Citation: Wei Xiao, Xinhua Wang, Ruixiu Liu, Jie Wu. Quinuclidine and its derivatives as hydrogen-atom-transfer catalysts in photoinduced reactions[J]. Chinese Chemical Letters, ;2021, 32(6): 1847-1856. doi: 10.1016/j.cclet.2021.02.009 shu

Quinuclidine and its derivatives as hydrogen-atom-transfer catalysts in photoinduced reactions

Wei Xiao ^a ,
Xinhua Wang ^b ,
Ruixiu Liu ^a ,
Jie Wu ^{a, c, d, *,}

a.
School of Pharmaceutical and Materials Engineering & Institute for Advanced Studies, Taizhou University, Taizhou 318000, China
b.
Key Laboratory of Functional Small Organic Molecules, Ministry of Education, and College of Chemistry & Chemical Engineering, Jiangxi Normal University, Nanchang 330022, China
c.
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China
d.
School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang 453007, China

jie_wu@fudan.edu.cn

Received Date: 15 December 2020
Revised Date: 2 February 2021
Accepted Date: 2 February 2021
Available Online: 9 February 2021

Figures(26)

Hydrogen-atom-transfer (HAT) is an efficient way for direct C—H functionalization of inert C—H bonds, therefore it has attracted great interests in recent years. So far, various HAT catalysts have been developed. Among them, quinuclidine and its derivatives show different characters toward other HAT catalysts as they tend to abstract electron-rich and hydridic hydrogens in the presence of weak and neutral C—H bonds. These features enable direct C—H functionalization of compounds with various groups which are unable or difficult by other methods. This review summarizes recent advance of photoinduced reactions with quinuclidine and its derivatives as HAT catalysts and exhibits powerful synthetic potential by using quinuclidine and its derivatives as HAT catalysts.
- Quinuclidine,
- Hydrogen-atom-transfer,
- Photoinduced reaction,
- Electron-rich hydrogens,
- C—H functionalization
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