Citation: Hong-Kai Li, Hai-Lin Ye, Xiao-Xue Zhao, Xiao-Long Sun, Qian-Qian Zhu, Zhang-Ye Han, Rongrong Yuan, Hongming He. Artful union of a zirconium-porphyrin MOF/GO composite for fabricating an aptamer-based electrochemical sensor with superb detecting performance[J]. Chinese Chemical Letters, ;2021, 32(9): 2851-2855. doi: 10.1016/j.cclet.2021.02.042 shu

Artful union of a zirconium-porphyrin MOF/GO composite for fabricating an aptamer-based electrochemical sensor with superb detecting performance

a.
Tianjin Key Laboratory of Structure and Performance for Functional Molecules, College of Chemistry, Tianjin Normal University, Tianjin 300387, China
b.
Department of Materials Science and Engineering, Jilin Jianzhu University, Changchun 130118, China

hehongminghz@163.com

hxxyhhm@tjnu.edu.cn

Received Date: 1 December 2020
Revised Date: 22 December 2020
Accepted Date: 18 February 2021
Available Online: 22 February 2021

Figures(5)

More and more attentions have been focused on design and synthesis of novel metal-organic framework/graphene oxide (MOF/GO) composites with unique performance. Zirconium-porphyrin MOF (PCN-222) is in-situ synthesis with the existence of GO with −COOH group to artfully fabricate a PCN-222/GO composite. This composite can be employed as functional material to modify the working electrode. Thanks to excellent electrical conductivity of GO, abundant mesoporous channels and numerous Zr(Ⅳ) metal sites of PCN-222, this composite can immobilize a large amount of aptamer through strong π-π stacking interaction and high affinity between phosphate group of aptamer and Zr(Ⅳ) site of PCN-222 simultaneously. Hence, an ultra-sensitive electrochemical aptasensor based on PCN-222/GO composite can quantificationally detect trace chloramphenicol with limit of detection of 7.04 pg/mL (21.79 pmol/L) from 0.01 ng/mL to 50 ng/mL by electrochemical impedance spectroscopy even in real samples. Meanwhile, this fabricated aptasensor reveals good repeatability, outstanding selectivity and preferable long-term storage. This research provides a useful approach to construct MOF/GO composites for fabricating electrochemical aptasensors in the electrochemical detection field.
- PCN-222/GO composite,
- Aptamer,
- Electrochemical aptasensor,
- Chloramphenicol,
- Electrochemical impedance spectroscopy
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