Citation: Jinhuan Dong, Mengying Jia, Xianxiu Xu. Aryl groups, supplement of amino protecting group chemistry![J]. Chinese Chemical Letters, ;2021, 32(6): 1831-1833. doi: 10.1016/j.cclet.2021.01.034 shu

Aryl groups, supplement of amino protecting group chemistry!

College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Center of Functionalized Probes for Chemical Imaging in Universities of Shandong, Key Laboratory of Molecular and Nano Probes, Ministry of Education, Institute of Molecular and Nano Science, Shandong Normal University, Ji'nan 250014, China

xuxx677@sdnu.edu.cn

Received Date: 2 December 2020
Revised Date: 4 January 2021
Accepted Date: 12 January 2021
Available Online: 27 January 2021

Figures(1)

Amino group protective strategy has consequently emerged in multistep organic synthesis. Easy and selective deprotection procedures are crucial to facilitate the chemical transformation. Recently, Zhang's group from Henan Normal University collaborating with Chen's group of Nankai University developed a novel strategy for the regiospecific cleavage of inert aryl C—N bonds in N-aryl amides by hypervalent iodine(V) reagents. These procedures allow removal of sort of aryl groups under mild conditions to give primary amides in high efficiency. It bestows these aryl groups with the characteristics of amino protecting groups that might be the supplement of amino protecting group chemistry.
- Organoiodine(V) reagent,
- C(aryl)—N bond cleavage,
- Amino protecting group,
- Dearylation,
- 8-Aminoquinoline,
- Primary amide
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