Citation: Fang Hu, Yao Gu, Fuhan Cui, Guihong Song, Kai Zhu. High-performance (NH₄)₂V₆O₁₆·0.9H₂O nanobelts modified with reduced graphene oxide for aqueous zinc ion batteries[J]. Chinese Chemical Letters, ;2021, 32(12): 3793-3798. doi: 10.1016/j.cclet.2021.04.032 shu

High-performance (NH₄)₂V₆O₁₆·0.9H₂O nanobelts modified with reduced graphene oxide for aqueous zinc ion batteries

Fang Hu ^{a, *,} ,
Yao Gu ^a ,
Fuhan Cui ^a ,
Guihong Song ^a ,
Kai Zhu ^{b, c, *,}

a.
School of Materials Science and Engineering, Shenyang University of Technology, Shenyang 110870, China
b.
Key Laboratory of Superlight Materials and Surface Technology of Ministry of Education, College of Materials Science and Chemical Engineering, Harbin Engineering University, Harbin 150010, China
c.
Department of Mechanical Engineering, the Hong Kong Polytechnic University, Hong Kong 999077, China

hufang25@126.com

kzhu@hrbeu.edu.cn

Received Date: 25 February 2021
Revised Date: 26 March 2021
Accepted Date: 16 April 2021
Available Online: 26 April 2021

Figures(4)

Ammonium vanadate has been considered as a competitive high-performance cathode material for aqueous Zn-ion batteries. However, it still suffers from insufficient rate capability and poor cyclability due to the low electronic conductivity. Herein, (NH₄)₂V₆O₁₆·0.9H₂O nanobelts with reduced graphene oxide (RGO) modification are synthesized by one-step hydrothermal reaction. Benefiting from the addition of RGO, an excellent electrochemical performance of (NH₄)₂V₆O₁₆·0.9H₂O@RGO nanobelts can be obtained. The (NH₄)₂V₆O₁₆·0.9H₂O@RGO displays a high-rate capacity and a high energy density of 386 Wh/kg at 72 W/kg. In particular, after 1000 cycles at 5 A/g, the capacity remains at 322 mAh/g with 92.8% capacity retention. In addition, the key reaction mechanisms of reversible Zn²⁺insertion/extraction in (NH₄)₂V₆O₁₆·0.9H₂O@RGO are clarified.
- (NH₄)₂V₆O₁₆·0.9H₂O@RGO,
- Nanobelts,
- Aqueous Zn-ion batteries,
- Electrochemical performance,
- Reaction mechanism
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通讯作者: 陈斌, bchen63@163.com

High-performance (NH₄)₂V₆O₁₆·0.9H₂O nanobelts modified with reduced graphene oxide for aqueous zinc ion batteries