Citation: Jing Xu, Juan Chen, Yanhui Ao, Peifang Wang. 0D/1D AgI/MoO₃ Z-scheme heterojunction photocatalyst: Highly efficient visible-light-driven photocatalyst for sulfamethoxazole degradation[J]. Chinese Chemical Letters, ;2021, 32(10): 3226-3230. doi: 10.1016/j.cclet.2021.04.003 shu

0D/1D AgI/MoO₃ Z-scheme heterojunction photocatalyst: Highly efficient visible-light-driven photocatalyst for sulfamethoxazole degradation

Key Laboratory of Integrated Regulation and Resource Development on Shallow Lakes of Ministry of Education, College of Environment, Hohai University, Nanjing 210098, China

andyao@hhu.edu.cn

Received Date: 16 December 2020
Revised Date: 14 February 2021
Accepted Date: 5 March 2021
Available Online: 3 April 2021

Figures(4)

Low dimension nano photocatalysts show great potential in the field of treating contaminated water for their large surface area and size effect. In this study, a 0D/1D AgI/MoO₃ Z-scheme photocatalyst with striking photocatalytic performance was constructed successfully. The one-dimensional MoO₃ nanobelts were prepared by a simple hydrothermal method, and then it was modified by AgI nanoparticles in a handy deposition approach. When choosing sulfamethoxazole (SMZ) as the target contaminant, the rate constant value of the optimal 0D/1D AgI/MoO₃ composite could hit up to 0.13 min^-1, which is nearly 22.4 times and 32.5 times as that of pure MoO₃ (0.0058 min^-1) and AgI (0.0040 min^-1), respectively. A series of detailed characterizations give evidences that the charge transfer in the composite followed Z scheme mechanism. Therefore, efficient separation/transfer and the remained high redox activity of photogenerated carriers played a vital role in the sharply enhanced photocatalytic properties. The possible degradation pathways of SMZ were proposed based on the intermediates detected by high-performance liquid chromatography-mass spectrometry (HPLC-MS). Meanwhile, the magnificent cyclic stability makes the material a promising material in the practical application.
- MoO₃-based-photocatalyst,
- 0D/1D,
- Z-scheme,
- Sulfamethoxazole,
- Visible-light-responsive
1. [1]
  Y. Yang, Y.S. Ok, K.H. Kim, et al., Sci. Total Environ. 596 (2017) 303-320.
2. [2]
  X. Feng, P. Wang, J. Hou, et al., Chem. Eng. J. 352 (2019) 947-956.
3. [3]
  H. Hai, X. Xing, S. Li, et al., Sci. Total Environ. 738 (2020) 265-283.
4. [4]
  D. Song, W.A. Jefferson, H. Cheng, et al., Chemosphere 222 (2019) 71-82. doi: 10.1016/j.chemosphere.2019.01.113
5. [5]
  S. He, C. Zhai, M. Fujitsuka, et al., Appl. Catal. B: Environ. 281 (2021) 119479. doi: 10.1016/j.apcatb.2020.119479
6. [6]
  M. Zhu, L. Zhang, S. Liu, et al., Chin. Chem. Lett. 31 (2020) 1961-1965. doi: 10.1016/j.cclet.2020.01.017
7. [7]
  Y. Ao, L. Xu, P. Wang, et al., Dalton Trans. 44 (2015) 11321-11330. doi: 10.1039/C5DT01168J
8. [8]
  S. Zhou, Y. Wang, K. Zhou, et al., Chin. Chem. Lett. 32 (2021) 2179-2182. . doi: 10.1016/j.cclet.2020.12.002
9. [9]
  X. Hu, X. Hu, Q. Peng, et al., Chem. Eng. J. 380 (2020) 122366. doi: 10.1016/j.cej.2019.122366
10. [10]
  E. Adamek, W. Baran, A. Sobczak, Process Saf. Environ. Prot. 103 (2016) 1-9. doi: 10.1016/j.psep.2016.06.015
11. [11]
  M. Tang, Y. Ao, P. Wang, et al., J. Hazard. Mater. 387 (2020) 121713. doi: 10.1016/j.jhazmat.2019.121713
12. [12]
  Z. Xie, Y. Feng, F. Wang, et al., Appl. Catal. B: Environ. 229 (2018) 96-104. doi: 10.1016/j.apcatb.2018.02.011
13. [13]
  D. Wang, Y. Ao, P. Wang, Sci. Total Environ. 746 (2020) 141149. doi: 10.1016/j.scitotenv.2020.141149
14. [14]
  Y. Zhang, S.J. Park, J. Catal. 361 (2018) 238-247. doi: 10.1016/j.jcat.2018.03.010
15. [15]
  Y. Zhang, S.J. Park, J. Mater. Chem. A: Mater. Energy Sustain. 6 (2018) 20304-20312. doi: 10.1039/C8TA08385A
16. [16]
  W. Yang, J. Xiao, Y. Ma, et al., Adv. Energy Mater. 9 (2019) 1803137. doi: 10.1002/aenm.201803137
17. [17]
  S.L. Prabavathi, P.S. Kumar, K. Saravanakumar, et al., J. Photochem. Photobiol. A: Chem. 356 (2018) 642-651. doi: 10.1016/j.jphotochem.2018.02.007
18. [18]
  Y. Zhang, S.J. Park, Appl. Catal. B: Environ. 240 (2019) 92-101. doi: 10.1016/j.apcatb.2018.08.077
19. [19]
  C. Lai, M. Zhang, B. Li, et al., Chem. Eng. J. 358 (2019) 891-902. doi: 10.1016/j.cej.2018.10.072
20. [20]
  J. Hu, D. Chen, Z. Mo, et al., Angew. Chem. Int. Ed. 58 (2019) 2073-2077. doi: 10.1002/anie.201813417
21. [21]
  H. Zhang, J. He, C. Zhai, et al., Chin. Chem. Lett. 30 (2019) 2338-2342. doi: 10.1016/j.cclet.2019.07.021
22. [22]
  Y.B. Chen, J.F. Li, P.Y. Liao, et al., Chin. Chem. Lett. 31 (2020) 1516-1519. doi: 10.1016/j.cclet.2019.12.013
23. [23]
  K.Z. Li, C.Y. Zhang, X. Li, et al., Catal. Today 335 (2019) 173-179. doi: 10.1016/j.cattod.2018.11.003
24. [24]
  M. Ren, Y. Ao, P. Wang, et al., Chem. Eng. J. 378 (2019) 122122. doi: 10.1016/j.cej.2019.122122
25. [25]
  S. He, C. Yan, X.Z. Chen, et al., Appl. Catal. B: Environ. 2 (2020) 119138.
26. [26]
  P. Zhou, J. Yu, M. Jaroniec, Adv. Mater. 26 (2014) 4920-4935. doi: 10.1002/adma.201400288
27. [27]
  W. Zhang, A.R. Mohamed, W.J. Ong, Angew. Chem. Int. Ed. 59 (2020) 22894-22915. doi: 10.1002/anie.201914925
28. [28]
  K. Maeda, ACS Catal. 3 (2013) 1486-1503. doi: 10.1021/cs4002089
29. [29]
  X.J. Wen, C.H. Shen, Z.H. Fei, et al., Chem. Eng. J. 383 (2020) 123083. doi: 10.1016/j.cej.2019.123083
30. [30]
  Y. Yang, Z. Zeng, C. Zhang, et al., Chem. Eng. J. 349 (2018) 808-821. doi: 10.1016/j.cej.2018.05.093
31. [31]
  T. Wang, W. Quan, D. Jiang, et al., Chem. Eng. J. 300 (2016) 280-290. doi: 10.1016/j.cej.2016.04.128
32. [32]
  M. Tang, Y. Ao, C. Wang, et al., Appl. Catal. B: Environ. 270 (2020) 118918. doi: 10.1016/j.apcatb.2020.118918
33. [33]
  M. Tang, Y. Ao, C. Wang, et al., Appl. Catal. B: Environ. 268 (2020) 118395. doi: 10.1016/j.apcatb.2019.118395
34. [34]
  X.J. Wen, L. Qian, X.X. Lv, et al., J. Hazard. Mater. 385 (2020) 121508. doi: 10.1016/j.jhazmat.2019.121508
35. [35]
  W. Teng, X. Tan, X. Li, et al., Appl. Surf. Sci. 409 (2017) 250-260. doi: 10.1016/j.apsusc.2017.03.025
36. [36]
  M.T. Qamar, M. Aslam, Z.A. Rehan, et al., Chem. Eng. J. 330 (2017) 322-336. doi: 10.1016/j.cej.2017.07.168
37. [37]
  J. Peña-Bahamonde, C. Wu, S.K. Fanourakis, et al., J. Catal. 381 (2020) 508-519. doi: 10.1016/j.jcat.2019.11.035
38. [38]
  Y. Wu, H. Wang, W. Tu, et al., Appl. Organomet. Chem. 33 (2019) e4780. doi: 10.1002/aoc.4780
39. [39]
  S. Li, F. Wang, W. Pan, et al., Chem. Eng. J. 373 (2019) 995-1002. doi: 10.1016/j.cej.2019.05.111
40. [40]
  Z. Wu, Y. Liang, X. Yuan, et al., Chem. Eng. J. 394 (2020) 124921. doi: 10.1016/j.cej.2020.124921
1. [1]
  Xingmin Chen , Yunyun Wu , Yao Tang , Peishen Li , Shuai Gao , Qiang Wang , Wen Liu , Sihui Zhan . Construction of Z-scheme Cu-CeO₂/BiOBr heterojunction for enhanced photocatalytic degradation of sulfathiazole. Chinese Chemical Letters, 2024, 35(7): 109245-. doi: 10.1016/j.cclet.2023.109245
2. [2]
  Cailiang Yue , Nan Sun , Yixing Qiu , Linlin Zhu , Zhiling Du , Fuqiang Liu . A direct Z-scheme 0D α-Fe₂O₃/TiO₂ heterojunction for enhanced photo-Fenton activity with low H₂O₂ consumption. Chinese Chemical Letters, 2024, 35(12): 109698-. doi: 10.1016/j.cclet.2024.109698
3. [3]
  Xiaoming Fu , Haibo Huang , Guogang Tang , Jingmin Zhang , Junyue Sheng , Hua Tang . Recent advances in g-C3N4-based direct Z-scheme photocatalysts for environmental and energy applications. Chinese Journal of Structural Chemistry, 2024, 43(2): 100214-100214. doi: 10.1016/j.cjsc.2024.100214
4. [4]
  Huan Hu , Ying Zhang , Shi-Shuang Huang , Zhi-Gang Li , Yungui Liu , Rui Feng , Wei Li . Temperature- and pressure-responsive photoluminescence in a 1D hybrid lead halide. Chinese Journal of Structural Chemistry, 2024, 43(10): 100395-100395. doi: 10.1016/j.cjsc.2024.100395
5. [5]
  Hualin Jiang , Wenxi Ye , Huitao Zhen , Xubiao Luo , Vyacheslav Fominski , Long Ye , Pinghua Chen . Novel 3D-on-2D g-C₃N₄/AgI._x._y heterojunction photocatalyst for simultaneous and stoichiometric production of H₂ and H₂O₂ from water splitting under visible light. Chinese Chemical Letters, 2025, 36(2): 109984-. doi: 10.1016/j.cclet.2024.109984
6. [6]
  Junjun Huang , Ran Chen , Yajian Huang , Hang Zhang , Anran Zheng , Qing Xiao , Dan Wu , Ruxia Duan , Zhi Zhou , Fei He , Wei Yi . Discovery of an enantiopure N-[2-hydroxy-3-phenyl piperazine propyl]-aromatic carboxamide derivative as highly selective α_1D/1A-adrenoceptor antagonist and homology modelling. Chinese Chemical Letters, 2024, 35(11): 109594-. doi: 10.1016/j.cclet.2024.109594
7. [7]
  Jiayuan Liang , Xin Mi , Songhao Guo , Hui Luo , Kejun Bu , Tonghuan Fu , Menglin Duan , Yang Wang , Qingyang Hu , Rengen Xiong , Peng Qin , Fuqiang Huang , Xujie Lü . Pressure-induced emission in 0D metal halide (EATMP)SbBr5 by regulating exciton-phonon coupling. Chinese Journal of Structural Chemistry, 2024, 43(7): 100333-100333. doi: 10.1016/j.cjsc.2024.100333
8. [8]
  Jiayu Huang , Kuan Chang , Qi Liu , Yameng Xie , Zhijia Song , Zhiping Zheng , Qin Kuang . Fe-N-C nanostick derived from 1D Fe-ZIFs for Electrocatalytic oxygen reduction. Chinese Journal of Structural Chemistry, 2023, 42(10): 100097-100097. doi: 10.1016/j.cjsc.2023.100097
9. [9]
  Xin Wang , Changzhao Chen , Qishen Wang , Kai Dai . Graphene quantum dot modified Bi2MoO6 nanoflower for efficient degradation of BPA under visible light. Chinese Journal of Structural Chemistry, 2024, 43(12): 100473-100473. doi: 10.1016/j.cjsc.2024.100473
10. [10]
  Jiaxing Cai , Wendi Xu , Haoqiang Chi , Qian Liu , Wa Gao , Li Shi , Jingxiang Low , Zhigang Zou , Yong Zhou . 具有0D/2D界面的InOOH/ZnIn₂S₄空心球S型异质结用于增强光催化CO₂转化性能. Acta Physico-Chimica Sinica, 2024, 40(11): 2407002-. doi: 10.3866/PKU.WHXB202407002
11. [11]
  Xudong Zhao , Yuxuan Wang , Xinxin Gao , Xinli Gao , Meihua Wang , Hongliang Huang , Baosheng Liu . Anchoring thiol-rich traps in 1D channel wall of metal-organic framework for efficient removal of mercury ions. Chinese Chemical Letters, 2025, 36(2): 109901-. doi: 10.1016/j.cclet.2024.109901
12. [12]
  Xiao-Ming Chen , Lianhui Song , Jun Pan , Fei Zeng , Yi Xie , Wei Wei , Dong Yi . Visible-light-induced four-component difunctionalization of alkenes to construct phosphorodithioate-containing quinoxalin-2(1H)-ones. Chinese Chemical Letters, 2024, 35(11): 110112-. doi: 10.1016/j.cclet.2024.110112
13. [13]
  Ping Lu , Baoyin Du , Ke Liu , Ze Luo , Abiduweili Sikandaier , Lipeng Diao , Jin Sun , Luhua Jiang , Yukun Zhu . Heterostructured In2O3/In2S3 hollow fibers enable efficient visible-light driven photocatalytic hydrogen production and 5-hydroxymethylfurfural oxidation. Chinese Journal of Structural Chemistry, 2024, 43(8): 100361-100361. doi: 10.1016/j.cjsc.2024.100361
14. [14]
  Guanyang Zeng , Xingqiang Liu , Liangqiao Wu , Zijie Meng , Debin Zeng , Changlin Yu . Novel visible-light-driven I- doped Bi2O2CO3 nano-sheets fabricated via an ion exchange route for dye and phenol removal. Chinese Journal of Structural Chemistry, 2024, 43(12): 100462-100462. doi: 10.1016/j.cjsc.2024.100462
15. [15]
  Yuexi Guo , Zhaoyang Li , Jingwei Dai . Charlie and the 3D Printing Chocolate Factory. University Chemistry, 2024, 39(9): 235-242. doi: 10.3866/PKU.DXHX202309067
16. [16]
  Jie Wu , Xiaoqing Yu , Guoxing Li , Su Chen . Engineering particles towards 3D supraballs-based passive cooling via grafting CDs onto colloidal photonic crystals. Chinese Chemical Letters, 2024, 35(4): 109234-. doi: 10.1016/j.cclet.2023.109234
17. [17]
  Yanrui Liu , Paramaguru Ganesan , Peng Gao . Harnessing d-f transition rare earth complexes for single layer white organic light emitting diodes. Chinese Journal of Structural Chemistry, 2024, 43(9): 100369-100369. doi: 10.1016/j.cjsc.2024.100369
18. [18]
  Hui Peng , Xiao Wang , Weiguo Huang , Shuiyue Yu , Linghang Kong , Qilin Wei , Jialong Zhao , Bingsuo Zou . Efficient tunable visible and near-infrared emission in Sb³⁺/Sm³⁺-codoped Cs₂NaLuCl₆ for near-infrared light-emitting diode, triple-mode fluorescence anti-counterfeiting and information encryption. Chinese Chemical Letters, 2024, 35(11): 109462-. doi: 10.1016/j.cclet.2023.109462
19. [19]
  Bicheng Zhu , Jingsan Xu . S-scheme heterojunction photocatalyst for H2 evolution coupled with organic oxidation. Chinese Journal of Structural Chemistry, 2024, 43(8): 100327-100327. doi: 10.1016/j.cjsc.2024.100327
20. [20]
  Zongyi Huang , Cheng Guo , Quanxing Zheng , Hongliang Lu , Pengfei Ma , Zhengzhong Fang , Pengfei Sun , Xiaodong Yi , Zhou Chen . Efficient photocatalytic biomass-alcohol conversion with simultaneous hydrogen evolution over ultrathin 2D NiS/Ni-CdS photocatalyst. Chinese Chemical Letters, 2024, 35(7): 109580-. doi: 10.1016/j.cclet.2024.109580

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(594)
HTML views(5)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

0D/1D AgI/MoO3 Z-scheme heterojunction photocatalyst: Highly efficient visible-light-driven photocatalyst for sulfamethoxazole degradation

Metrics

通讯作者: 陈斌, bchen63@163.com

0D/1D AgI/MoO₃ Z-scheme heterojunction photocatalyst: Highly efficient visible-light-driven photocatalyst for sulfamethoxazole degradation