Citation: Shanshan Chen, Liying Yin, Lin Liu, Ning Zhang, Dewen Dong. Ion-induced white-light-emitting polymeric hydrogels with high mechanical strength and reversible stimuli-responsive properties[J]. Chinese Chemical Letters, ;2021, 32(10): 3133-3136. doi: 10.1016/j.cclet.2021.03.059 shu

Ion-induced white-light-emitting polymeric hydrogels with high mechanical strength and reversible stimuli-responsive properties

Shanshan Chen ^{a, b} ,
Liying Yin ^c ,
Lin Liu ^c ,
Ning Zhang ^{a, c, *,} ,
Dewen Dong ^{a, b, *,}

a.
CAS Key Laboratory of High-Performance Synthetic Rubber and its Composite Materials, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
b.
University of Science and Technology of China, Hefei 230026, China
c.
Department of Chemistry, Northeast Normal University, 5268 Renmin Street, Changchun 130024, China

zhangn380@nenu.edu.cn

dwdong@ciac.ac.cn

Received Date: 2 March 2021
Revised Date: 17 March 2021
Accepted Date: 22 March 2021
Available Online: 23 March 2021

Figures(4)

We have developed a facile strategy to fabricate model multicolor hydrogels via a straightforward mixing process of poly acrylonitrile-grafted methacrylamide (PANMAM), polymethacrylic acid (PMAA) and doped lanthanide (Eu/Tb) and zinc ions to form the interpenetrating dual-polymer gel networks. The hydrogels exhibit excellent tunability of multi-spectrum emission colors (including white light) by simply varying the stoichiometry of metal ions. Furthermore, taking the advantage of different metal ion response mechanisms, we have demonstrated the reversible acidity/alkalinity stimuli-responsive behaviors of white-light-emitting hydrogel (WLE gel). Meanwhile, the unique cross-linked network formed through hydrogen-bonding, metal-ligand coordination and ionic interaction is introduced to achieve favorable mechanical strength of hydrogels. These properties enable the possibility in obtaining fluorescent patterns on hydrogels, which are promising candidate for encrypted information with improved security.
- Polymeric hydrogel,
- Tunable fluorescence,
- White-light-emitting,
- Metal-coordination,
- Pattern
1. [1]
  E.A. Widder, Science 328 (2010) 704-708. doi: 10.1126/science.1174269
2. [2]
  S.A. Morin, R.F. Shepherd, S.W. Kwok, et al., Science 337 (2012) 828-832. doi: 10.1126/science.1222149
3. [3]
  H. Wei, N. Shi, J. Zhang, et al., Chem. Commun. 50 (2014) 9333-9335. doi: 10.1039/C4CC04000G
4. [4]
  W. Lu, S. Wei, H. S, et al., Aggregate 2 (2021) e37.
5. [5]
  Y. Yao, Y. Wang, Z. Li, H. Li, Langmuir 31 (2015) 12736-12741. doi: 10.1021/acs.langmuir.5b03102
6. [6]
  M.D. Weber, L. Niklaus, M. Proeschel, et al., Adv. Mater. 27 (2015) 5493-5498. doi: 10.1002/adma.201502349
7. [7]
  P. Wei, Z. Li, J.X. Zhang, et al., Chem. Mater. 31 (2019) 1092-1100. doi: 10.1021/acs.chemmater.8b04909
8. [8]
  X. Ji, Z. Li, X. Liu, et al., Adv. Mater. 31 (2019) 1902365-1902372. doi: 10.1002/adma.201902365
9. [9]
  W. Lu, C. Ma, D. Zhang, et al., J. Phys. Chem. C 122 (2018) 9499-9506.
10. [10]
  K. Meng, C. Yao, Q. Ma, et al., Adv. Sci. 6 (2019) 1802112. doi: 10.1002/advs.201802112
11. [11]
  Q. Li, Y. Zhang, C. Wang, D.A. Weitz, S. Chen, Adv. Mater. 30(2018).
12. [12]
  S. Wei, Z. Li, W. Lu, et al., Angew. Chem. 132 (2020) 2-19. doi: 10.1002/ange.201914768
13. [13]
  K. Binnemans, Chem. Rev. 109 (2009) 4283-4374.
14. [14]
  D. Ananias, F.A.A. Paz, D.S. Yufit, L.D. Carlos, J. Rocha, J. Am, Chem. Soc. 46 (2015) 3051-3058.
15. [15]
  P. Falcaro, P.D.S. Furukawa, Angew. Chem. Int. Ed. 51 (2012) 8431-8433. doi: 10.1002/anie.201203719
16. [16]
  V.K. Praveen, C. Ranjith, N. Armaroli, Angew. Chem. Int. Ed. 53 (2014) 365-368. doi: 10.1002/anie.201306787
17. [17]
  G. He, D. Guo, C. He, X. Zhang, X. Zhao, Angew. Chem. 121 (2009) 6248-6251. doi: 10.1002/ange.200901266
18. [18]
  F. Zhou, Z.G. Xu, J.H. Suo, et al., Macromol. Rapid Commun. 36 (2015) 465-471. doi: 10.1002/marc.201400630
19. [19]
  Z. Tang, X. Lyu, L. Luo, Z. Shen, X.H. Fan, ACS Appl. Mater. Interfaces 12 (2020) 45420-45428. doi: 10.1021/acsami.0c15656
20. [20]
  S. Chen, T. Sun, Z. Xie, D. Dong, N. Zhang, Polym. Chem. 11 (2020) 6650-6657. doi: 10.1039/D0PY01054E
21. [21]
  Y. Wang, S. Liu, Y. Yang, et al., ACS Appl. Mater. Interfaces 7 (2015) 4415-4422. doi: 10.1021/am5089346
22. [22]
  X. Chen, Y. Wang, R. Chai, Y. Xu, B. Liu, ACS Appl. Mater. Interfaces 9 (2017) 13554-13563. doi: 10.1021/acsami.7b02679
23. [23]
  P.P. Neelakandan, M. Hariharan, D.A. Ramaiah, J. Am. Chem. Soc. 128 (2006) 11334-11335. doi: 10.1021/ja062651m
24. [24]
  S.K. Samanta, S. Bhattacharya, J. Mater. Chem. 22 (2012) 25277-25287. doi: 10.1039/c2jm35012b
25. [25]
  C. Vijayakumar, V.K. Praveen, A. Ajayaghosh, Adv. Mater. 21 (2010) 2059-2063.
26. [26]
  G. Weng, S. Thanneeru, J. He, Adv. Mater. 30 (2018) 1706526. doi: 10.1002/adma.201706526
27. [27]
  M. Martínez-Calvo, O. Kotova, M.E. Möbius, et al., J. Am. Chem. Soc. 137 (2015) 1983-1992. doi: 10.1021/ja511799n
28. [28]
  Z. Li, G. Wang, Y. Wang, H. Li, Angew. Chem. Int. Ed. 57 (2018) 2194-2198. doi: 10.1002/anie.201712670
29. [29]
  Y. Xiong, Z. Chen, H. Wang, et al., Chem. Commun. 52 (2016) 14157-14160. doi: 10.1039/C6CC08513J
30. [30]
  X. Yu, Z. Wang, Y. Li, et al., Inorg. Chem. 56 (2017) 7512-7518. doi: 10.1021/acs.inorgchem.7b01031
31. [31]
  S. Bhattacharya, S.K. Samanta, Chemistry 18 (2012) 16632-16641. doi: 10.1002/chem.201201940
32. [32]
  M. Kawa, J.M. Fréchet, Chem. Mater. 10 (1998) 286-296. doi: 10.1021/cm970441q
33. [33]
  N. Sabbatini, M. Guardigli, Guardigli, J.M. Guardigli, Coord. Chem. Rev. 123 (1993) 201-228. doi: 10.1016/0010-8545(93)85056-A
34. [34]
  Z. Liu, W. He, Z. Guo, Chem. Soc. Rev. 42 (2013) 1568-1600. doi: 10.1039/c2cs35363f
35. [35]
  P. Li, D. Zhang, Y. Zhang, et al., ACS Macro Lett. 8 (2019) 937-942. doi: 10.1021/acsmacrolett.9b00337
36. [36]
  X. Le, H. Shang, H. Yan, et al., Angew. Chem. Int. Ed. 60 (2021) 3640-3646. doi: 10.1002/anie.202011645
1. [1]
  Hui Peng , Xiao Wang , Weiguo Huang , Shuiyue Yu , Linghang Kong , Qilin Wei , Jialong Zhao , Bingsuo Zou . Efficient tunable visible and near-infrared emission in Sb³⁺/Sm³⁺-codoped Cs₂NaLuCl₆ for near-infrared light-emitting diode, triple-mode fluorescence anti-counterfeiting and information encryption. Chinese Chemical Letters, 2024, 35(11): 109462-. doi: 10.1016/j.cclet.2023.109462
2. [2]
  Pingping Wang , Huixian Miao , Kechuan Sheng , Bin Wang , Fan Feng , Xuankun Cai , Wei Huang , Dayu Wu . Efficient blue-light-excitable copper(Ⅰ) coordination network phosphors for high-performance white LEDs. Chinese Chemical Letters, 2024, 35(4): 108600-. doi: 10.1016/j.cclet.2023.108600
3. [3]
  Yanrui Liu , Paramaguru Ganesan , Peng Gao . Harnessing d-f transition rare earth complexes for single layer white organic light emitting diodes. Chinese Journal of Structural Chemistry, 2024, 43(9): 100369-100369. doi: 10.1016/j.cjsc.2024.100369
4. [4]
  Xiangan Song , Shaogang Shen , Mengyao Lu , Ying Wang , Yong Zhang . Trifluoromethyl enable high-performance single-emitter white organic light-emitting devices based on quinazoline acceptor. Chinese Chemical Letters, 2024, 35(4): 109118-. doi: 10.1016/j.cclet.2023.109118
5. [5]
  Yue Pan , Wenping Si , Yahao Li , Haotian Tan , Ji Liang , Feng Hou . Promoting exciton dissociation by metal ion modification in polymeric carbon nitride for photocatalysis. Chinese Chemical Letters, 2024, 35(12): 109877-. doi: 10.1016/j.cclet.2024.109877
6. [6]
  Ziruo Zhou , Wenyu Guo , Tingyu Yang , Dandan Zheng , Yuanxing Fang , Xiahui Lin , Yidong Hou , Guigang Zhang , Sibo Wang . Defect and nanostructure engineering of polymeric carbon nitride for visible-light-driven CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(3): 100245-100245. doi: 10.1016/j.cjsc.2024.100245
7. [7]
  Ziyou Zhang , Te Ji , Hongliang Dong , Zhiqiang Chen , Zhi Su . Effect of coordination restriction on pressure-induced fluorescence evolution. Chinese Chemical Letters, 2024, 35(12): 109542-. doi: 10.1016/j.cclet.2024.109542
8. [8]
  Jun-Ting Mo , Zheng Wang . Achieving tunable long persistent luminescence in metal organic halides based on pyridine solvent. Chinese Chemical Letters, 2024, 35(9): 109360-. doi: 10.1016/j.cclet.2023.109360
9. [9]
  Deshuai Zhen , Chunlin Liu , Qiuhui Deng , Shaoqi Zhang , Ningman Yuan , Le Li , Yu Liu . A review of covalent organic frameworks for metal ion fluorescence sensing. Chinese Chemical Letters, 2024, 35(8): 109249-. doi: 10.1016/j.cclet.2023.109249
10. [10]
  Shuwen SUN , Gaofeng WANG . Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368
11. [11]
  Yuan Liu , Boyang Wang , Yaxin Li , Weidong Li , Siyu Lu . Understanding excitonic behavior and electroluminescence light emitting diode application of carbon dots. Chinese Chemical Letters, 2025, 36(2): 110426-. doi: 10.1016/j.cclet.2024.110426
12. [12]
  Chaoqun Ma , Yuebo Wang , Ning Han , Rongzhen Zhang , Hui Liu , Xiaofeng Sun , Lingbao Xing . Carbon dot-based artificial light-harvesting systems with sequential energy transfer and white light emission for photocatalysis. Chinese Chemical Letters, 2024, 35(4): 108632-. doi: 10.1016/j.cclet.2023.108632
13. [13]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
14. [14]
  Zhiqiang Liu , Qiang Gao , Wei Shen , Meifeng Xu , Yunxin Li , Weilin Hou , Hai-Wei Shi , Yaozuo Yuan , Erwin Adams , Hian Kee Lee , Sheng Tang . Removal and fluorescence detection of antibiotics from wastewater by layered double oxides/metal-organic frameworks with different topological configurations. Chinese Chemical Letters, 2024, 35(8): 109338-. doi: 10.1016/j.cclet.2023.109338
15. [15]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
16. [16]
  Tao Zhou , Jing Zhou , Yunyun Liu , Jie-Ping Wan , Fen-Er Chen . Transition metal-free tunable synthesis of 3-(trifluoromethylthio) and 3-trifluoromethylsulfinyl chromones via domino C–H functionalization and chromone annulation of enaminones. Chinese Chemical Letters, 2024, 35(11): 109683-. doi: 10.1016/j.cclet.2024.109683
17. [17]
  Peipei CUI , Xin LI , Yilin CHEN , Zhilin CHENG , Feiyan GAO , Xu GUO , Wenning YAN , Yuchen DENG . Transition metal coordination polymers with flexible dicarboxylate ligand: Synthesis, characterization, and photoluminescence property. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2221-2231. doi: 10.11862/CJIC.20240234
18. [18]
  Rui Wang , He Qi , Haijiao Zheng , Qiong Jia . Light/pH dual-responsive magnetic metal-organic frameworks composites for phosphorylated peptide enrichment. Chinese Chemical Letters, 2024, 35(7): 109215-. doi: 10.1016/j.cclet.2023.109215
19. [19]
  Lang Gao , Cen Zhou , Rui Wang , Feng Lan , Bohang An , Xiaozhou Huang , Xiao Zhang . Unveiling inverse vulcanized polymers as metal-free, visible-light-driven photocatalysts for cross-coupling reactions. Chinese Chemical Letters, 2024, 35(4): 108832-. doi: 10.1016/j.cclet.2023.108832
20. [20]
  Yiran Tao , Chunlei Dai , Zhaoxiang Xie , Xinru You , Kaiwen Li , Jun Wu , Hai Huang . Redox responsive polymeric nanoparticles enhance the efficacy of cyclin dependent kinase 7 inhibitor for enhanced treatment of prostate cancer. Chinese Chemical Letters, 2024, 35(8): 109170-. doi: 10.1016/j.cclet.2023.109170

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(582)
HTML views(7)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142