Citation: Xi Fan, Lvbing Yuan, Jian Zhang, Lei Zhang. Phenol-triggered supramolecular transformation of titanium–oxo cluster based coordination capsules[J]. Chinese Chemical Letters, ;2021, 32(8): 2415-2418. doi: 10.1016/j.cclet.2021.01.010 shu

Phenol-triggered supramolecular transformation of titanium–oxo cluster based coordination capsules

Xi Fan ^{a, b} ,
Lvbing Yuan ^a ,
Jian Zhang ^a ,
Lei Zhang ^{a, *,}

a.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
b.
Fujian Provincial Key Laboratory of Polymer Materials, College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China

LZhang@fjirsm.ac.cn

Received Date: 7 December 2020
Revised Date: 2 January 2021
Accepted Date: 6 January 2021
Available Online: 9 January 2021

Figures(4)

Supramolecular transformations of coordination cage or capsule have received much attention recently, which help elucidate this natural self-assembly behavior in biological systems. The current study describes the first supramolecular transformation of titanium–organic coordination capsule triggered by phenol (and H₃PO₃). The structural alterations are accompanied by the reconstruction of 5-coordinated Ti centers to 6-coordinated ones. Meanwhile, different amounts of encapsulated phenol guest molecules can be identified, dependent on the sizes of the obtained cavities. In addition, they display much better visible light absorption and air stability than the isopropanol stabilized ones.
- Titanium-oxo clusters,
- Phenol,
- Supramolecular transformation,
- Post-synthesis modulation,
- Coordination capsules
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