field magnetocaloric effect