Citation: Yangyang Fang, Xiaozhong Wang, Qianyan Pan, Yingqi Chen, Liyan Dai. Overcoming the limitations of anthracene alkylation using SZ-DeAl-DFNS acid catalyst[J]. Chinese Chemical Letters, ;2021, 32(12): 3976-3979. doi: 10.1016/j.cclet.2021.04.024 shu

Overcoming the limitations of anthracene alkylation using SZ-DeAl-DFNS acid catalyst

Yangyang Fang ^a ,
Xiaozhong Wang ^{a, b, *} ,
Qianyan Pan ^a ,
Yingqi Chen ^{a, b} ,
Liyan Dai ^{a, b, *,}

a.
College of Chemical and Biological Engineering, Zhejiang University, Zhejiang Provincial Key Laboratory of Advanced Chemical Engineering Manufacture Technology, Hangzhou 310027, China
b.
Institute of Zhejiang University - Quzhou, Quzhou 324000, China

dailiyan@zju.edu.cn

Received Date: 26 February 2021
Revised Date: 10 April 2021
Accepted Date: 14 April 2021
Available Online: 20 April 2021

Figures(7)

In situ formation of composite micro-mesoporous dendritic fibrous nano-silica (DFNS) and Al-DFNS was prepared using a cetylpyridinium bromide (CPB) template synthetic system. Dealumination is induced by impregnation of zirconium with flux followed by a sulfuric acid treatment. This procedure results in a series of highly uniform nano-spheres, which exhibit stronger acid property than that of Al-MCM-41. In the selective alkylation of anthracene with tert‑amyl alcohol, SO₄²⁻ modified Zr-contained dealuminated Al-DFNS (SZ-DeAl-DFNS) shows great catalytic activity and higher conversion (60.8%). The DFNS samples were characterized with XRD, SEM, TEM, NH₃-TPD and other techniques. The results reveal that DFNSs consist of center-radial micro-mesopores and that the acid contribution of SZ-DeAl-DFNS is much broader, as compared with amorphous aluminosilicate
- Dendritic fibrous nano-silica,
- Hierarchical structure,
- Anthracene alkylation,
- Shape-selective catalysis
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