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Citation: Meng-Meng Xu, Lu-Yao Kou, Xiao-Guang Bao, Xiao-Ping Xu, Shun-Jun Ji. A radical addition and cyclization relay promoted by Mn(OAc)3·2H2O: Synthesis of 1, 2-oxaphospholoindoles and mechanistic study[J]. Chinese Chemical Letters, ;2021, 32(6): 1915-1919. doi: 10.1016/j.cclet.2021.02.001 shu

A radical addition and cyclization relay promoted by Mn(OAc)3·2H2O: Synthesis of 1, 2-oxaphospholoindoles and mechanistic study

  • Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science & Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou 215123, China

    * Corresponding authors.
    E-mail addresses: xgbao@suda.edu.cn (X.-G. Bao), xuxp@suda.edu.cn(X.-P. Xu), shunjun@suda.edu.cn (S.-J. Ji).
  • Received Date: 30 November 2020
    Revised Date: 1 February 2021
    Accepted Date: 2 February 2021
    Available Online: 4 February 2021

Figures(6)

  • Novel and efficient Mn(OAc)3·2H2O promoted radical addition-[4+1] cyclization relay of 3-indolymethanols and phosphites was disclosed, which afforded 1, 2-oxaphospholoindole derivatives in moderate to good yields. Based on the experimental and computational studies, a mechanism involving radical addition and intramolecular cyclization cascade was proposed.
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