Citation: Jing Li, Zhuanjun Zhao, Yiran Song, Yang You, Jie Li, Xiuwen Cheng. Synthesis of Mg(Ⅱ) doped ferrihydrite-humic acid coprecipitation and its Pb(Ⅱ)/Cd(Ⅱ) ion sorption mechanism[J]. Chinese Chemical Letters, ;2021, 32(10): 3231-3236. doi: 10.1016/j.cclet.2021.03.086 shu

Synthesis of Mg(Ⅱ) doped ferrihydrite-humic acid coprecipitation and its Pb(Ⅱ)/Cd(Ⅱ) ion sorption mechanism

Key Laboratory of Western China's Environmental Systems (Ministry of Education) and Key Laboratory for Environmental Pollution Prediction and Control, Gansu Province, College of Earth and Environmental Sciences, Lanzhou University, Lanzhou 730000, China

zhj_zhao@lzu.edu.cn

chengxw@lzu.edu.cn

Received Date: 3 December 2020
Revised Date: 27 February 2021
Accepted Date: 30 March 2021
Available Online: 2 April 2021

Figures(4)

A magnesium doped ferrihydrite-humic acid coprecipitation (Mg-doped Fh-HA) was synthesized by coprecipitation method. The removal of heavy metals such as Pb(Ⅱ) and Cd(Ⅱ) was assessed. The isotherms and kinetic studies indicated that the Mg-doped Fh-HA exhibited a remarkable Pb(Ⅱ) and Cd(Ⅱ) sorption capacity (maximum 120.43 mg/g and 27.7 mg/g, respectively.) in aqueous solution. The sorption of Pb(Ⅱ) and Cd(Ⅱ) onto best fitted pseudo-second-order kinetic equation and Langmuir model. The adsorption mechanism of Mg-doped Fh-HA on Pb(Ⅱ) and Cd(Ⅱ) involves surface adsorption, surface complexation and surface functional groups (such as carboxyl group, hydroxyl group). In addition, ion-exchange and precipitation cannot be ignored. The Mg-doped Fh-HA is a low-cost and high-performance adsorption material and has a wide range of application prospects.
- Ferrihydrite,
- Humic acid,
- Magnesium,
- Adsorption
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