Citation: Jialiang Wei, Jie Li, Chuang Yu, Qimeng Sun, Jinghui He, Jianmei Lu. Application of ion-in-conjugation molecules in resistive memories and gas sensors: The role of conjugation[J]. Chinese Chemical Letters, ;2021, 32(8): 2463-2468. doi: 10.1016/j.cclet.2021.03.017 shu

Application of ion-in-conjugation molecules in resistive memories and gas sensors: The role of conjugation

Jialiang Wei ^b ,
Jie Li ^b ,
Chuang Yu ^b ,
Qimeng Sun ^b ,
Jinghui He ^{b, *} ,
Jianmei Lu ^{b, *}

a.
College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Center of Suzhou Nano Science and Technology, National United Engineering Laboratory of Functionalized Environmental Adsorption Materials, Soochow University, Suzhou 215123, China
b.
Shanghai Institute of Measurement and Testing Technology, Shanghai 201203, China

jinghhe@suda.edu.cn

lujm@suda.edu.cn

Received Date: 29 December 2020
Revised Date: 3 March 2021
Accepted Date: 7 March 2021
Available Online: 9 March 2021

Figures(8)

Ion-in-conjugation (IIC) materials are emerging as an important class of organic electronic materials with wide applications in energy storage, resistive memories and gas sensors. Many IIC materials were designed and investigated, however the role of conjugation in IIC materials' performance is yet investigated. Here we designed two molecules obtained by condensation of 4-butylaniline and oxocarbon acid. Squaric acid derivatives squaraine named SA-Bu and a croconamide named CA-Bu which only differ in their oxocarbon cores. While employing SA-Bu and CA-Bu as resistive memory and gas sensory materials, SA-Bu has attained promising performance in ternary memory and detection of NO₂ as low as 10 parts-per-billion whereas CA-Bu show mainly binary memory behavior and negligible NO₂ response. Theoretical calculations reveal that conjugation of CA-Bu was distorted by the increased steric hindrance, frustrating the charge transport and suppressing the conductivity. Our work demonstrates that the conjugation plays a crucial role in ion-in-materials promoting ternary RRAM devices and high-performance gas sensors manufacture.
- Ion-in-conjugation,
- Organic electronic materials,
- RRAM,
- Gas sensing,
- Density functional theory
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