Citation: Xuepeng Ni, Yang Jiang, Haoyu Chen, Kunming Li, Huifang Chen, Qilin Wu, Anqi Ju. Fabrication of 3D ordered needle-like polyaniline@hollow carbon nanofibers composites for flexible supercapacitors[J]. Chinese Chemical Letters, ;2021, 32(8): 2448-2452. doi: 10.1016/j.cclet.2021.01.043 shu

Fabrication of 3D ordered needle-like polyaniline@hollow carbon nanofibers composites for flexible supercapacitors

Xuepeng Ni ^a ,
Yang Jiang ^c ,
Haoyu Chen ^a ,
Kunming Li ^a ,
Huifang Chen ^{a, b} ,
Qilin Wu ^{a, b} ,
Anqi Ju ^{a, b, *,}

a.
College of Materials Science and Engineering & State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donghua University, Shanghai 201620, China
b.
Key Laboratory of High-Performance Fibers & Products, Ministry of Education, Donghua University, Shanghai 201620, China
c.
Zhejiang Provincial Key Laboratory of Yarn Material Forming and Composite Processing Technology, Jiaxing University, Jiaxing 314001, China

anqiju@dhu.edu.cn

Received Date: 2 December 2020
Revised Date: 20 January 2021
Accepted Date: 22 January 2021
Available Online: 27 January 2021

Figures(4)

Carbon nanofiber-based supercapacitors have broad prospects in powering wearable electronics owing to their high specific capacity, fast charge/discharge process, along with long-cycling life. Herein, a poly(acrylonitrile-co-β-methylhydrogen itaconate) copolymer was prepared and used to synthesize flexible hollow carbon nanofibers (HCNFs) via an electrospinning method without breaking after multiple bending. Subsequently, the inner and outer surfaces of HCNFs were evenly covered with ordered needle-like polyaniline (PANI) through in-situ polymerization methods to obtain three-dimensional flexible HCNFs/PANI composites, which exhibited a high capacity 1196.7 F/g at 1 A/g and good cycling stability (90.1% retention at 5 A/g after 3000 cycles). The symmetrical supercapacitor based on the HCNFs/PANI composites also delivered an outstanding electrochemical performance with high energy/power density (60.28 Wh/kg at 1000 W/kg) and superior cycling durability (90% capacitance retention after at 5 A/g 3000 cycles), which confirmed that the HCNFs/PANI composites had a wide application potential in flexible energy storage devices.
- Flexible,
- Polyaniline,
- Electrospinning,
- Hollow carbon nanofibers,
- Supercapacitors
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