Citation: Jie Liu, Miao Ben, Andeng Liu, Jianwen Liu, Shiquan Wang, Jiujun Zhang. Highly elastic cobweb-like SiO/CNF composites with reconstructed heterostructure for high-efficient lithium storage[J]. Chinese Chemical Letters, ;2021, 32(9): 2914-2918. doi: 10.1016/j.cclet.2021.02.051 shu

Highly elastic cobweb-like SiO/CNF composites with reconstructed heterostructure for high-efficient lithium storage

Jie Liu ^{a, 1} ,
Miao Ben ^{a, 1} ,
Andeng Liu ^a ,
Jianwen Liu ^{a, *,} ,
Shiquan Wang ^{a, *,} ,
Jiujun Zhang ^{b, *,}

a.
Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials & Ministry of Educational Key Laboratory for the Synthesis and Application of Organic Functional Molecules & College of Chemistry and Chemical Engineering, Hubei University, Wuhan 430062, China
b.
Institute for Sustainable Energy, College of Science, Shanghai University, Shanghai 200444, China

jianwen@hubu.edu.cn

wsqhao@126.com

jiujun.zhang@i.shu.edu.cn

Received Date: 22 December 2020
Revised Date: 9 January 2021
Accepted Date: 24 February 2021
Available Online: 26 February 2021

Figures(4)

The silicon-based materials are promising candidates for lithium-ion batteries owing to their high energy density. However, achieving long lifespan under realistic conditions remains a challenge because of the volume expansion and low conductivity. In this work, the highly elastic cobweb-like composite materials consisted by SiO and nanofibers are designed and fabricated for high-efficient lithium storage by ball-milling & ; electrostatic spinning method. The reconstructed heterostructure and highly elastic nanofibers can simultaneously increase the conductivity and inhibit the "expansion effect" of silicon-based materials. The constructed electrode of n-SiO/CNF delivers an initial capacity of 1700 mAh/g, and maintains the capacities over 1000 mAh/g after 100 cycles at the current density of 500 mA/g. Meanwhile, this electrode can give an initial coulombic efficiency over 85% and maintains at 98% in the following charge/discharge processes. Furthermore, it exhibits efficient long-term electrochemical performance, maintaining the capacity at about 1000 mAh/g at a high current density of 1000 mA/g after 1000 cycles. This work could provide a promising strategy for enhancing the performance of silicon-based composite materials for practical application in lithium-ion batteries.
- Lithium ion batteries,
- Silicon-based materials,
- SiO/CNF composites,
- Highly elastic composites,
- Reconstructed heterostructure
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