Citation: Jing-Jing Pang, Rui-Huan Du, Xin Lian, Zhao-Quan Yao, Jian Xu, Xian-He Bu. Selective sensing of Cr^Ⅵ and Fe^Ⅲ ions in aqueous solution by an exceptionally stable Tb^Ⅲ-organic framework with an AIE-active ligand[J]. Chinese Chemical Letters, ;2021, 32(8): 2443-2447. doi: 10.1016/j.cclet.2021.01.040 shu

Selective sensing of Cr^Ⅵ and Fe^Ⅲ ions in aqueous solution by an exceptionally stable Tb^Ⅲ-organic framework with an AIE-active ligand

Jing-Jing Pang ^a ,
Rui-Huan Du ^a ,
Xin Lian ^a ,
Zhao-Quan Yao ^{a, *,} ,
Jian Xu ^{a, *,} ,
Xian-He Bu ^{a, b}

a.
School of Materials Science and Engineering, National Institute for Advanced Materials, Tianjin Key Laboratory of Metal and Molecule-Based Material Chemistry, Nankai University, Tianjin 300350, China
b.
State Key Laboratory of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071, China

lawyer185@163.com

jxu@nankai.edu.cn

Received Date: 20 December 2020
Revised Date: 14 January 2021
Accepted Date: 19 January 2021
Available Online: 27 January 2021

Figures(4)

We herein report a new lanthanide metal-organic framework (MOF) that exhibits excellent chemical stability, especially in the aqueous solution over a wide pH range from 1 to 14. In contrast to many reported lanthanide MOFs, this Tb-based MOF emits cyan fluorescence inherited from the integrated AIE-active ligand, rather than Ln³⁺ ions. More remarkably, its fluorescence signal features a highly selective and sensitive "turn-off" response toward CrO₄²⁻, Cr₂O₇²⁻ and Fe³⁺ ions, highlighted with the low detection limits down to 68.18, 69.85 and 138.8 ppm, respectively. Thus, the exceptional structural stability and sensing performance render this material able to be a superior luminescent sensor for heavy metal ions in wastewater.
- Lanthanide metal-organic framework,
- Aggregation-induced emission,
- Heavy metal ions,
- Selective luminescence sensing,
- Aqueous-phase sensing
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Selective sensing of CrⅥ and FeⅢ ions in aqueous solution by an exceptionally stable TbⅢ-organic framework with an AIE-active ligand

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通讯作者: 陈斌, bchen63@163.com

Selective sensing of Cr^Ⅵ and Fe^Ⅲ ions in aqueous solution by an exceptionally stable Tb^Ⅲ-organic framework with an AIE-active ligand