Citation: Qian Li, Yuchao Wang, Jian Zeng, Qiumei Wu, Qichen Wang, Lian Sun, Liang Xu, Tong Ye, Xin Zhao, Lei Chen, Zhiyan Chen, Limiao Chen, Yongpeng Lei. Phosphating-induced charge transfer on CoO/CoP interface for alkaline H₂ evolution[J]. Chinese Chemical Letters, ;2021, 32(11): 3355-3358. doi: 10.1016/j.cclet.2021.03.063 shu

Phosphating-induced charge transfer on CoO/CoP interface for alkaline H₂ evolution

Qian Li ^{a, b, 1} ,
Yuchao Wang ^{a, b, 1} ,
Jian Zeng ^{a, c, 1} ,
Qiumei Wu ^a ,
Qichen Wang ^{a, d} ,
Lian Sun ^a ,
Liang Xu ^c ,
Tong Ye ^{a, e} ,
Xin Zhao ^a ,
Lei Chen ^a ,
Zhiyan Chen ^b ,
Limiao Chen ^d ,
Yongpeng Lei ^{a, d, *,}

a.
State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, China
b.
School of Material Science and Engineering, Central South University of Forestry and Technology, Changsha 410004, China
c.
Energy Materials Computing Center, Jiangxi University of Science and Technology, Nanchang 330013, China
d.
Hunan Provincial Key Laboratory of Chemical Power Sources, College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China
e.
School of Material and Chemical Engineering, Xi'an Technological University, Xi'an 710021, China

lypkd@163.com

Received Date: 22 January 2021
Revised Date: 7 February 2021
Accepted Date: 23 March 2021
Available Online: 26 March 2021

Figures(4)

Designing non-noble metal electrocatalysts toward alkaline hydrogen evolution reaction (HER) with high performance at a large current density is urgent. Herein, a CoO/CoP heterostructure catalyst (termed POZ) was designed by a phosphating strategy. The strong electron transfer on the interface of CoO/CoP was experimentally and theoretically proven. POZ showed a low overpotential of 236 mV at 400 mA/cm², which was 249 mV lower than non-phosphated sample. It also exhibited a remarkable solar-to-hydrogen conversion efficiency of 10.5%. In this work, the construction of CoO/CoP interface realized by a simple phosphating strategy could provide an important reference to boost the HER performance on those materials not merely metal oxides.
- CoO/CoP heterostructure,
- Phosphating,
- H₂ evolution reaction,
- Alkaline media,
- Solar-driven water splitting
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Phosphating-induced charge transfer on CoO/CoP interface for alkaline H2 evolution

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通讯作者: 陈斌, bchen63@163.com

Phosphating-induced charge transfer on CoO/CoP interface for alkaline H₂ evolution