Citation: Mengdi Sun, Zemin Zhang, Qiujin Shi, Jianlong Yang, Mingzheng Xie, Weihua Han. Toward photocatalytic hydrogen generation over BiVO₄ by controlling particle size[J]. Chinese Chemical Letters, ;2021, 32(8): 2419-2422. doi: 10.1016/j.cclet.2021.01.013 shu

Toward photocatalytic hydrogen generation over BiVO₄ by controlling particle size

Mengdi Sun ^a ,
Zemin Zhang ^b ,
Qiujin Shi ^a ,
Jianlong Yang ^a ,
Mingzheng Xie ^{a, *,} ,
Weihua Han ^{b, *,}

a.
Key Laboratory of Western China's Environmental Systems of the Ministry of Education, Key Laboratory for Environmental Pollution Prediction and Control of Gansu Province, College of Earth and Environmental Sciences, Lanzhou University, Lanzhou 730000, China
b.
School of Physical Science and Technology, Lanzhou University, Lanzhou 730000, China

xiemzh@lzu.edu.cn

hanwh@lzu.edu.cn

Received Date: 30 November 2020
Revised Date: 31 December 2020
Accepted Date: 7 January 2021
Available Online: 12 January 2021

Figures(4)

Owing to excellent light absorption and high activity for oxygen evolution, monoclinic bismuth vanadate (BiVO₄) is regarded as an ideal candidate for photocatalytic water splitting. However, its application is limited by the large particle size in micrometer scale, as well as the slightly positive conduction band. In this work, we successfully synthesized nano-BiVO₄ with particle size ranged from 27 nm to 57 nm by wet chemical method based on electrostatic spinning method. Unlike bulk BiVO₄, the nano-sized BiVO₄ possesses the ability to generate hydrogen by water splitting, and the activity could reach up to 1.66 μmol h⁻¹g⁻¹ with the assistance of Pt. The enhanced activity is mainly attributed to the improvements resulted from reduced particle size, which includes elevated conduction band, enlarged specific surface area and promoted charge separation. This work provides a simple method for synthesizing photocatalyst with small particle size and high yield.
- Nano-sized bismuth vanadate,
- Electrospinning process,
- Charge carrier separation,
- Elevated conduction band,
- Water splitting
1. [1]
  V. Kumaravel, S. Mathew, J. Bartlett, S.C. Pillai, Appl. Catal. B: Environ. 244 (2019) 1021-1064 doi: 10.1016/j.apcatb.2018.11.080
2. [2]
  F.E. Osterloh, Chem. Soc. Rev. 42 (2013) 2294-320 doi: 10.1039/C2CS35266D
3. [3]
  N. Tian, H.W. Huang, X. Du, F. Dong, Y.H. Zhang, J. Mater. Chem. A 7 (2019) 11584–11612 doi: 10.1039/c9ta01819k
4. [4]
  Y. Li, Y.Y. Tian, R.F. Zhang, et al., Inorg. Chim. Acta 439 (2016) 123-129 doi: 10.1016/j.ica.2015.10.014
5. [5]
  Y.H. Ng, A. Iwase, A. Kudo, R. Amal, J. Phys. Chem. Lett. 1 (2010) 2607–2612 doi: 10.1021/jz100978u
6. [6]
  M.G. Lee, D.H. Kim, W. Sohn, et al., Nano Energy 28 (2016) 250-260 doi: 10.1016/j.nanoen.2016.08.046
7. [7]
  J. Song, J. Cha, M.G. Lee, et al., J. Mater. Chem. A 5 (2017) 18831-18838 doi: 10.1039/C7TA04695B
8. [8]
  G. Zhang, G. Liu, L.Z. Wang, J.T.S. Irvine, Chem. Soc. Rev. 45 (2016) 5951-5984 doi: 10.1039/C5CS00769K
9. [9]
  C.M. Ding, J.Y. Shi, D. Wang, et al., Phys. Chem. Chem. Phys. 15 (2013) 4589-4595 doi: 10.1039/c3cp50295c
10. [10]
  J.L. Yang, Q.J. Shi, R. Zhang, et al., Carbon 138 (2018) 118-124 doi: 10.1016/j.carbon.2018.06.003
11. [11]
  W.T. Sun, M.Z. Xie, L.Q. Jing, Y.B. Luan, H.G. Fu, J. Solid State Chem. 184 (2011) 3050-3054 doi: 10.1016/j.jssc.2011.09.013
12. [12]
  O.F. Lopes, K.T.G. Carvalho, A.E. Nogueira, W. Avansi, C. Ribeiro, Appl. Catal. B: Environ. 188 (2016) 87-97 doi: 10.1016/j.apcatb.2016.01.065
13. [13]
  M.Z. Xie, Z.M. Zhang, W.H. Han, et al., J. Mater. Chem. A 1 (2017) 1-9 doi: 10.1155/2017/3956027
14. [14]
  Q.J. Shi, Z.J. Li, L. Chen, et al., Appl. Catal. B: Environ. 244 (2019) 641-649 doi: 10.1016/j.apcatb.2018.11.089
15. [15]
  X.F. Lu, C. Wang, F. Favier, N. Pinna, Adv. Energy Mater. 7 (2016) 1601301
16. [16]
  T.V. Pinto, D.M. Fernandes, A. Guedes, et al., Chem. Eng. J. 350 (2018) 856-866 doi: 10.1016/j.cej.2018.05.155
17. [17]
  Z.G. Zhu, P. Wu, G.J. Liu, et al., Chem. Eng. J. 313 (2017) 957-966 doi: 10.1016/j.cej.2016.10.145
18. [18]
  T. Tatarchuk, M. Myslin, I. Mironyuk, et al., J. Alloys Compd. 819 (2020) 152945 doi: 10.1016/j.jallcom.2019.152945
19. [19]
  J.P. Wang, Y.N. Song, J. Hu, et al., Appl. Catal. B: Environ. 251 (2019) 94-101 doi: 10.1016/j.apcatb.2019.03.049
20. [20]
  W.J. Luo, Z.S. Li, T. Yu, Z.G. Zou, J. Phys. Chem. C 116 (2012) 5076–5081 doi: 10.1021/jp210207q
21. [21]
  H. Lin, C.P. Huang, W. Li, et al., Appl. Catal. B: Environ. 68 (2006) 1-11 doi: 10.1080/10170660609508991
22. [22]
  R. Selvaraj, K.Z. Qi, S.M.Z. Al-Kindy, et al, RSC Adv. 4 (2014) 15371-15376 doi: 10.1039/C4RA00483C
23. [23]
  S.N.F.M. Nasir, H. Ullah, M. Ebadi, et al., J. Phys. Chem. C 121 (2017) 6218-6228 doi: 10.1021/acs.jpcc.7b01149
24. [24]
  Z.M. Zhang, C.T. Gao, Z.M. Wu, et al., Nano Energy 19 (2016) 318-327 doi: 10.1016/j.nanoen.2015.11.011
25. [25]
  A. Kudo, K. Omori, H. Kato, J. Am. Chem. Soc. 121 (1999) 11459-11467 doi: 10.1021/ja992541y
26. [26]
  S. Tokunaga, H. Kato, A. Kudo, Chem. Mater. 13 (2001) 4624-4628 doi: 10.1021/cm0103390
27. [27]
  D.Q. Feng, Y.H. Cheng, J. He, et al., Carbon 125 (2017) 454-463 doi: 10.1016/j.carbon.2017.09.084
28. [28]
  J. Han, G. Zhu, M. Hojamberdiev, J. Peng, P. Liu, J. Mater. Sci. 51 (2015) 2057-2071
29. [29]
  C.Y. Jin, M. Wang, Z.L. Li, et al., Chem. Eng. J. 398 (2020) 125569 doi: 10.1016/j.cej.2020.125569
30. [30]
  R.G. He, S.W. Cao, J.G. Yu, Y.C. Yang, Catal. Today 264 (2016) 221-228 doi: 10.1016/j.cattod.2015.07.029
31. [31]
  X. Zhang, C. Li, J. Liang, et al., ChemCatChem. 12 (2020) 1212-1219 doi: 10.1002/cctc.201901808
32. [32]
  M.X. Ji, Z.Y. Zhang, J.X. Xia, et al., Chin. Chem. Lett. 29 (2018) 805-810 doi: 10.1016/j.cclet.2018.05.002
33. [33]
  H.J. Liang, P. Hua, Y.F. Zhou, et al., Chin. Chem. Lett. 30 (2019) 2245-2248 doi: 10.1016/j.cclet.2019.05.046
34. [34]
  K.Z. Qi, Y.B. Xie, R.D. Wang, S.Y. Liu, Z. Zhao, Appl. Surf Sci. 466 (2019) 847-853 doi: 10.1016/j.apsusc.2018.10.037
35. [35]
  F. Chen, H.W. Huang, Y.H. Zhang, T.R. Zhang, Chin. Chem. Lett. 28 (2017) 2244-2250 doi: 10.1016/j.cclet.2017.09.017
36. [36]
  D. Liu, Z. Wei, Y. Shen, et al., J. Mater. Chem. A. 40 (2015) 20322-20329
37. [37]
  K.Z. Qi, W.X. Lv, I. Khan, S.Y. Liu, Chin. J. Catal. 41 (2020) 114-121 doi: 10.1016/S1872-2067(19)63459-5
38. [38]
  M.Z. Xie, X.D. Fu, L.Q. Jing, et al., Adv. Energy Mater. 4 (2014) 1300995 doi: 10.1002/aenm.201300995
39. [39]
  F.Q. Zhou, J.C. Fan, Q.J. Xu, Y.L. Min, Appl. Catal. B: Environ. 201 (2017) 77-83 doi: 10.1016/j.apcatb.2016.08.027
40. [40]
  N.K. Veldurthi, N.K. Eswar, S.A. Singh, G. Madras, Appl. Catal. B: Environ. 220 (2018) 512-523 doi: 10.1016/j.apcatb.2017.08.082
41. [41]
  A. Kudo, K. Ueda, H. Kato, I. Mikami, Catal. Lett. 53 (1998) 229-230 doi: 10.1023/A:1019034728816
42. [42]
  R.G. He, S.W. Cao, D.P. Guo, et al, J. Nanopart. Res. 41 (2015) 3511-3517
43. [43]
  J. Liu, Y. Liu, N.Y. Liu, et al., Science 347 (2015) 970-974 doi: 10.1126/science.aaa3145
44. [44]
  Y.L. Zhao, A.R. Barman, S. Dhar, et al., AIP Adv. 1 (2011) 022151 doi: 10.1063/1.3609927
45. [45]
  F. Reurings, F. Tuomisto, C.S. Gallinat, G. Koblmüller, J.S. Speck, Appl. Phys. Lett. 97 (2010) 1-3
1. [1]
  Kai Han , Guohui Dong , Ishaaq Saeed , Tingting Dong , Chenyang Xiao . Boosting bulk charge transport of CuWO4 photoanodes via Cs doping for solar water oxidation. Chinese Journal of Structural Chemistry, 2024, 43(2): 100207-100207. doi: 10.1016/j.cjsc.2023.100207
2. [2]
  Chunru Liu , Ligang Feng . Advances in anode catalysts of methanol-assisted water-splitting reactions for hydrogen generation. Chinese Journal of Structural Chemistry, 2023, 42(10): 100136-100136. doi: 10.1016/j.cjsc.2023.100136
3. [3]
  Hongye Bai , Lihao Yu , Jinfu Xu , Xuliang Pang , Yajie Bai , Jianguo Cui , Weiqiang Fan . Controllable Decoration of Ni-MOF on TiO2: Understanding the Role of Coordination State on Photoelectrochemical Performance. Chinese Journal of Structural Chemistry, 2023, 42(10): 100096-100096. doi: 10.1016/j.cjsc.2023.100096
4. [4]
  Wenhao Chen , Jian Du , Hanbin Zhang , Hancheng Wang , Kaicheng Xu , Zhujun Gao , Jiaming Tong , Jin Wang , Junjun Xue , Ting Zhi , Longlu Wang . Surface treatment of GaN nanowires for enhanced photoelectrochemical water-splitting. Chinese Chemical Letters, 2024, 35(9): 109168-. doi: 10.1016/j.cclet.2023.109168
5. [5]
  Entian Cui , Yulian Lu , Zhaoxia Li , Zhilei Chen , Chengyan Ge , Jizhou Jiang . Interfacial B-O bonding modulated S-scheme B-doped N-deficient C₃N₄/O-doped-C₃N₅ for efficient photocatalytic overall water splitting. Chinese Chemical Letters, 2025, 36(1): 110288-. doi: 10.1016/j.cclet.2024.110288
6. [6]
  Hualin Jiang , Wenxi Ye , Huitao Zhen , Xubiao Luo , Vyacheslav Fominski , Long Ye , Pinghua Chen . Novel 3D-on-2D g-C₃N₄/AgI._x._y heterojunction photocatalyst for simultaneous and stoichiometric production of H₂ and H₂O₂ from water splitting under visible light. Chinese Chemical Letters, 2025, 36(2): 109984-. doi: 10.1016/j.cclet.2024.109984
7. [7]
  Ji Chen , Yifan Zhao , Shuwen Zhao , Hua Zhang , Youyu Long , Lingfeng Yang , Min Xi , Zitao Ni , Yao Zhou , Anran Chen . Heterogeneous bimetallic oxides/phosphides nanorod with upshifted d band center for efficient overall water splitting. Chinese Chemical Letters, 2024, 35(9): 109268-. doi: 10.1016/j.cclet.2023.109268
8. [8]
  Zhao Lu , Hu Lv , Qinzhuang Liu , Zhongliao Wang . Modulating NH₂ Lewis Basicity in CTF-NH₂ through Donor-Acceptor Groups for Optimizing Photocatalytic Water Splitting. Acta Physico-Chimica Sinica, 2024, 40(12): 2405005-. doi: 10.3866/PKU.WHXB202405005
9. [9]
  Xin Jiang , Han Jiang , Yimin Tang , Huizhu Zhang , Libin Yang , Xiuwen Wang , Bing Zhao . g-C₃N₄/TiO_2-X heterojunction with high-efficiency carrier separation and multiple charge transfer paths for ultrasensitive SERS sensing. Chinese Chemical Letters, 2024, 35(10): 109415-. doi: 10.1016/j.cclet.2023.109415
10. [10]
  Wangyan Hu , Ke Li , Xiangnan Dou , Ning Li , Xiayan Wang . Nano-sized stationary phase packings retained by single-particle frit for microchip liquid chromatography. Chinese Chemical Letters, 2024, 35(4): 108806-. doi: 10.1016/j.cclet.2023.108806
11. [11]
  Congyan Liu , Xueyao Zhou , Fei Ye , Bin Jiang , Bo Liu . Confined electric field in nano-sized channels of ionic porous framework towards unique adsorption selectivity. Chinese Chemical Letters, 2025, 36(2): 109969-. doi: 10.1016/j.cclet.2024.109969
12. [12]
  Shuyuan Pan , Zehui Yang , Fang Luo . Ni-based electrocatalysts for urea assisted water splitting. Chinese Journal of Structural Chemistry, 2024, 43(8): 100373-100373. doi: 10.1016/j.cjsc.2024.100373
13. [13]
  Wenkai Liu , Yanxian Hou , Weijian Liu , Ran Wang , Shan He , Xiang Xia , Chengyuan Lv , Hua Gu , Qichao Yao , Qingze Pan , Zehou Su , Danhong Zhou , Wen Sun , Jiangli Fan , Xiaojun Peng . Se-substituted pentamethine cyanine for anticancer photodynamic therapy mediated using the hot band absorption process. Chinese Chemical Letters, 2024, 35(12): 109631-. doi: 10.1016/j.cclet.2024.109631
14. [14]
  Shuo Zhang , Haitao Liao , Zhi-Qun Liu , Chong Yan , Jia-Qi Huang . Re-evaluating the nano-sized inorganic protective layer on Cu current collector for anode free lithium metal batteries. Chinese Chemical Letters, 2024, 35(7): 109284-. doi: 10.1016/j.cclet.2023.109284
15. [15]
  Yuchen Guo , Xiangyu Zou , Xueling Wei , Weiwei Bao , Junjun Zhang , Jie Han , Feihong Jia . Fe regulating Ni3S2/ZrCoFe-LDH@NF heterojunction catalysts for overall water splitting. Chinese Journal of Structural Chemistry, 2024, 43(2): 100206-100206. doi: 10.1016/j.cjsc.2023.100206
16. [16]
  Rui Deng , Wenjie Jiang , Tianqi Yu , Jiali Lu , Boyao Feng , Panagiotis Tsiakaras , Shibin Yin . Cycad-leaf-like crystalline-amorphous heterostructures for efficient urea oxidation-assisted water splitting. Chinese Journal of Structural Chemistry, 2024, 43(7): 100290-100290. doi: 10.1016/j.cjsc.2024.100290
17. [17]
  Shudi Yu , Jie Li , Jiongting Yin , Wanyu Liang , Yangping Zhang , Tianpeng Liu , Mengyun Hu , Yong Wang , Zhengying Wu , Yuefan Zhang , Yukou Du . Built-in electric field and core-shell structure of the reconstructed sulfide heterojunction accelerated water splitting. Chinese Chemical Letters, 2024, 35(12): 110068-. doi: 10.1016/j.cclet.2024.110068
18. [18]
  Lu Qi , Zhaoyang Chen , Xiaoyu Luan , Zhiqiang Zheng , Yurui Xue , Yuliang Li . Atomically dispersed Mn enhanced catalytic performance for overall water splitting on graphdiyne-coated copper hydroxide nanowire. Chinese Journal of Structural Chemistry, 2024, 43(1): 100197-100197. doi: 10.1016/j.cjsc.2024.100197
19. [19]
  Jun LI , Huipeng LI , Hua ZHAO , Qinlong LIU . Preparation and photocatalytic performance of AgNi bimetallic modified polyhedral bismuth vanadate. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 601-612. doi: 10.11862/CJIC.20230401
20. [20]
  Wengao Zeng , Yuchen Dong , Xiaoyuan Ye , Ziying Zhang , Tuo Zhang , Xiangjiu Guan , Liejin Guo . Crystalline carbon nitride with in-plane built-in electric field accelerates carrier separation for excellent photocatalytic hydrogen evolution. Chinese Chemical Letters, 2024, 35(4): 109252-. doi: 10.1016/j.cclet.2023.109252

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(556)
HTML views(28)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Toward photocatalytic hydrogen generation over BiVO4 by controlling particle size

Metrics

通讯作者: 陈斌, bchen63@163.com

Toward photocatalytic hydrogen generation over BiVO₄ by controlling particle size