Citation: Youya Yu, Peizhi Huang, Yuzhen Wang, Zhixu Zhang, Tie Zhang, Yi Zhang, Dawei Fu. X-site doping in ABX₃ triggers phase transition and higher T_c of the dielectric switch in perovskite[J]. Chinese Chemical Letters, ;2021, 32(11): 3558-3561. doi: 10.1016/j.cclet.2021.02.040 shu

X-site doping in ABX₃ triggers phase transition and higher T_c of the dielectric switch in perovskite

Youya Yu ^{a, b} ,
Peizhi Huang ^b ,
Yuzhen Wang ^{a, b} ,
Zhixu Zhang ^a ,
Tie Zhang ^a ,
Yi Zhang ^{a, *,} ,
Dawei Fu ^{a, b, *,}

a.
Ordered Matter Science Research Center, Jiangsu Key Laboratory for Science andApplications of Molecular Ferroelectrics, Southeast University, Nanjing 211189, China
b.
Institute for Science and Applications of Molecular Ferroelectrics, Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Zhejiang Normal University, Jinhua 321004, China

yizhang1980@seu.edu.cn

dawei@seu.edu.cn

Received Date: 29 January 2021
Revised Date: 18 February 2021
Accepted Date: 18 February 2021
Available Online: 22 February 2021

Figures(4)

Material stability is always the key factor for applied materials especially the working environment that requires higher temperature sensitivity or temperature fluctuation range. In which, the stimulus-response perovskite materials are just sensitive to stability to ensure the accuracy and stability of the signals, in the applied devices of batteries and memory storage devices and so on. However, it is still a tremendous challenge to improve the stability of perovskite materials, and maintain reliability in the devices. Here, a novel ABX₂X'₁ (X-site doping in an ABX₃) compound [CEMP]-[CdBr₂(SCN)] (1, CEMP = 1-(2-chloro-ethyl)-1-methyl-piperidine) with remarkable high-temperature reversible dielectric switching behavior was proposed. The strategy of [SCN]⁻ doping in perovskite for improving the stability was successfully achieved. Meanwhile, the steric hindrance is increased while the energy barrier is also increased by replacing hydrogen with flexible groups, which leads to a high-temperature reversible phase transition. The new finding provides a new direction to enrich new applications and design ideas of perovskite materials. Especially the X-site strategy of doping or substitution in the ABX₃, it will promote ingenious and perfect experimental results in material synthesis and performance improvement by chemistry disciplines.
- Dielectric switch,
- X-site doping,
- High-temperature,
- Phase transition,
- Molecule design
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

X-site doping in ABX3 triggers phase transition and higher Tc of the dielectric switch in perovskite

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通讯作者: 陈斌, bchen63@163.com

X-site doping in ABX₃ triggers phase transition and higher T_c of the dielectric switch in perovskite