Citation: Tun Wu, Zhiyuan Jiang, Xiaobo Xue, Shi-Cheng Wang, Mingzhao Chen, Jun Wang, Haisheng Liu, Jun Yan, Yi-Tsu Chan, Pingshan Wang. Molecular hexagram and octagram: Position determined 3D metallo-supermolecules and concentration-induced transformation[J]. Chinese Chemical Letters, ;2021, 32(6): 1911-1914. doi: 10.1016/j.cclet.2021.01.052 shu

Molecular hexagram and octagram: Position determined 3D metallo-supermolecules and concentration-induced transformation

Tun Wu ^{a, 1} ,
Zhiyuan Jiang ^{b, 1} ,
Xiaobo Xue ^b ,
Shi-Cheng Wang ^c ,
Mingzhao Chen ^a ,
Jun Wang ^b ,
Haisheng Liu ^b ,
Jun Yan ^b ,
Yi-Tsu Chan ^c ,
Pingshan Wang ^{a, b, *,}

a.
Institute of Environmental Research at Greater Bay Area, Key Laboratory for Water Quality and Conservation of the Pearl River Delta, Ministry of Education, Guangzhou University, Guangzhou 510006, China
b.
Department of Organic and Polymer Chemistry, College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China
c.
Department of Chemistry, National Taiwan University, Taipei 10617

chemwps@csu.edu.cn

Received Date: 24 July 2020
Revised Date: 23 January 2021
Accepted Date: 31 January 2021
Available Online: 3 February 2021

Figures(4)

The reaction of a metallo-organic ligand (LA) in which two "V"-shaped bisterpyridines attaching to meta-position of "X"-shaped tetraterpyridine via < tpy-Ru²⁺-tpy > connectivity and Zn²⁺ ions gave rise to 3D supramolecular architectures: octagram (Zn₈LA₄). However, a position varied ligand (LB) in which two "V"-shaped bisterpyridines locating at the ortho-position of "X"-shaped tetraterpyridine afforded a different 3D hexagram (Zn₆LB₃). Full characterizations included NMR (¹H, ¹³C, 2D COSY, NOESY and DOSY), ESI-MS, TWIM-MS, TEM and AFM. The resulted structures were directly determined by the position of two "V"-shaped bisterpyridines attaching to "X"-shaped tetraterpyridine.
- Self-assembly,
- Terpyridine,
- Supramolecular transformation,
- Metal-organic ligand,
- Metalla-cage
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