Citation: Haizhen Ding, Jiahui Xu, Lei Jiang, Chen Dong, Qi Meng, Sajid ur Rehman, Junfeng Wang, Zhishen Ge, Vladimir Yu. Osipov, Hong Bi. Fluorine-defects induced solid-state red emission of carbon dots with an excellent thermosensitivity[J]. Chinese Chemical Letters, ;2021, 32(11): 3646-3651. doi: 10.1016/j.cclet.2021.04.033 shu

Fluorine-defects induced solid-state red emission of carbon dots with an excellent thermosensitivity

Haizhen Ding ^{a, 1} ,
Jiahui Xu ^{a, 1} ,
Lei Jiang ^a ,
Chen Dong ^a ,
Qi Meng ^a ,
Sajid ur Rehman ^b ,
Junfeng Wang ^b ,
Zhishen Ge ^c ,
Vladimir Yu. Osipov ^{a, d} ,
Hong Bi ^{a, *,}

a.
School of Chemistry and Chemical Engineering, Anhui Key Laboratory of Modern Biomanufacturing, Anhui University, Hefei 230601, China
b.
High Magnetic Field Laboratory, Hefei Institutes of Physical Science, Chinese Academy of Sciences, Hefei 230031, China
c.
CAS Key Laboratory of Soft Matter Chemistry, Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei 230601, China
d.
Ioffe Institute, Russian Academy of Sciences, St. Petersburg 194021, Russian Federation

bihong@ahu.edu.cn

Received Date: 4 March 2021
Revised Date: 11 April 2021
Accepted Date: 18 April 2021
Available Online: 26 April 2021

Figures(6)

Up to date, solid-state carbon dots (CDs) with bright red fluorescence have scarcely achieved due to aggregation-caused quenching (ACQ) effect and extremely low quantum yield in deep-red to near infrared region. Here, we report a novel fluorine-defects induced solid-state red fluorescence (λ_em = 676 nm, the absolute fluorescence quantum yields is 4.17%) in fluorine, nitrogen and sulfur co-doped CDs (F, N, S-CDs), which is the first report of such a long wavelength emission of solid-state CDs. As a control, CDs without fluorine-doping (N, S-CDs) show no fluorescence in solid-state, and the fluorescence quantum yield/emission wavelength of N, S-CDs in solution-state are also lower/shorter than that of F, N, S-CDs, which is mainly due to the F-induced defect traps on the surface/edge of F, N, S-CDs. Moreover, the solid-state F, N, S-CDs exhibit an interesting temperature-sensitive behavior in the range of 80-420 K, with the maximum fluorescence intensity at 120 K, unveiling its potential as the temperature-dependent fluorescent sensor and the solid-state light-emitting device adapted to multiple temperatures.
- Carbon dots,
- Fluorine defects,
- Solid-state fluorescence,
- Thermosensitivity,
- Red emission
1. [1]
  Y.P. Sun, B. Zhou, Y. Lin, et al., J. Am. Chem. Soc. 128 (2006) 7756-7757 doi: 10.1021/ja062677d
2. [2]
  H. Li, Z. Kang, Y. Liu, et al., J. Mater. Chem. 22 (2012) 24230-24253 doi: 10.1039/c2jm34690g
3. [3]
  S.Y. Lim, W. Shen, Z. Gao, Chem. Soc. Rev. 44 (2015) 362-381 doi: 10.1039/C4CS00269E
4. [4]
  X.W. Hua, Y.W. Bao, F.G. Wu, ACS Appl. Mater. Interfaces 10 (2018) 16924-16924. doi: 10.1021/acsami.8b05530
5. [5]
  A. Xu, G. Wang, Y. Li, et al., Small 16 (2020) 2004621 doi: 10.1002/smll.202004621
6. [6]
  B. Wang, J. Li, Z. Tang, et al., Sci. Bull. 64 (2019) 1285-1292 doi: 10.1016/j.scib.2019.07.021
7. [7]
  W. Li, Y. Liu, B. Wang, et al., Chin. Chem. Lett. 30 (2019) 2323-2327 doi: 10.1016/j.cclet.2019.06.040
8. [8]
  S.T. Yang, L. Cao, P.G. Luo, et al., J. Am. Chem. Soc. 131 (2009) 11308-11309 doi: 10.1021/ja904843x
9. [9]
  X. Teng, C. Ma, C. Ge, et al., J. Mater. Chem. B 2 (2014) 4631-4639 doi: 10.1039/c4tb00368c
10. [10]
  Y. Hong, J.W.Y. Lam, B.Z. Tang, Chem. Commun. (2009) 4332-4353 doi: 10.1039/b904665h
11. [11]
  Y. Hong, J.W.Y. Lam, B.Z. Tang, Chem. Soc. Rev. 40 (2011) 5361-5388 doi: 10.1039/c1cs15113d
12. [12]
  Y. Chen, M. Zheng, Y. Xiao, et al., Adv. Mater. 28 (2016) 312-318 doi: 10.1002/adma.201503380
13. [13]
  J. Shao, S. Zhu, H. Liu, et al., Adv. Sci. 4 (2017) 1700395 doi: 10.1002/advs.201700395
14. [14]
  T. Feng, Q. Zeng, S. Lu, et al., ACS Photonics 5 (2018) 502-510 doi: 10.1021/acsphotonics.7b01010
15. [15]
  H. Yang, Y. Liu, Z. Guo, et al., Nat. Commun. 10 (2019) 1789 doi: 10.1038/s41467-019-09830-6
16. [16]
  Y. Liu, W. Duan, W. Song, et al. ACS Appl. Mater. Interfaces 9 (2017) 12663-12672 doi: 10.1021/acsami.6b15746
17. [17]
  J. Zhou, H. Zhou, J. Tang, et al., Microchimica Acta 184 (2017) 343-368 doi: 10.1007/s00604-016-2043-9
18. [18]
  K. Jiang, Y. Wang, X. Gao, et al., Angew. Chem. Int. Ed. 57 (2018) 6216-6220 doi: 10.1002/anie.201802441
19. [19]
  T. Lei, X. Xia, J.Y. Wang, et al., J. Am. Chem. Soc. 136 (2014) 2135-2141 doi: 10.1021/ja412533d
20. [20]
  L.E. Zimmer, C. Sparr, R. Gilmour, Angew. Chem. Int. Ed. 50 (2011) 11860-11871 doi: 10.1002/anie.201102027
21. [21]
  D. O'Hagan, Chem. Soc. Rev. 37 (2008) 308-319 doi: 10.1039/B711844A
22. [22]
  H. Sun, H. Ji, E. Ju, et al., Chem. Eur. J. 21 (2015) 3791-3797 doi: 10.1002/chem.201406345
23. [23]
  W. Yang, H. Zhang, J. Lai, et al., Carbon 128 (2018) 78-85 doi: 10.1016/j.carbon.2017.11.069
24. [24]
  G. Zuo, A. Xie, J. Li, et al., J. Phys. Chem. C 121 (2017) 26558-26565 doi: 10.1021/acs.jpcc.7b10179
25. [25]
  L. Jiang, H. Ding, M. Xu, et al., Small 16 (2020) 2000680 doi: 10.1002/smll.202000680
26. [26]
  J. Zhou, J. Lian, L. Hou, et al., Nat. Commun. 6 (2015) 8503 doi: 10.1038/ncomms9503
27. [27]
  M. Lan, S. Zhao, Z. Zhang, et al., Nano Res. 10 (2017) 3113-3123 doi: 10.1007/s12274-017-1528-0
28. [28]
  S. Lu, L. Sui, J. Liu, et al., Adv. Mater. 29 (2017) 1603443 doi: 10.1002/adma.201603443
29. [29]
  H. Song, X. Liu, B. Wang, et al., Sci. Bull. 64 (2019) 1788-1794 doi: 10.1016/j.scib.2019.10.006
30. [30]
  F. Yuan, Z. Wang, X. Li, et al., Adv. Mater. 29 (2017) 1604436 doi: 10.1002/adma.201604436
31. [31]
  K. Bogdanov, A. Fedorov, V. Osipov, et al., Carbon 73 (2014) 78-86 doi: 10.1016/j.carbon.2014.02.041
32. [32]
  C. Hu, S. Sedghi, A. Silvestre-Albero, et al., Carbon 85 (2015) 147-158 doi: 10.1016/j.carbon.2014.12.098
33. [33]
  M.J. Krysmann, A. Kelarakis, P. Dallas, et al., J. Am. Chem. Soc. 134 (2012) 747-750 doi: 10.1021/ja204661r
34. [34]
  Y. Li, Y. Zhao, H. Cheng, et al., J. Am. Chem. Soc. 134 (2012) 15-18 doi: 10.1021/ja206030c
35. [35]
  H. Ding, S.B. Yu, J.S. Wei, et al., ACS Nano 10 (2016) 484-491 doi: 10.1021/acsnano.5b05406
36. [36]
  Q. Xu, P. Pu, J. Zhao, et al., J. Mater. Chem. A3 (2015) 542-546 doi: 10.1039/C4TA05483K
37. [37]
  P. Long, Y. Feng, C. Cao, et al., Adv. Funct. Mater. 28 (2018) 1800791 doi: 10.1002/adfm.201800791
38. [38]
  J. Viger-Gravel, C.E. Avalos, D.J. Kubicki, et al., Angew. Chem. Int. Ed. 58 (2019) 7249-7253 doi: 10.1002/anie.201814416
39. [39]
  M. Murakami, K. Matsumoto, R. Hagiwara, et al., Carbon 138 (2018) 179-187 doi: 10.1016/j.carbon.2018.06.004
40. [40]
  W. Feng, P. Long, Y. Feng, et al., Adv. Sci. 3 (2016) 1500413 doi: 10.1002/advs.201500413
41. [41]
  Y. Dong, H. Pang, H.B. Yang, et al., Angew. Chem. Int. Ed. 52 (2013) 7800-7804 doi: 10.1002/anie.201301114
42. [42]
  Z. Song, F. Quan, Y. Xu, et al., Carbon 104 (2016) 169-178 doi: 10.1016/j.carbon.2016.04.003
43. [43]
  K. Jiang, S. Sun, L. Zhang, et al., Angew. Chem. Int. Ed. 54 (2015) 5360-5363 doi: 10.1002/anie.201501193
44. [44]
  C. Hu, C. Yu, M. Li, et al., Small 10 (2014) 4926-4933 doi: 10.1002/smll.201401328
45. [45]
  C. Struzzi, M. Scardamaglia, N. Reckinger, et al., Nano Res. 10 (2017) 3151-3163 doi: 10.1007/s12274-017-1532-4
46. [46]
  R. Hu, L. Li, W.J. Jin, Carbon 111 (2017) 133-141 doi: 10.1016/j.carbon.2016.09.038
47. [47]
  X. Miao, X. Yan, D. Qu, et al., ACS Appl. Mater. Interfaces 9 (2017) 18549-18556 doi: 10.1021/acsami.7b04514
48. [48]
  C. Scialabba, A. Sciortino, F. Messina, et al., ACS Appl. Mater. Interfaces 11 (2019) 19854-19866 doi: 10.1021/acsami.9b04925
49. [49]
  H. Kwon, A.O. Furmanchuk, M. Kim, et al., J. Am. Chem. Soc. 138 (2016) 6878-6885 doi: 10.1021/jacs.6b03618
50. [50]
  D. Li, P. Jing, L. Sun, et al., Adv. Mater. 30 (2018) 1705913 doi: 10.1002/adma.201705913
51. [51]
  D. Li, C. Liang, E.V. Ushakova, et al., Small 15 (2019) 1905050 doi: 10.1002/smll.201905050
52. [52]
  F. Rigodanza, L. Đorđević, F. Arcudi, et al., Angew. Chem. Int. Ed. 57 (2018) 5062-5067 doi: 10.1002/anie.201801707
53. [53]
  A. Bayat, E. Saievar-Iranizad, J. Lumin. 192 (2017) 180-183 doi: 10.1016/j.jlumin.2017.06.055
1. [1]
  Rui Cheng , Xin Huang , Tingting Zhang , Jiazhuang Guo , Jian Yu , Su Chen . Solid superacid catalysts promote high-performance carbon dots with narrow-band fluorescence emission for luminescence solar concentrators. Chinese Chemical Letters, 2024, 35(8): 109278-. doi: 10.1016/j.cclet.2023.109278
2. [2]
  Boran Cheng , Lei Cao , Chen Li , Fang-Yi Huo , Qian-Fang Meng , Ganglin Tong , Xuan Wu , Lin-Lin Bu , Lang Rao , Shubin Wang . Fluorine-doped carbon quantum dots with deep-red emission for hypochlorite determination and cancer cell imaging. Chinese Chemical Letters, 2024, 35(6): 108969-. doi: 10.1016/j.cclet.2023.108969
3. [3]
  Meiling Xu , Xinyang Li , Pengyuan Liu , Junjun Liu , Xiao Han , Guodong Chai , Shuangling Zhong , Bai Yang , Liying Cui . A novel and visible ratiometric fluorescence determination of carbaryl based on red emissive carbon dots by a solvent-free method. Chinese Chemical Letters, 2025, 36(2): 109860-. doi: 10.1016/j.cclet.2024.109860
4. [4]
  Liwen Wang , Boyang Wang , Siyu Lu , Shubo Lv , Xiaoli Qu . High quantum yield yellow emission carbon dots for the construction of blue light blocking films. Chinese Chemical Letters, 2025, 36(2): 110497-. doi: 10.1016/j.cclet.2024.110497
5. [5]
  Chaoqun Ma , Yuebo Wang , Ning Han , Rongzhen Zhang , Hui Liu , Xiaofeng Sun , Lingbao Xing . Carbon dot-based artificial light-harvesting systems with sequential energy transfer and white light emission for photocatalysis. Chinese Chemical Letters, 2024, 35(4): 108632-. doi: 10.1016/j.cclet.2023.108632
6. [6]
  Shuangying Li , Qingxiang Zhou , Zhi Li , Menghua Liu , Yanhui Li . Sensitive measurement of silver ions in environmental water samples integrating magnetic ion-imprinted solid phase extraction and carbon dot fluorescent sensor. Chinese Chemical Letters, 2024, 35(5): 108693-. doi: 10.1016/j.cclet.2023.108693
7. [7]
  Qiang Fu , Shouhong Sun , Kangzhi Lu , Ning Li , Zhanhua Dong . Boron-doped carbon dots: Doping strategies, performance effects, and applications. Chinese Chemical Letters, 2024, 35(7): 109136-. doi: 10.1016/j.cclet.2023.109136
8. [8]
  Chenghao Liu , Xiaofeng Lin , Jing Liao , Min Yang , Min Jiang , Yue Huang , Zhizhi Du , Lina Chen , Sanjun Fan , Qitong Huang . Carbon dots-based dopamine sensors: Recent advances and challenges. Chinese Chemical Letters, 2024, 35(12): 109598-. doi: 10.1016/j.cclet.2024.109598
9. [9]
  Quan Zhang , Shunjie Xing , Jingqian Han , Li Feng , Jianchun Li , Zhaosheng Qian , Jin Zhou . Organic pollutant sensing for human health based on carbon dots. Chinese Chemical Letters, 2025, 36(1): 110117-. doi: 10.1016/j.cclet.2024.110117
10. [10]
  Yuan Liu , Boyang Wang , Yaxin Li , Weidong Li , Siyu Lu . Understanding excitonic behavior and electroluminescence light emitting diode application of carbon dots. Chinese Chemical Letters, 2025, 36(2): 110426-. doi: 10.1016/j.cclet.2024.110426
11. [11]
  Jianye Kang , Xinyu Yang , Xuhao Yang , Jiahui Sun , Yuhang Liu , Shutao Wang , Wenlong Song . Carbon dots-enhanced pH-responsive lubricating hydrogel based on reversible dynamic covalent bondings. Chinese Chemical Letters, 2024, 35(5): 109297-. doi: 10.1016/j.cclet.2023.109297
12. [12]
  Rui Cheng , Tingting Zhang , Xin Huang , Jian Yu . Facile synthesis of high-brightness green-emitting carbon dots with narrow bandwidth towards backlight display. Chinese Chemical Letters, 2024, 35(5): 108763-. doi: 10.1016/j.cclet.2023.108763
13. [13]
  Wu-Jian Long , Yang Yu , Chuang He . A novel and promising engineering application of carbon dots: Enhancing the chloride binding performance of cement. Chinese Chemical Letters, 2024, 35(6): 108943-. doi: 10.1016/j.cclet.2023.108943
14. [14]
  Qiang Li , Jiangbo Fan , Hongkai Mu , Lin Chen , Yongzhen Yang , Shiping Yu . Nucleus-targeting orange-emissive carbon dots delivery adriamycin for enhanced anti-liver cancer therapy. Chinese Chemical Letters, 2024, 35(6): 108947-. doi: 10.1016/j.cclet.2023.108947
15. [15]
  Xiaoning Li , Quanyu Shi , Meng Li , Ningxin Song , Yumeng Xiao , Huining Xiao , Tony D. James , Lei Feng . Functionalization of cellulose carbon dots with different elements (N, B and S) for mercury ion detection and anti-counterfeit applications. Chinese Chemical Letters, 2024, 35(7): 109021-. doi: 10.1016/j.cclet.2023.109021
16. [16]
  Hao Cai , Xiaoyan Wu , Lei Jiang , Feng Yu , Yuxiang Yang , Yan Li , Xian Zhang , Jian Liu , Zijian Li , Hong Bi . Lysosome-targeted carbon dots with a light-controlled nitric oxide releasing property for enhanced photodynamic therapy. Chinese Chemical Letters, 2024, 35(4): 108946-. doi: 10.1016/j.cclet.2023.108946
17. [17]
  Xiuzheng Deng , Changhai Liu , Xiaotong Yan , Jingshan Fan , Qian Liang , Zhongyu Li . Carbon dots anchored NiAl-LDH@In₂O₃ hierarchical nanotubes for promoting selective CO₂ photoreduction into CH₄. Chinese Chemical Letters, 2024, 35(6): 108942-. doi: 10.1016/j.cclet.2023.108942
18. [18]
  Binyang Qin , Mengqi Wang , Shimei Wu , Yining Li , Chilin Liu , Yufei Zhang , Haosen Fan . Carbon dots confined nanosheets assembled NiCo₂S₄@CDs cross-stacked architecture for enhanced sodium ion storage. Chinese Chemical Letters, 2024, 35(7): 108921-. doi: 10.1016/j.cclet.2023.108921
19. [19]
  Xiuzheng Deng , Yi Ke , Jiawen Ding , Yingtang Zhou , Hui Huang , Qian Liang , Zhenhui Kang . Construction of ZnO@CDs@Co₃O₄ sandwich heterostructure with multi-interfacial electron-transfer toward enhanced photocatalytic CO₂ reduction. Chinese Chemical Letters, 2024, 35(4): 109064-. doi: 10.1016/j.cclet.2023.109064
20. [20]
  Jie Wu , Xiaoqing Yu , Guoxing Li , Su Chen . Engineering particles towards 3D supraballs-based passive cooling via grafting CDs onto colloidal photonic crystals. Chinese Chemical Letters, 2024, 35(4): 109234-. doi: 10.1016/j.cclet.2023.109234

Get Citation

PDF

XML

Metrics

PDF Downloads(7)
Abstract views(516)
HTML views(92)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142