Citation: Mei-Hua Shen, Ting-Biao Wan, Xiu-Rong Huang, Yan Li, Dan-Hua Qian, Hua-Dong Xu, Defeng Xu. Copper catalyzed borylative cyclization of 3-arylallyl carbamoyl chloride with B₂pin₂: stereoselective synthesis of cis-2-aryl-3-boryl-γ-lactams[J]. Chinese Chemical Letters, ;2021, 32(7): 2297-2300. doi: 10.1016/j.cclet.2021.02.016 shu

Copper catalyzed borylative cyclization of 3-arylallyl carbamoyl chloride with B₂pin₂: stereoselective synthesis of cis-2-aryl-3-boryl-γ-lactams

Jiangsu Key Laboratory of Advanced Catalytic Materials & Technology, School of Pharmacy, Changzhou University, Changzhou 213164, China

shenmh@cczu.edu.cn

markxu@cczu.edu.cn

Received Date: 28 October 2020
Revised Date: 3 February 2021
Accepted Date: 8 February 2021
Available Online: 12 February 2021

Figures(7)

Borylative cyclization of E-3-arylallyl carbamoyl chlorides is achieved through copper catalyzed intramolecular carboboration with B₂pin₂. 2-Aryl-3-boryl-γ-lactams are formed with exclusive cis-diastereoselectivity. CuBr-Dppp combination gives the best outcomes. The substrate scope is profiled.
- Carboboration,
- Borylative cyclization,
- Copper catalysis,
- Allyl carbamoyl chloride,
- Borocupration,
- γ-lactam
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沈阳化工大学材料科学与工程学院沈阳 110142

Copper catalyzed borylative cyclization of 3-arylallyl carbamoyl chloride with B2pin2: stereoselective synthesis of cis-2-aryl-3-boryl-γ-lactams

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通讯作者: 陈斌, bchen63@163.com

Copper catalyzed borylative cyclization of 3-arylallyl carbamoyl chloride with B₂pin₂: stereoselective synthesis of cis-2-aryl-3-boryl-γ-lactams