Citation: Yucui Bian, Yongpan Gu, Xiaofei Zhang, Haijun Chen, Zhongjun Li. Engineering BiOBr_xI_1-x solid solutions with enhanced singlet oxygen production for photocatalytic benzylic C-H bond activation mediated by N-hydroxyl compounds[J]. Chinese Chemical Letters, ;2021, 32(9): 2837-2840. doi: 10.1016/j.cclet.2021.02.006 shu

Engineering BiOBr_xI_1-x solid solutions with enhanced singlet oxygen production for photocatalytic benzylic C-H bond activation mediated by N-hydroxyl compounds

Green Catalysis Center, College of Chemistry, Zhengzhou University, Zhengzhou 450001, China

chenhaijun@zzu.edu.cn

lizhongjun@zzu.edu.cn

Received Date: 9 December 2020
Revised Date: 25 December 2020
Accepted Date: 1 February 2021
Available Online: 4 February 2021

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The aerobic, selective oxidation of hydrocarbons via C-H bond activation is still a challenge. This work shows the achievement of the room temperature visible light driven photocatalytic activation of benzylic C-H bonds with N-hydroxysuccinimide over BiOBr_xI_1-x (0 ≤ x ≤ 1) solid solutions, whose valance bands were engineered through varying the ratio of bromide to iodide. The optimal BiOBr_0.85I_0.15 catalyst exhibited over 98% conversion ratio of ethylbenzene, which was about 3.9 and 8.9 times that of pure BiOBr and BiOI, respectively. The excellent photocatalytic activity of BiOBr_0.85I_0.15 solid solution can be ascribed to the orbital hybridization of the valence band containing both Br 4p and I 5p orbitals, which could promote photo-induced charge carrier separation and improve the generation of singlet oxygen. This work shed some light on the rational design of photocatalysts for targeted organic transformation.
- BiOBr_xI_1-x solid solutions,
- Ethylbenzene oxidation,
- N-Hydroxysuccinimide,
- Photocatalysis,
- Singlet oxygen
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沈阳化工大学材料科学与工程学院沈阳 110142

Engineering BiOBrxI1-x solid solutions with enhanced singlet oxygen production for photocatalytic benzylic C-H bond activation mediated by N-hydroxyl compounds

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通讯作者: 陈斌, bchen63@163.com

Engineering BiOBr_xI_1-x solid solutions with enhanced singlet oxygen production for photocatalytic benzylic C-H bond activation mediated by N-hydroxyl compounds