Citation: Changli Wang, Xinran Li, Wenping Yang, Yuxia Xu, Huan Pang. Solvent regulation strategy of Co-MOF-74 microflower for supercapacitors[J]. Chinese Chemical Letters, ;2021, 32(9): 2909-2913. doi: 10.1016/j.cclet.2021.04.017 shu

Solvent regulation strategy of Co-MOF-74 microflower for supercapacitors

Changli Wang ^a ,
Xinran Li ^a ,
Wenping Yang ^a ,
Yuxia Xu ^{b, *,} ,
Huan Pang ^{a, *,}

a.
School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225009, China
b.
Guangling College, Yangzhou University, Yangzhou 225009, China

xuyuxia1105@163.com

panghuan@yzu.edu.cn

Received Date: 30 December 2020
Revised Date: 6 April 2021
Accepted Date: 9 April 2021
Available Online: 16 April 2021

Figures(6)

Metal-organic frameworks (MOFs) with porous crystal structures have attracted extensive attention in application of energy storage and conversion, owing to their regularity, porosity, large specific surface area, etc. In this work, Co-MOF-74 microflower has been successfully prepared via a controllable solvent regulation strategy. Through modulating the polarity of the solvent, crystals grow in certain preferred orientation and Co-MOF-74 with various morphologies were obtained. Thereinto, the energy storage performance of Co-MOF-74 microflower was measured in both three-electrode system and asymmetric supercapacitor device (specific capacitance of 164.2 F/g at 0.5 A/g in the three-electrode system and 62.5 F/g at 1 A/g in the asymmetric supercapacitor device). This can be attributed to the preferred crystal orientation resulting in a regular and uniform microflower, which is of great significance to electronic interfacial exchange and ion transfer during electrochemical reactions.
- Metal-organic frameworks,
- Solvent regulation strategy,
- Co-MOF-74 microflower,
- Pseudocapacitive-controlled behavior,
- Asymmetric supercapacitor device
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