Citation: Xiaoqing Niu, Tianbing Song, Huanming Xiong. Large scale synthesis of red emissive carbon dots powder by solid state reaction for fingerprint identification[J]. Chinese Chemical Letters, ;2021, 32(6): 1953-1956. doi: 10.1016/j.cclet.2021.01.006 shu

Large scale synthesis of red emissive carbon dots powder by solid state reaction for fingerprint identification

Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200438, China

hmxiong@fudan.edu.cn

Received Date: 5 December 2020
Revised Date: 31 December 2020
Accepted Date: 4 January 2021
Available Online: 9 January 2021

Figures(6)

Red emissive carbon dots (CDs) powder was synthesized on a large scale from phloroglucinol and boric acid by a novel solid state reaction with yield up to 75%. This method is safe and convenient, for it needs neither high pressure reactors nor complicated post-treatment procedures. The as-prepared carbon dots powder exhibited strong red fluorescence with excitation-independent behavior. XPS measurement and PL spectra suggest that such red fluorescence arise from boron-doped structures in CDs, which increases along with the boron concentration on CDs surface but decreases when the concentration quenching effect takes place. To overcome the aggregation induced fluorescence quenching of the solid CDs powder, the conventional methods are dispersing CDs into a large amount of inert substrates. But our present work provides a new strategy to realize strong red fluorescence of CDs in solid state. As a result, such carbon dots powder works well for latent fingerprint identification on various material surfaces.
- Carbon dots,
- Red fluorescence,
- Solid reaction,
- Large scale,
- Fingerprint identification
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