Citation: Siqi Zou, Qun Chen, Yang Liu, Yuting Pan, Gang Yao, Zhicheng Pan, Bo Lai. The capacity and mechanisms of various oxidants on regulating the redox function of ZVI[J]. Chinese Chemical Letters, ;2021, 32(6): 2066-2072. doi: 10.1016/j.cclet.2021.02.019 shu

The capacity and mechanisms of various oxidants on regulating the redox function of ZVI

Siqi Zou ^{a, b, 1} ,
Qun Chen ^{c, 1} ,
Yang Liu ^{a, b, f, *,} ,
Yuting Pan ^{a, b} ,
Gang Yao ^{b, d} ,
Zhicheng Pan ^f ,
Bo Lai ^{a, b, e, *,}

a.
State Key Laboratory of Hydraulics and Mountain River Engineering, College of Architecture and Environment, Sichuan University, Chengdu 610065, China
b.
Sino-German Centre for Water and Health Research, Sichuan University, Chengdu 610065, China
c.
Department of Central Transportation Center, West China Hospital, Sichuan University/West China School of Nursing, Sichuan University, Chengdu 610065, China
d.
Institute of Environmental Engineering, RWTH Aachen University, Aachen 52072, Germany
e.
Sichuan University Yinbin Park, Yibin Institute of Industrial Technology, Yibin 644044, China
f.
Laboratory of Wastewater Treatment Technology in Sichuan Province, Haitian Water Group, Chengdu 610065, China

liuyang_scu@scu.edu.cn

laibo@scu.edu.cn

Received Date: 22 November 2020
Revised Date: 6 January 2021
Accepted Date: 8 February 2021
Available Online: 11 February 2021

Figures(6)

It is well known that zero-valent iron (ZVI) could catalyze the oxidation of various oxidants to realize the rapid oxidation removal of pollutants. However, in this study, we found that the addition of different oxidants could regulate the redox function of ZVI system. In three different co-treatment systems, the effects of different oxidizers (peroxymonosulfate (PMS), persulfate (PDS), hydrogen peroxide (H₂O₂)) dosages on the ratios of oxidative degradation rate and reductive degradation rate of p-nitrophenol (PNP) were studied. The effect of the H⁺ released from oxidizers and the generated reactive oxygen species (ROS) in ZVI/PMS, ZVI/PDS, ZVI/H₂O₂ systems were detailed discussed. Especially, the contribution of generated ROS for reductive degradation of PNP was quantified in the ZVI/H₂O₂ system. Based on the results of TOC removal, UV–vis absorption spectra, and intermediates concentration curves, it was found that the degradation of PNP changed from reduction to oxidation with the increase of oxidant proportion. When the molar ratio of ZVI to oxidizer equal to 100, PNP was mainly degraded by reduction accompanied by slight oxidation. Combined with the results of SEM-EDS and XPS, it was confirmed that the enhanced degradation of PNP under the addition of oxidant was mainly related to the generated ROS, the additional H⁺, and the corrosion products of ZVI.
- Zero-valent iron,
- Oxidizer,
- Redox,
- Mechanisms,
- p-Nitrophenol
1. [1]
  G. Eichenbaum, M. Johnson, D. Kirkland, et al., Regul. Toxicol. Pharmacol. 55 (2009) 33-42. doi: 10.1016/j.yrtph.2009.05.018
2. [2]
  F. Liu, Z. Wu, D. Wang, et al., Colloids Surf. A: Physicochem. Eng. Aspects 490 (2016) 207-214. doi: 10.1016/j.colsurfa.2015.11.053
3. [3]
  J. Chen, X. Sun, L. Lin, X. Dong, Y. He, Chin. J. Chem. Eng. 25 (2017) 775-781. doi: 10.1016/j.cjche.2016.10.014
4. [4]
  X. Mei, J. Liu, Z. Guo, et al., J. Hazard. Mater. 363 (2019) 99-108. doi: 10.1016/j.jhazmat.2018.09.072
5. [5]
  J. Li, Y. Li, Z. Xiong, G. Yao, B. Lai, Chin. Chem. Lett. 30 (2019) 2139-2146. doi: 10.1016/j.cclet.2019.04.057
6. [6]
  M. Zhu, L. Zhang, S. Liu, et al., Chin. Chem. Lett. 31 (2020) 1961-1965. doi: 10.1016/j.cclet.2020.01.017
7. [7]
  P. Hu, M. Long, Appl. Catal. B: Environ. 181 (2016) 103-117. doi: 10.1016/j.apcatb.2015.07.024
8. [8]
  M.A. Oturan, J. Peiroten, P. Chartrin, A.J. Acher, Environ. Sci. Technol. 34 (2000) 3474-3479. doi: 10.1021/es990901b
9. [9]
  R.M. Cardoso, R.H.O. Montes, A.P. Lima, et al., Electrochim. Acta 176 (2015) 36-43. doi: 10.1016/j.electacta.2015.06.117
10. [10]
  D. Méndez, R. Vargas, C. Borrás, et al., Appl. Catal. B: Environ. 166-167 (2015) 529-534.
11. [11]
  N. Wang, T. Zheng, G. Zhang, P. Wang, J. Environ. Chem. Eng. 4 (2016) 762-787. doi: 10.1016/j.jece.2015.12.016
12. [12]
  G. Liu, J. Zhou, W. Zhao, Z. Ao, T. An, Chin. Chem. Lett. 31 (2020) 1966-1969. doi: 10.1016/j.cclet.2019.12.023
13. [13]
  X. Xiong, B. Sun, J. Zhang, N. Gao, J. Shen, J. Li, X. Guan, Water Res. 62 (2014) 53-62. doi: 10.1016/j.watres.2014.05.042
14. [14]
  M. Nie, C. Yan, M. Li, X. Wang, W. Bi, W. Dong, Chem. Eng. J. 279 (2015) 507-515. doi: 10.1016/j.cej.2015.05.055
15. [15]
  A. Rastogi, S.R. Al-Abed, D.D. Dionysiou, Appl. Catal. B: Environ. 85 (2009) 171-179. doi: 10.1016/j.apcatb.2008.07.010
16. [16]
  Y.R. Wang, W. Chu, J. Hazard. Mater. 186 (2011) 1455-1461.
17. [17]
  G. Ayoub, A. Ghauch, Chem. Eng. J. 256 (2014) 280-292. doi: 10.1016/j.cej.2014.07.002
18. [18]
  M. Yang, S. Zhou, Y. Zheng, K. Zheng, Chem. Indust. Eng. Prog. 31 (2012) 2093-2096.
19. [19]
  Z. Wang, RSC Adv. 7 (2017) 30941-30948. doi: 10.1039/C7RA03872K
20. [20]
  B. Lai, Z. Chen, Y. Zhou, P. Yang, J. Wang, Z. Chen, J. Hazard. Mater. 250-251 (2013) 220-228.
21. [21]
  H. Zhang, Q. Ji, L. Lai, G. Yao, B. Lai, Chin. Chem. Lett. 30 (2019) 1129-1132. doi: 10.1016/j.cclet.2019.01.025
22. [22]
  X. Zou, T. Zhou, J. Mao, X. Wu, Chem. Eng. J. 257 (2014) 36-44. doi: 10.1016/j.cej.2014.07.048
23. [23]
  H. Kusic, I. Peternel, S. Ukic, et al., Chem. Eng. J. 172 (2011) 109-121.
24. [24]
  J. Cao, L. Lai, B. Lai, et al., Chem. Eng. J. 364 (2019) 45-56. doi: 10.1016/j.cej.2019.01.113
25. [25]
  Y.H. Huang, T.C. Zhang, Water Res. 39 (2015) 1751-1760.
26. [26]
  Y. Nakatsuji, Z. Salehi, Y. Kawase, J. Environ. Manag. 152 (2015) 183-191. doi: 10.1016/j.jenvman.2015.01.012
27. [27]
  L. Tang, J. Tang, G. Zeng, et al., Appl. Surf. Sci. 333 (2015) 220-228. doi: 10.1016/j.apsusc.2015.02.025
28. [28]
  D. Zhi, Y. Lin, L. Jiang, et al., J. Environ. Manag. 260 (2020) 110-125.
29. [29]
  M.M. Bello, A.A. Abdul Raman, A. Asghar, Process Saf. Environ. Prot. 126 (2019) 119-140. doi: 10.1016/j.psep.2019.03.028
30. [30]
  L.W. Matzek, K.E. Carter, Chemosphere 151 (2016) 178-188. doi: 10.1016/j.chemosphere.2016.02.055
31. [31]
  C. Qi, X. Liu, J. Ma, et al., Chemosphere 151 (2016) 280-288. doi: 10.1016/j.chemosphere.2016.02.089
32. [32]
  J. Li, Q. Ji, B. Lai, D. Yuan, J. Taiwan Instit. Chem. Eng. 80 (2017) 686-694. doi: 10.1016/j.jtice.2017.09.002
33. [33]
  G.X. Huang, C.Y. Wang, C.W. Yang, P.C. Guo, H.Q. Yu, Environ. Sci. Technol. 51 (2017) 12611-12618. doi: 10.1021/acs.est.7b03007
34. [34]
  L. Lai, J. Yan, J. Li, B. Lai, Chem. Eng. J. 343 (2018) 676-688. doi: 10.1016/j.cej.2018.01.035
35. [35]
  M.S. Dieckmann, K.A. Gray, Water Res. 30 (1996) 1169-1183. doi: 10.1016/0043-1354(95)00240-5
36. [36]
  Z. Yang, C. Shan, W. Zhang, et al., Water Res. 106 (2016) 461-469. doi: 10.1016/j.watres.2016.10.030
37. [37]
  M. Zhu, L. Zhang, S. Liu, D. Wang, J. Zou, Chin. Chem. Lett. 31 (2020) 1961-1965. doi: 10.1016/j.cclet.2020.01.017
38. [38]
  J. Li, Q. Liu, Qq. Ji, B. Lai, Applied. Catal. B: Environ. 200 (2017) 633-646. doi: 10.1016/j.apcatb.2016.07.026
39. [39]
  Q. Ji, J. Li, Z. Xiong, B. Lai, Chemosphere 172 (2017) 10-20. doi: 10.1016/j.chemosphere.2016.12.128
40. [40]
  B. Lai, Y. Zhou, H. Qin, et al., Chem. Eng. J. 179 (2012) 1-7. doi: 10.1016/j.cej.2010.12.089
41. [41]
  M. Omran, T. Fabritius, A.M. Elmahdy, et al., Appl. Surf. Sci. 345 (2015) 127-140. doi: 10.1016/j.apsusc.2015.03.209
42. [42]
  P. Tang, C. Deng, X. Tang, S. Si, K. Xiao, Chem. Eng. J. 210 (2012) 203-211. doi: 10.1016/j.cej.2012.08.089
43. [43]
  S.H. Do, Y.J. Kwon, S.J. Bang, S.H. Kong, Chem. Eng. J. 221 (2013) 72-80. doi: 10.1016/j.cej.2013.01.097
44. [44]
  N.S. Mcintyre, D.G. Zetaruk, Anal. Chem. 49 (1977) 1521-1529. doi: 10.1021/ac50019a016
45. [45]
  A. Masic, A.T. Santos, B. Etter, K.M. Udert, K. Villez, Water Res. 85 (2015) 244-254. doi: 10.1016/j.watres.2015.08.031
46. [46]
  R.V. Siriwardane, J.M. Cook, J. Colloid Interf. Sci. 108 (1985) 414-422. doi: 10.1016/0021-9797(85)90280-2
47. [47]
  H. Cheng, W. Xu, J. Liu, et al., J. Hazard. Mater. 146 (2007) 385-392. doi: 10.1016/j.jhazmat.2006.12.038
48. [48]
  X. Guo, Z. Yang, H. Liu, et al., Sep. Purif. Technol. 146 (2015) 227-234. doi: 10.1016/j.seppur.2015.03.059
49. [49]
  X. Wei, N. Gao, C. Li, et al., Chem. Eng. J. 285 (2016) 660-670. doi: 10.1016/j.cej.2015.08.120
50. [50]
  L. Zhao, Y. Ji, D. Kong, et al., Chem. Eng. J. 303 (2016) 458-466. doi: 10.1016/j.cej.2016.06.016
51. [51]
  Y. Sun, J. Li, T. Huang, X. Guan, Water Res. 100 (2016) 277-295. doi: 10.1016/j.watres.2016.05.031
52. [52]
  X. Guo, Z. Yang, H. Dong, et al., Water Res. 88 (2016) 671-680. doi: 10.1016/j.watres.2015.10.045
53. [53]
  F. Ghanbari, M. Moradi, Chem. Eng. J. 310 (2017) 41-62. doi: 10.1016/j.cej.2016.10.064
54. [54]
  S. Zhao, H. Ma, M. Wang, et al., J. Hazard. Mater. 180 (2010) 86-90. doi: 10.1016/j.jhazmat.2010.03.076
1. [1]
  Zhongsen Wang , Lijun Qiu , Yunhua Huang , Meng Zhang , Xi Cai , Fanyu Wang , Yang Lin , Yanbiao Shi , Xiao Liu . Alcohothermal synthesis of sulfidated zero-valent iron for enhanced Cr(Ⅵ) removal. Chinese Chemical Letters, 2024, 35(7): 109195-. doi: 10.1016/j.cclet.2023.109195
2. [2]
  Zhongjie Li , Xiangyue Kong , Yuhao Liu , Huayu Qiu , Lingling Zhan , Shouchun Yin . Progress of additives for morphology control in organic photovoltaics. Chinese Chemical Letters, 2024, 35(6): 109378-. doi: 10.1016/j.cclet.2023.109378
3. [3]
  Yun-Fei Zhang , Chun-Hui Zhang , Jian-Hui Xu , Lei Li , Dan Li , Jin-Hong Fan , Jiale Gao , Xin Quan , Qi Wu , Yue Zou , Yan-Ling Liu . Enhanced degradation of florfenicol by microscale SiC/Fe: Dechlorination via hydrogenolysis. Chinese Chemical Letters, 2024, 35(7): 109385-. doi: 10.1016/j.cclet.2023.109385
4. [4]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
5. [5]
  Haitao Yin , Liang Meng , Li Li , Jiamu Xiao , Longrui Liang , Nannan Huang , Yansong Shi , Angang Zhao , Jingwen Hou . Polydopamine-modified biochar supported polylactic acid and zero-valent iron affects the functional microbial community structure for 1,1,1-trichloroethane removal in simulated groundwater. Chinese Chemical Letters, 2025, 36(1): 110313-. doi: 10.1016/j.cclet.2024.110313
6. [6]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
7. [7]
  Meijin Li , Xirong Fu , Xue Zheng , Yuhan Liu , Bao Li . The Marvel of NAD⁺: Nicotinamide Adenine Dinucleotide. University Chemistry, 2024, 39(9): 35-39. doi: 10.12461/PKU.DXHX202401027
8. [8]
  Yanan Zhou , Li Sheng , Lanlan Chen , Wenhua Zhang , Jinlong Yang . Axial coordinated iron-nitrogen-carbon as efficient electrocatalysts for hydrogen evolution and oxygen redox reactions. Chinese Chemical Letters, 2025, 36(1): 109588-. doi: 10.1016/j.cclet.2024.109588
9. [9]
  Huipeng Zhao , Xiaoqiang Du . Polyoxometalates as the redox anolyte for efficient conversion of biomass to formic acid. Chinese Journal of Structural Chemistry, 2024, 43(2): 100246-100246. doi: 10.1016/j.cjsc.2024.100246
10. [10]
  Mengjun Sun , Zhi Wang , Jvhui Jiang , Xiaobing Wang , Chuang Yu . Gelation mechanisms of gel polymer electrolytes for zinc-based batteries. Chinese Chemical Letters, 2024, 35(5): 109393-. doi: 10.1016/j.cclet.2023.109393
11. [11]
  Yinglan Yu , Sajid Hussain , Jianping Qi , Lei Luo , Xuemei Zhang . Mechanisms and applications: Cargos transport to basolateral membranes in polarized epithelial cells. Chinese Chemical Letters, 2024, 35(12): 109673-. doi: 10.1016/j.cclet.2024.109673
12. [12]
  Yuanzhe Lu , Yuanqin Zhu , Linfeng Zhong , Dingshan Yu . Long-lifespan aqueous alkaline and acidic batteries enabled by redox conjugated covalent organic polymer anodes. Chinese Journal of Structural Chemistry, 2024, 43(3): 100249-100249. doi: 10.1016/j.cjsc.2024.100249
13. [13]
  Yiran Tao , Chunlei Dai , Zhaoxiang Xie , Xinru You , Kaiwen Li , Jun Wu , Hai Huang . Redox responsive polymeric nanoparticles enhance the efficacy of cyclin dependent kinase 7 inhibitor for enhanced treatment of prostate cancer. Chinese Chemical Letters, 2024, 35(8): 109170-. doi: 10.1016/j.cclet.2023.109170
14. [14]
  Jing Wang , Zenghui Li , Xiaoyang Liu , Bochao Su , Honghong Gong , Chao Feng , Guoping Li , Gang He , Bin Rao . Fine-tuning redox ability of arylene-bridged bis(benzimidazolium) for electrochromism and visible-light photocatalysis. Chinese Chemical Letters, 2024, 35(9): 109473-. doi: 10.1016/j.cclet.2023.109473
15. [15]
  Hao WANG , Kun TANG , Jiangyang SHAO , Kezhi WANG , Yuwu ZHONG . Electro-copolymerized film of ruthenium catalyst and redox mediator for electrocatalytic water oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2193-2202. doi: 10.11862/CJIC.20240176
16. [16]
  Jinlong Li , Ruixin Li , Jiahui Liu , Ji-Quan Liu , Jia Xu , Xianglin Zhou , Yefan Zhang , Kairui Wang , Lin Lei , Gang Xie , Fengmei Wang , Ying Yang , Liping Cao . A TOC- and deposition-free electrochromic window driven by redox flow battery. Chinese Chemical Letters, 2024, 35(12): 110355-. doi: 10.1016/j.cclet.2024.110355
17. [17]
  Linjing Li , Wenlai Xu , Jianyong Ning , Yaping Zhong , Chuyue Zhang , Jiane Zuo , Zhicheng Pan . Revealing the intrinsic mechanisms for accelerating nitrogen removal efficiency in the Anammox reactor by adding Fe(II) at low temperature. Chinese Chemical Letters, 2024, 35(8): 109243-. doi: 10.1016/j.cclet.2023.109243
18. [18]
  Chunxiu Yu , Zelin Wu , Hongle Shi , Lingyun Gu , Kexin Chen , Chuan-Shu He , Yang Liu , Heng Zhang , Peng Zhou , Zhaokun Xiong , Bo Lai . Insights into the electron transfer mechanisms of peroxydisulfate activation by modified metal-free acetylene black for degradation of sulfisoxazole. Chinese Chemical Letters, 2024, 35(8): 109334-. doi: 10.1016/j.cclet.2023.109334
19. [19]
  Xin Lu , Haoran Sun , Xiaomeng Li , Chunrui Li , Jinfeng Wang , Dandan Zhou . C14-HSL limits the mycelial morphology of pathogen Trichosporon cells but enhances their aggregation: Mechanisms and implications. Chinese Chemical Letters, 2024, 35(6): 108936-. doi: 10.1016/j.cclet.2023.108936
20. [20]
  Shili Wang , Mamitiana Roger Razanajatovo , Xuedong Du , Shunli Wan , Xin He , Qiuming Peng , Qingrui Zhang . Recent advances on decomplexation mechanisms of heavy metal complexes in persulfate-based advanced oxidation processes. Chinese Chemical Letters, 2024, 35(6): 109140-. doi: 10.1016/j.cclet.2023.109140

Get Citation

PDF

XML

Metrics

PDF Downloads(8)
Abstract views(603)
HTML views(70)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142