Citation: Baozhu Wu, Shuo Qi, Xikai Wu, Haoli Wang, Qiangqiang Zhuang, Huimin Yi, Pu Xu, Zhennan Xiong, Gejun Shi, Shuangqiang Chen, Baofeng Wang. FeBO₃ as a low cost and high-performance anode material for sodium-ion batteries[J]. Chinese Chemical Letters, ;2021, 32(10): 3113-3117. doi: 10.1016/j.cclet.2021.03.014 shu

FeBO₃ as a low cost and high-performance anode material for sodium-ion batteries

Baozhu Wu ^a ,
Shuo Qi ^b ,
Xikai Wu ^a ,
Haoli Wang ^a ,
Qiangqiang Zhuang ^a ,
Huimin Yi ^a ,
Pu Xu ^a ,
Zhennan Xiong ^a ,
Gejun Shi ^a ,
Shuangqiang Chen ^b ,
Baofeng Wang ^{a, *,}

a.
Shanghai Key Laboratory of Materials Protection and Advanced Materials in Electric Power, Shanghai University of Electric Power, Shanghai 200090, China
b.
Department of Chemical Engineering, School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, China

wangbaofeng@shiep.edu.cn

Received Date: 5 February 2021
Revised Date: 2 March 2021
Accepted Date: 4 March 2021
Available Online: 9 March 2021

Figures(5)

The research of borate materials as sodium-ion batteries (SIBs) anode is still in the early stages, but the boron polyoxoanions are attracting intense interest due to their low atomic weight and high electronegative features. In this work, FeBO₃ was prepared with low-cost raw materials and evaluated as SIBs anode. The FeBO₃ shows a high reversible capacity of 328 mAh/g at the current density of 0.4 A/g. In addition, the electrochemical performance of FeBO₃ can be improved by carbon coating. The prepared carbon-coated FeBO₃ composite has a reversible capacity of 426 mAh/g (at 0.4 A/g) and an outstanding rate capability of 272 mAh/g (at 1.6 A/g). Furthermore, the sodium storage mechanism of FeBO₃ was studied by in-situ XRD and ex-situ XPS.
- FeBO₃,
- Metal borates,
- Anode materials,
- Sodium-ion batteries,
- Sodium storage mechanism
1. [1]
  H. Pan, Y.S. Hu, L.Q. Chen, et al., Energy Environ. Sci. 6 (2013) 2338-2360 doi: 10.1039/c3ee40847g
2. [2]
  H. Kang, Y. Liu, K. Cao, et al., J. Mater. Chem. A 3 (2015) 17899-17913 doi: 10.1039/C5TA03181H
3. [3]
  C. Delmas, Adv. Energy Mater. 8 (2018) 1703137 doi: 10.1002/aenm.201703137
4. [4]
  M.D. Slater, D. Kim, E. Lee, et al., Adv. Funct. Mater. 23 (2013) 947-958 doi: 10.1002/adfm.201200691
5. [5]
  Y. Fang, L. Xiao, Z. Chen, et al., Electro. Ener. Rev. 1 (2018) 294-323 doi: 10.1007/s41918-018-0008-x
6. [6]
  K. Chayambuka, G. Mulder, D.L. Danilov, et al., Adv. Funct. Mater. 8 (2018) 1800079 doi: 10.1002/aenm.201800079
7. [7]
  J.Y. Hwang, S.T. Myung, Y.K. Sun, Chem. Soc. Rev. 46 (2017) 3529-3614 doi: 10.1039/C6CS00776G
8. [8]
  E. Irisarri, A. Ponrouch, M. Palacin, J. Electrochem. Soc. 162 (2015) A2476 doi: 10.1149/2.0091514jes
9. [9]
  M. -S. Balogun, Y. Luo, W. Qiu, et al., Carbon 98 (2016) 162-178 doi: 10.1016/j.carbon.2015.09.091
10. [10]
  P. Lu, Y. Sun, H. Xiang, et al., Adv. Energy Mater. 8 (2018) 1702434 doi: 10.1002/aenm.201702434
11. [11]
  Y. Jiang, M. Hu, D. Zhang, et al., Nano Energy 5 (2014) 60-66 doi: 10.1016/j.nanoen.2014.02.002
12. [12]
  H. Su, S. Jaffer, H. Yu, Energy Storage Mater. 5 (2016) 116-131 doi: 10.1016/j.ensm.2016.06.005
13. [13]
  M.K. Datta, R. Epur, P. Saha, et al., J. Power Sources 225 (2013) 316-322 doi: 10.1016/j.jpowsour.2012.10.014
14. [14]
  Z. Li, J. Ding, D. Mitlin, Acc. Chem. Res. 48 (2015) 1657-1665 doi: 10.1021/acs.accounts.5b00114
15. [15]
  L. Li, J. Zhao, Y. Zhu, et al., Electrochim. Acta 353 (2020) 136532 doi: 10.1016/j.electacta.2020.136532
16. [16]
  Z. Zheng, P. Li, J. Huang, et al., J. Energy Chem. 41 (2020) 126-134 doi: 10.1016/j.jechem.2019.05.009
17. [17]
  B. Xu, Y. Liu, J. Tian, et al., Chem. Eng. J. 363 (2019) 285-291 doi: 10.1016/j.cej.2019.01.089
18. [18]
  S. Wang, X.B. Zhang, Adv. Mater. 31 (2019) e1805432 doi: 10.1002/adma.201805432
19. [19]
  Q. Ping, B. Xu, X. Ma, et al., Dalton Trans. 48 (2019) 5741-5748 doi: 10.1039/c9dt00010k
20. [20]
  K. Zhou, G. Xu, Y. Chen, et al., Chem. Eng. J. 375 (2019) 121998 doi: 10.1016/j.cej.2019.121998
21. [21]
  M. Dong, Q. Kuang, X. Zeng, et al., J. Alloys Compd. 812 (2020) 152165 doi: 10.1016/j.jallcom.2019.152165
22. [22]
  D. Wu, Q. Kuang, Y. Zhao, et al., J. Alloys Compd. 732 (2018) 506-510 doi: 10.1016/j.jallcom.2017.10.254
23. [23]
  J. Tian, B. Wang, F. Zhao, et al., Chem. Commun. 53 (2017) 4698-4701 doi: 10.1039/C7CC01612C
24. [24]
  K. Cao, L. Jiao, H. Liu, et al., Adv. Energy Mater. 5 (2015) 1401421 doi: 10.1002/aenm.201401421
25. [25]
  S.H. Yu, D.E. Conte, S. Baek, et al., Adv. Funct. Mater. 23 (2013) 4293-4305 doi: 10.1002/adfm.201300190
26. [26]
  R. Ge, X. Ren, F. Qu, et al., Chem. Eur. J. 23 (2017) 6959-6963 doi: 10.1002/chem.201700408
27. [27]
  K. Dastafkan, Y. Li, Y. Zeng, et al., J. Mater. Chem. A 7 (2019) 15252-15261 doi: 10.1039/c9ta03346g
28. [28]
  H. Zhao, Y. Wang, Y. Wang, et al., Appl. Catal. B: Environ. 125 (2012) 120-127 doi: 10.1016/j.apcatb.2012.05.044
29. [29]
  W.J. Jiang, S. Niu, T. Tang, et al., Angew. Chem. Int. Ed. 56 (2017) 6572-6577 doi: 10.1002/anie.201703183
30. [30]
  H. Li, H. Zhou, Chem. Commun. 48 (2012) 1201-1217 doi: 10.1039/C1CC14764A
31. [31]
  X. Li, J. Li, Q. Gao, et al., Electrochim. Acta 254 (2017) 172-180 doi: 10.1016/j.electacta.2017.09.128
32. [32]
  Y. Jiang, Z. Yang, W. Li, et al., Adv. Energy Mater. 5 (2015) 1402104 doi: 10.1002/aenm.201402104
33. [33]
  X. Chen, C. Chen, Y. Zhang, et al., Nano Res. 12 (2018) 631-636 doi: 10.1109/AMC.2019.8371167
34. [34]
  L. Chen, L. Huang, G. Chen, et al., Chemistry 26 (2020) 8926-8934 doi: 10.1002/chem.202000558
35. [35]
  F. Kong, L. Lv, Y. Gu, et al., J. Mater. Sci. 54 (2018) 4225-4235
36. [36]
  S. Zhao, K. Yan, P. Munroe, et al., Adv. Energy Mater. 9 (2019) 1803757 doi: 10.1002/aenm.201803757
37. [37]
  D. Li, Y. Zhang, Q. Sun, et al., Energy Storage Mater. 23 (2019) 367-374 doi: 10.1016/j.ensm.2019.04.037
38. [38]
  Z. Jian, Z. Xing, C. Bommier, et al., Adv. Energy Mater. 6 (2016) 1501874 doi: 10.1002/aenm.201501874
39. [39]
  S.R. Das, S.B. Majumder, R.S. Katiyar, J. Power Sources 139 (2005) 261-268 doi: 10.1016/j.jpowsour.2004.06.056
40. [40]
  V. Augustyn, J. Come, M.A. Lowe, et al., Nat Mater. 12 (2013) 518-522 doi: 10.1038/nmat3601
41. [41]
  G. Fang, Z. Wu, J. Zhou, et al., Adv. Energy Mater. 8 (2018) 1703155 doi: 10.1002/aenm.201703155
42. [42]
  M.C. Biesinger, B.P. Payne, A.P. Grosvenor, et al., Appl. Surf. Sci. 257 (2011) 2717-2730 doi: 10.1016/j.apsusc.2010.10.051
1. [1]
  Xiping Dong , Xuan Wang , Zhixiu Lu , Qinhao Shi , Zhengyi Yang , Xuan Yu , Wuliang Feng , Xingli Zou , Yang Liu , Yufeng Zhao . Construction of Cu-Zn Co-doped layered materials for sodium-ion batteries with high cycle stability. Chinese Chemical Letters, 2024, 35(5): 108605-. doi: 10.1016/j.cclet.2023.108605
2. [2]
  Huixin Chen , Chen Zhao , Hongjun Yue , Guiming Zhong , Xiang Han , Liang Yin , Ding Chen . Unraveling the reaction mechanism of high reversible capacity CuP₂/C anode with native oxidation PO_x component for sodium-ion batteries. Chinese Chemical Letters, 2025, 36(1): 109650-. doi: 10.1016/j.cclet.2024.109650
3. [3]
  Ruofan Yin , Zhaoxin Guo , Rui Liu , Xian-Sen Tao . Ultrafast synthesis of Na₃V₂(PO₄)₃ cathode for high performance sodium-ion batteries. Chinese Chemical Letters, 2025, 36(2): 109643-. doi: 10.1016/j.cclet.2024.109643
4. [4]
  Zhijia Zhang , Shihao Sun , Yuefang Chen , Yanhao Wei , Mengmeng Zhang , Chunsheng Li , Yan Sun , Shaofei Zhang , Yong Jiang . Epitaxial growth of Cu_2-xSe on Cu (220) crystal plane as high property anode for sodium storage. Chinese Chemical Letters, 2024, 35(7): 108922-. doi: 10.1016/j.cclet.2023.108922
5. [5]
  Jiaojiao Liang , Youming Peng , Zhichao Xu , Yufei Wang , Menglong Liu , Xin Liu , Di Huang , Yuehua Wei , Zengxi Wei . Boron/phosphorus co-doped nitrogen-rich carbon nanofiber with flexible anode for robust sodium-ion battery. Chinese Chemical Letters, 2025, 36(1): 110452-. doi: 10.1016/j.cclet.2024.110452
6. [6]
  Guangchang Yang , Shenglong Yang , Jinlian Yu , Yishun Xie , Chunlei Tan , Feiyan Lai , Qianqian Jin , Hongqiang Wang , Xiaohui Zhang . Regulating local chemical environment in O3-type layered sodium oxides by dual-site Mg²⁺/B³⁺ substitution achieves durable and high-rate cathode. Chinese Chemical Letters, 2024, 35(9): 109722-. doi: 10.1016/j.cclet.2024.109722
7. [7]
  Mingxin Song , Lijing Xie , Fangyuan Su , Zonglin Yi , Quangui Guo , Cheng-Meng Chen . New insights into the effect of hard carbons microstructure on the diffusion of sodium ions into closed pores. Chinese Chemical Letters, 2024, 35(6): 109266-. doi: 10.1016/j.cclet.2023.109266
8. [8]
  Yan-Jiang Li , Shu-Lei Chou , Yao Xiao . Detecting dynamic structural evolution based on in-situ high-energy X-ray diffraction technology for sodium layered oxide cathodes. Chinese Chemical Letters, 2025, 36(2): 110389-. doi: 10.1016/j.cclet.2024.110389
9. [9]
  Shengyu Zhao , Qinhao Shi , Wuliang Feng , Yang Liu , Xinxin Yang , Xingli Zou , Xionggang Lu , Yufeng Zhao . Suppression of multistep phase transitions of O3-type cathode for sodium-ion batteries. Chinese Chemical Letters, 2024, 35(5): 108606-. doi: 10.1016/j.cclet.2023.108606
10. [10]
  Shengyu Zhao , Xuan Yu , Yufeng Zhao . A water-stable high-voltage P3-type cathode for sodium-ion batteries. Chinese Chemical Letters, 2024, 35(9): 109933-. doi: 10.1016/j.cclet.2024.109933
11. [11]
  Haiying Lu , Weijie Li . The electrolyte solvation and interfacial chemistry for anode-free sodium metal batteries. Chinese Journal of Structural Chemistry, 2024, 43(11): 100334-100334. doi: 10.1016/j.cjsc.2024.100334
12. [12]
  Fanjun Kong , Yixin Ge , Shi Tao , Zhengqiu Yuan , Chen Lu , Zhida Han , Lianghao Yu , Bin Qian . Engineering and understanding SnS_0.5Se_0.5@N/S/Se triple-doped carbon nanofibers for enhanced sodium-ion batteries. Chinese Chemical Letters, 2024, 35(4): 108552-. doi: 10.1016/j.cclet.2023.108552
13. [13]
  Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na_3.5-xMn_0.5V_1.5-xZr_x(PO₄)₃/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-. doi: 10.3866/PKU.WHXB202407023
14. [14]
  Tao Long , Peng Chen , Bin Feng , Caili Yang , Kairong Wang , Yulei Wang , Can Chen , Yaping Wang , Ruotong Li , Meng Wu , Minhuan Lan , Wei Kong Pang , Jian-Fang Wu , Yuan-Li Ding . Reinforced concrete-like Na_3.5V_1.5Mn_0.5(PO₄)₃@graphene hybrids with hierarchical porosity as durable and high-rate sodium-ion battery cathode. Chinese Chemical Letters, 2024, 35(4): 109267-. doi: 10.1016/j.cclet.2023.109267
15. [15]
  Jun-Ming Cao , Kai-Yang Zhang , Jia-Lin Yang , Zhen-Yi Gu , Xing-Long Wu . Differential bonding behaviors of sodium/potassium-ion storage in sawdust waste carbon derivatives. Chinese Chemical Letters, 2024, 35(4): 109304-. doi: 10.1016/j.cclet.2023.109304
16. [16]
  Mianying Huang , Zhiguang Xu , Xiaoming Lin . Mechanistic analysis of Co2VO4/X (X = Ni, C) heterostructures as anode materials of lithium-ion batteries. Chinese Journal of Structural Chemistry, 2024, 43(7): 100309-100309. doi: 10.1016/j.cjsc.2023.100309
17. [17]
  Changyuan Bao , Yunpeng Jiang , Haoyin Zhong , Huaizheng Ren , Junhui Wang , Binbin Liu , Qi Zhao , Fan Jin , Yan Meng Chong , Jianguo Sun , Fei Wang , Bo Wang , Ximeng Liu , Dianlong Wang , John Wang . Synergizing 3D-printed structure and sodiophilic interface enables highly efficient sodium metal anodes. Chinese Chemical Letters, 2024, 35(11): 109353-. doi: 10.1016/j.cclet.2023.109353
18. [18]
  Binyang Qin , Mengqi Wang , Shimei Wu , Yining Li , Chilin Liu , Yufei Zhang , Haosen Fan . Carbon dots confined nanosheets assembled NiCo₂S₄@CDs cross-stacked architecture for enhanced sodium ion storage. Chinese Chemical Letters, 2024, 35(7): 108921-. doi: 10.1016/j.cclet.2023.108921
19. [19]
  Xueyu Lin , Ruiqi Wang , Wujie Dong , Fuqiang Huang . 高性能双金属氧化物负极的理性设计及储锂特性. Acta Physico-Chimica Sinica, 2025, 41(3): 2311005-. doi: 10.3866/PKU.WHXB202311005
20. [20]
  Ze Liu , Xiaochen Zhang , Jinlong Luo , Yingjian Yu . Application of metal-organic frameworks to the anode interface in metal batteries. Chinese Chemical Letters, 2024, 35(11): 109500-. doi: 10.1016/j.cclet.2024.109500

Get Citation

PDF

XML

Metrics

PDF Downloads(10)
Abstract views(691)
HTML views(69)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

FeBO3 as a low cost and high-performance anode material for sodium-ion batteries

Metrics

通讯作者: 陈斌, bchen63@163.com

FeBO₃ as a low cost and high-performance anode material for sodium-ion batteries