Citation: Zhirong Zhang, Zhongping Yao, Zhaohua Jiang. Fast self-assembled microfibrillated cellulose@MXene film with high-performance energy storage and superior mechanical strength[J]. Chinese Chemical Letters, ;2021, 32(11): 3575-3578. doi: 10.1016/j.cclet.2021.03.025 shu

Fast self-assembled microfibrillated cellulose@MXene film with high-performance energy storage and superior mechanical strength

School of Chemistry and Chemical Engineering, State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology, Harbin 150001, China

yaozhongping@hit.edu.cn

Received Date: 17 February 2021
Revised Date: 9 March 2021
Accepted Date: 10 March 2021
Available Online: 17 March 2021

Figures(3)

The trade-off between the electrochemical performance and mechanical strength is still a challenge for Ti₃C₂T_x free-standing electrode. Herein, a facile approach was proposed to fabricate a Microfibrillated cellulose@Ti₃C₂T_x (MFC@Ti₃C₂T_x) self-assembled microgel film by means of hydrogen bonding linkage. Benefiting from the rich hydroxyl groups on the MFC, the Ti₃C₂T_x nanosheets coated on the MFC in a time scale of minutes (within 1 min) instead of hours. The ultralong 1D frame of MFC effectively mitigated the re-aggregation of Ti₃C₂T_x nanosheet. The fluffy MFC@Ti₃C₂T_x film structure and the constructed 1D/2D conducting Ti₃C₂T_x pathways in horizontal and vertical directions endowed the fast ion transport of the electrolytes and the improved accessibility to the Ti₃C₂T_x surface. As a result, the freestanding MFC@Ti₃C₂T_x microgel film delivered a high specific capacitance of 451 F/g. And the rate performance was increased to 71% from the 64% of that of pristine Ti₃C₂T_x film. Furthermore, the tensile strength of MFC@Ti₃C₂T_x film was also promoted to 46.3 MPa, 3 folds of that of the pristine Ti₃C₂T_x film, due to the high strength of MFC and the hydrogen bonding effect.
- MXene,
- Microfibrillated cellulose,
- Supercapacitor,
- Self-assemble,
- Microgel
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