Citation: Fan Wu, Liqiong Li, Yanxi Tan, El-Sayed M. El-Sayed, Daqiang Yuan. The competitive and synergistic effect between adsorption enthalpy and capacity in D₂/H₂ separation of M₂(m-dobdc) frameworks[J]. Chinese Chemical Letters, ;2021, 32(11): 3562-3565. doi: 10.1016/j.cclet.2021.02.063 shu

The competitive and synergistic effect between adsorption enthalpy and capacity in D₂/H₂ separation of M₂(m-dobdc) frameworks

Fan Wu ^{a, b} ,
Liqiong Li ^{a, c} ,
Yanxi Tan ^a ,
El-Sayed M. El-Sayed ^{a, b, d} ,
Daqiang Yuan ^{a, *,}

a.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
b.
University of the Chinese Academy of Sciences, Beijing 100049, China
c.
College of Chemistry, Fuzhou University, Fuzhou 350108, China
d.
Chemical Refining Laboratory, Refining Department, Egyptian Petroleum Research Institute, Nasr City, Cairo 11727, Egypt

ydq@fjirsm.ac.cn

Received Date: 17 January 2021
Revised Date: 19 February 2021
Accepted Date: 25 February 2021
Available Online: 27 February 2021

Figures(4)

Hydrogen isotope separation is a challenging task due to their similar properties. Herein, based on the chemical affinity quantum sieve (CAQS) effect, the D₂/H₂ separation performance of M₂(m-dobdc) (M = Co, Ni, Mg, Mn; m-dobdc⁴⁻ = 4,6-dioxido-1,3-benzenedicarboxylate), a series of honeycomb-shaped MOFs with high stability and abundant open metal sites, are studied by gases sorption and breakthrough experiments, in which two critical factors, gas uptake and adsorption enthalpy, are taken into consideration. Among these MOFs, Co₂(m-dobdc) exhibits the longest D₂ retention time of 180 min/g (H₂/D₂/Ne: 1/1/98) at 77 K because of its second-highest adsorption enthalpy (10.7 kJ/mol for H₂ and 11.8 kJ/mol for D₂) and the best sorption capacity (5.22 mmol/g for H₂ and 5.49 mmol/g for D₂) under low pressure of 1 kPa and 77 K), which make it a promising material for industrial hydrogen isotope separation. Moreover, the results indicate that H₂ and D₂ capacities under low pressure (about 1 kPa) dominate the final D₂/H₂ separation property of MOFs.
- Breakthrough experiment,
- Open metal sites,
- Hydrogen isotope separation,
- Sorption and separation,
- Chemical affinity quantum sieve
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The competitive and synergistic effect between adsorption enthalpy and capacity in D2/H2 separation of M2(m-dobdc) frameworks

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通讯作者: 陈斌, bchen63@163.com

The competitive and synergistic effect between adsorption enthalpy and capacity in D₂/H₂ separation of M₂(m-dobdc) frameworks