Citation: Haibo He, Gang Wang, Shengchao Chai, Xiang Li, Liang Zhai, Lixin Wu, Haolong Li. Self-assembled lamellar nanochannels in polyoxometalate-polymer nanocomposites for proton conduction[J]. Chinese Chemical Letters, ;2021, 32(6): 2013-2016. doi: 10.1016/j.cclet.2021.01.051 shu

Self-assembled lamellar nanochannels in polyoxometalate-polymer nanocomposites for proton conduction

State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, China

hl_li@jlu.edu.cn

Received Date: 21 December 2020
Revised Date: 27 January 2021
Accepted Date: 31 January 2021
Available Online: 3 February 2021

Figures(4)

The construction of nanostructured ion-transport channels is highly desirable in the design of advanced electrolyte materials, as it can enhance ion conductivity by offering short ion-transport pathways. In this work, we present a supramolecular strategy to fabricate a nanocomposite electrolyte containing highly ordered lamellar proton-conducting nanochannels, by the electrostatic self-assembly of a polyoxometalate H₃PW₁₂O₄₀ (PW) and a comb copolymer poly(4-methlstyrene)-graft-poly(N-vinyl pyrrolidone). PW can effectively regulate the self-assembling order of polymer moieties to form a large-range lamellar structure, meanwhile, introducing protons into the nanoscale lamellar domains to build proton transport channels. Moreover, the rigid PW clusters contribute a remarkable mechanical reinforcement to the nanocomposites. The lamellar nanocomposite exhibits a conductivity of 4.3×10^-4 S/cm and a storage modulus of 1.1×10⁷ Pa at room temperature. This study provides a new strategy to construct nanostructured ion-conductive pathways in electrolyte materials.
- Self-assembly,
- Lamellar nanochannels,
- Nanocomposite electrolytes,
- Comb copolymers,
- Polyoxometalates
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