Citation: Xixi Zhang, Guangmeng Qu, Zonghua Wang, Guotao Xiang, Shuhua Hao, Xiaoke Wang, Xijin Xu, Wenxuan Ma, Gang Zhao. Hollow polyhedron structure of amorphous Ni-Co-S/Co(OH)₂ for high performance supercapacitors[J]. Chinese Chemical Letters, ;2021, 32(8): 2453-2458. doi: 10.1016/j.cclet.2021.01.042 shu

Hollow polyhedron structure of amorphous Ni-Co-S/Co(OH)₂ for high performance supercapacitors

School of Physics and Technology, University of Jinan, Ji'nan 250022, China

sps_xuxj@ujn.edu.cn

sps_zhaog@ujn.edu.cn

Received Date: 19 December 2020
Revised Date: 17 January 2021
Accepted Date: 19 January 2021
Available Online: 27 January 2021

Figures(4)

In power storage technology, ion exchange is widely used to modify the electronic structures of electrode materials to stimulate their electrochemical properties. Here, we proposed a multistep ion exchange (cation exchange and anion exchange) strategy to synthesize amorphous Ni-Co-S and β-Co(OH)₂ hybrid nanomaterials with a hollow polyhedron structures. The synergistic effects of different components and the remarkable superiorities of hollow structure endow Ni-Co-S/Co(OH)₂ electrode with outstanding electrochemical performance, including ultra-high specific capacity (1440.0 C/g at 1 A/g), superior capacitance retention rate (79.1% retention at 20 A/g) and long operating lifespan (81.4% retention after 5000 cycles). Moreover, the corresponding hybrid supercapacitor enjoys a high energy density of 58.4 Wh/kg at the power density of 0.8 kW/kg, and a decent cyclability that the capacitances are maintained at 80.8% compared with the initial capacitance. This research presents a high-performance electrode material and provides a promising route for the construction of electrode materials for supercapacitors with both structural and component advantages.
- Ion exchange,
- Amorphous,
- β-Co(OH)₂,
- Hollow polyhedron,
- Supercapacitor
1. [1]
  G.A. Snook, P. Kao, A.S. Best, J. Power Sources 196(2011) 1-12. doi: 10.1016/j.jpowsour.2010.06.084
2. [2]
  N. Choudhary, C. Li, J. Moore, et al., Adv. Mater. 29(2017) 1605336. doi: 10.1002/adma.201605336
3. [3]
  H. Luo, G.W. Wang, J.T. Lu, L. Zhuang, L. Xiao, ACS Appl. Mater. Inter. 11(2019) 41215-41221. doi: 10.1021/acsami.9b10860
4. [4]
  A. Borenstein, O. Hanna, R. Attias, et al., J. Mater. Chem. A 5(2017) 12653-12672. doi: 10.1039/C7TA00863E
5. [5]
  M. Wang, Y.B. Tang, Adv. Energy Mater. 8(2018) 1703320. doi: 10.1002/aenm.201703320
6. [6]
  W.D. He, C.G. Wang, H.Q. Li, et al., Adv. Energy Mater. 7(2017) 1700983. doi: 10.1002/aenm.201700983
7. [7]
  J.Y. Cao, Y. Zhao, Y.F. Xu, et al., J Mater. Chem. A 6(2018) 3355-3360. doi: 10.1039/C7TA10756K
8. [8]
  P.S. Kumar, P. Prakash, A. Srinivasan, C. Karuppiah, J. Power Sources 482(2020) 228892.
9. [9]
  C.G. Wang, K. Guo, W.D. He, et al., Sci. Bull. 62(2017) 1122-1131. doi: 10.1016/j.scib.2017.08.014
10. [10]
  J. Xie, Y.C. Lu, Nat. Commun. 11(2020) 2499. doi: 10.1038/s41467-020-16259-9
11. [11]
  Y. Merla, B. Wu, V. Yufit, et al., J. Power Sources 1(2016) 224-231.
12. [12]
  G.J. He, M. Ling, X.Y. Han, et al., Energy Storage Mater. 9(2017) 119-125. doi: 10.1016/j.ensm.2017.07.005
13. [13]
  N. Feng, R.J. Meng, L.H. Zu, et al., Nat. Commun. 10(2019) 1372. doi: 10.1038/s41467-019-09384-7
14. [14]
  T.Z. Hao, Y.Y. Liu, G.L. Liu, et al., Energy Storage Mater. 23(2019) 225-232. doi: 10.1016/j.ensm.2019.05.011
15. [15]
  C.G. Wang, P.X. Sun, G.M. Qu, J.M. Yin, X.J. Xu, Chin. Chem. Lett. 29(2018) 1731-1740. doi: 10.1016/j.cclet.2018.12.005
16. [16]
  Y.F. Tang, Z.Y. Liu, W.F. Guo, et al., Electrochim. Acta 190(2016) 118-125. doi: 10.1016/j.electacta.2016.01.042
17. [17]
  Q. Rong, L.L. Long, X. Zhang, Y.X. Huang, H.Q. Yu, Appl. Energy 153(2015) 63-69. doi: 10.1016/j.apenergy.2014.11.077
18. [18]
  M.H. Ye, L. Ma, M.Y. Gan, et al., Appl. Surf. Sci. 456(2018) 390-397. doi: 10.1016/j.apsusc.2018.06.101
19. [19]
  N. Zhao, H.Q. Fan, M.C. Zhang, et al., Electrochim. Acta 321(2019) 134681. doi: 10.1016/j.electacta.2019.134681
20. [20]
  G.M. Qu, C.L. Li, G. Zhao, et al., Nanoscale 7(2020) 4686-4694.
21. [21]
  Y.X. Wen, S.L. Peng, Z.L. Wang, et al., J. Mater. Chem. A 15(2017) 7144-7152.
22. [22]
  Q. Li, Y.X. Xu, S.S. Zheng, et al., Small 14(2018) 1800426. doi: 10.1002/smll.201800426
23. [23]
  Y. Li, F.F. An, H.R. Wu, et al., J. Power Sources 427(2019) 138-144. doi: 10.1016/j.jpowsour.2019.04.060
24. [24]
  R.S. Gao, Q.G. Zhang, F.Z. Soyekwo, et al., Electrochim. Acta 237(2017) 94-101. doi: 10.1016/j.electacta.2017.03.214
25. [25]
  S.H. Bi, Y.Z. Wu, A.Y. Cao, et al., Mater. Today Energy 1(2020) 100548.
26. [26]
  Q.H. Wang, F. Gao, B.Y. Xu, et al., Chem. Eng. J. 327(2017) 387-396. doi: 10.1016/j.cej.2017.06.124
27. [27]
  W.C. Jiang, D.S. Yu, Q. Zhang, et al., Energy Storage Mater. 25(2015) 1063-1073.
28. [28]
  H.S. Han, H. Choi, S. Mhin, et al., Energy Environ. Sci. 8(2019) 2443-2454.
29. [29]
  X.M. Yin, H.J. Li, H.Q. Wang, et al., ACS Appl. Mater. Inter. 10(2018) 29496-29504. doi: 10.1021/acsami.8b08455
30. [30]
  Q. Xue, H.B. Gan, Y. Huang, et al., Adv. Energy Mater. 8(2018) 1703117. doi: 10.1002/aenm.201703117
31. [31]
  Y.Q. Xu, S.J. Hou, G. Yang, et al., Electrochim. Acta 285(2018) 192-201. doi: 10.1016/j.electacta.2018.07.211
32. [32]
  R.S. Gao, Q.G. Zhang, F. Soyekwo, et al., Electrochim. Acta 237(2017) 94-101. doi: 10.1016/j.electacta.2017.03.214
33. [33]
  J.X. Wang, C. Ma, Y.M. Choi, et al., J. Am. Chem. Soc. 34(2011) 13551-13557.
34. [34]
  Y.Z. Su, K. Xiao, N. Li, Z.Q. Liu, S.Z. Qiao, J. Mater. Chem. A 34(2014) 13845-13853.
35. [35]
  P.F. Cai, T. Liu, L.Y. Zhang, B. Cheng, J.G. Yu, Appl. Surf. Sci. 504(2020) 144501. doi: 10.1016/j.apsusc.2019.144501
36. [36]
  G.M. Qu, P.X. Sun, G.T. Xiang, et al., Appl. Mater. Today 20(2020) 100713. doi: 10.1016/j.apmt.2020.100713
37. [37]
  G.M. Qu, X.X. Zhang, G.T. Xiang, et al., Chin. Chem. Lett. 31(2020) 2007-2012. doi: 10.1016/j.cclet.2020.01.040
38. [38]
  C.H. Liang, X.D. Zhang, P. Feng, H.X. Chai, Y.M. Huang, Chem. Eng. J. 344(2018) 95-104. doi: 10.1016/j.cej.2018.03.064
39. [39]
  H.B. Wu, B.Y. Guan, P.L. He, X.Y. Yu, J. Mater. Chem. A 6(2018) 19338-19341. doi: 10.1039/C8TA07080F
40. [40]
  X.H. Guan, M.H. Huang, L. Yang, G.S. Wang, X. Guan, Chem. Eng. J. 372(2019) 151-162. doi: 10.1016/j.cej.2019.04.145
41. [41]
  W.R. Zou, W.X. Guo, X.Y. Liu, et al., Chem. Eng. J. 24(2018) 19309-19316.
42. [42]
  T. Chen, Y.F. Tang, W.F. Guo, et al., Electrochim. Acta 212(2018) 294-302.
43. [43]
  Y.Q. Jiang, J.P. Liu, Energy Environ. Mater. 2(2019) 30-37. doi: 10.1002/eem2.12028
44. [44]
  Y.R. Wei, X.X. ZHang, Z.H. Wang, et al., Chin. Chem. Lett. 32(2021) 119-124. doi: 10.1016/j.cclet.2020.10.046
45. [45]
  B.Y. Guan, X. Wang, S.Y. Song, X.W. Lou, Adv. Mater. 29(2016) 1605051.
46. [46]
  J.F. Qian, F. Sun, L.Z. Qin, Mater. Lett. 82(2012) 220-223. doi: 10.1016/j.matlet.2012.05.077
47. [47]
  R. Li, S.L. Wang, Z.C. Huang, F.X. Lu, T.B. He, J. Power Sources 312(2016) 156-164. doi: 10.1016/j.jpowsour.2016.02.047
48. [48]
  Y.S. He, D.W. Bai, X.W. Yang, et al., Electrochem. Commun. 12(2010) 570-573. doi: 10.1016/j.elecom.2010.02.002
49. [49]
  H. Wang, C. Wang, C. Qing, et al., Electrochim. Acta 174(2015) 1104-1112. doi: 10.1016/j.electacta.2015.06.074
50. [50]
  Z.H. Wang, G.M. Qu, X.X. Zhang, et al., Nanoscale 35(2020) 18400-18408.
51. [51]
  R. Li, S.L. Wang, Z.C. Huang, F.X. Lu, T.B. He, J. Power Sources 312(2018) 156-164.
52. [52]
  S.D. Liu, Y. Yin, D.X. Ni, et al., Energy Storage Mater. 19(2019) 186-196. doi: 10.1016/j.ensm.2018.10.022
53. [53]
  X.L. Bai, X.L. Tong, Y.L. Gao, et al., Electrochim. Acta 281(2018) 525-533. doi: 10.1016/j.electacta.2018.06.003
54. [54]
  Z. Yu, Y. Bai, S.M. Zhang, et al., Int. J. Hydrogen Energy 43(2018) 8815-8823. doi: 10.1016/j.ijhydene.2018.03.154
55. [55]
  F.L. Zhao, W.X. Huang, D. Xie, et al., J. Mater. Sci. Mater. Electron. 20(2019) 21229-21239.
56. [56]
  Y.X. Chen, C. Jing, X. Fu, et al., Chem. Eng. J. 384(2020) 123367. doi: 10.1016/j.cej.2019.123367
57. [57]
  W.S. Li, M.L. Chang, H.C. Cheng, Chem. Phys. Lett. 739(2020) 137003. doi: 10.1016/j.cplett.2019.137003
58. [58]
  Y. Zhang, H. Liu, M. Huang, et al., ChemElectroChem 4(2017) 721-727. doi: 10.1002/celc.201600661
59. [59]
  Y.Y. Yang, P.L. Zhu, L.C. Zhang, et al., ACS Sustain. Chem. Eng. 7(2019) 16803-16813. doi: 10.1021/acssuschemeng.9b04321
60. [60]
  X.M. Wu, M. Lian, Q. Wang, Electrochim. Acta 295(2019) 655-661. doi: 10.1016/j.electacta.2018.10.199
61. [61]
  Q. Huang, J.Z. Wang, F. Lin, et al., RSC Adv. 20(2016) 16745-16750.
62. [62]
  Y. Wang, W.C. Huo, X.Y. Yuan, Y.X. Zhang, Acta Phys. Chim. Sin. 36(2020) 1904007. doi: 10.3866/PKU.WHXB201904007
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4. [4]
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沈阳化工大学材料科学与工程学院沈阳 110142

Hollow polyhedron structure of amorphous Ni-Co-S/Co(OH)2 for high performance supercapacitors

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通讯作者: 陈斌, bchen63@163.com

Hollow polyhedron structure of amorphous Ni-Co-S/Co(OH)₂ for high performance supercapacitors