Citation: Pengjia Ding, Jianrui Niu, Fengqin Chang, Zhuang He, Thomas Wågberg, Zaixing Li, Guangzhi Hu. NiCo₂O₄ hollow microsphere–mediated ultrafast peroxymonosulfate activation for dye degradation[J]. Chinese Chemical Letters, ;2021, 32(8): 2495-2498. doi: 10.1016/j.cclet.2020.12.063 shu

NiCo₂O₄ hollow microsphere–mediated ultrafast peroxymonosulfate activation for dye degradation

Pengjia Ding ^{a, b} ,
Jianrui Niu ^a,, ,
Fengqin Chang ^b ,
Zhuang He ^{a, b} ,
Thomas Wågberg ^c ,
Zaixing Li ^a,, ,
Guangzhi Hu ^{a, b,,}

a.
College of Environmental Science and Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, China
b.
Institute for Ecological Research and Pollution Control of Plateau Lakes, School of Ecology and Environmental Science, Yunnan University, Kunming 650504, China
c.
Department of Physics, Umeå University, Umeå 901 87, Sweden

Corresponding author: Jianrui Niu, njrhepjs@163.com Zaixing Li, 13832111831@163.com Guangzhi Hu, guangzhihu@ynu.edu.cn
Received Date: 15 September 2020
Revised Date: 27 November 2020
Accepted Date: 25 December 2020
Available Online: 5 January 2021

Figures(4)

Morphology and dispersity are key factors for activating peroxymonosulfate (PMS). In this study, we designed a recyclable open-type NiCo₂O₄ hollow microsphere via a simple hydrothermal method with the assistance of an NH₃ vesicle. The physical structure and chemical properties were characterized using techniques such as scanning electron microscope (SEM), transmission electron microscope (TEM), X-ray diffraction (XRD), N₂ adsorption and X-ray photoelectron spectroscopy (XPS). The test results confirm that the inner and outer surfaces of open-type NiCo₂O₄ hollow-sphere can be efficiently utilized because of the hole on the surface of the catalyst, which can minimize the diffusion resistance of the reactants and products. Under optimized conditions, the total organic carbon (TOC) removal efficiency of rhodamine B (RhB) can reach up to 80% in 40 min, which is almost 50% shorter than the reported values. The reactive radicals were identified and the proposed reaction mechanism was well described. Moreover, the disturbances of HCO₃⁻, NO₃⁻, Cl⁻ and H₂PO₄⁻ were further investigated. As a result, HCO₃⁻ and NO₃⁻ suppressed the reaction while Cl⁻ and H₂PO₄⁻ had a double effect on reaction.
- Open-type sphere,
- Hollow NiCo₂O₄,
- Vesicle,
- Inner and outer surface,
- Ultra peroxymonosulfate activation
1. [1]
  K.A. Lin, J.T. Lin, Chemosphere 182 (2017) 54-64. doi: 10.1016/j.chemosphere.2017.04.152
2. [2]
  M.H. Cui, L. Gao, H.S. Lee, A.J. Wang, Bioresour. Technol. 297 (2020) 122420. doi: 10.1016/j.biortech.2019.122420
3. [3]
  P. Liu, L. Xing, H. Lin, et al., Sci. Bull. 62 (2017) 931-937. doi: 10.1016/j.scib.2017.05.031
4. [4]
  J. Wu, Q. Li, W. Li, et al., J. Cleaner Prod. 251 (2020) 119694. doi: 10.1016/j.jclepro.2019.119694
5. [5]
  L. Zeng, L. Xiao, X. Shi, et al., J. Colloid Interface Sci. 534 (2019) 586-594. doi: 10.1016/j.jcis.2018.09.074
6. [6]
  M. Aleksić, H. Kušić, N. Koprivanac, D. Leszczynska, A.L. Božić, Desalination 257 (2010) 22-29. doi: 10.1016/j.desal.2010.03.016
7. [7]
  X. Wang, Y. Pan, Z. Zhu, J. Wu, Chemosphere 117 (2014) 638-643. doi: 10.1016/j.chemosphere.2014.09.055
8. [8]
  S. Rodríguez, D. Lorenzo, A. Santos, A. Romero, J. Environ. Manage. 255 (2020) 109926. doi: 10.1016/j.jenvman.2019.109926
9. [9]
  B. Kakavandi, A. Takdastan, N. Jaafarzadeh, et al., J. Photochem. Photobiol. A 314 (2016) 178-188. doi: 10.1016/j.jphotochem.2015.08.008
10. [10]
  J. Seo, H.J. Lee, H. Lee, et al., Chem. Eng. J. 273 (2015) 502-508. doi: 10.1016/j.cej.2015.03.114
11. [11]
  M. Cheng, C. Lai, Y. Liu, et al., Coord. Chem. Rev. 368 (2018) 80-92. doi: 10.1016/j.ccr.2018.04.012
12. [12]
  Y. Zhang, M. Zhou, J. Hazard. Mater. 362 (2019) 436-450.
13. [13]
  A.D. Bokare, W. Choi, J. Hazard. Mater. 275 (2014) 121-135. doi: 10.1016/j.jhazmat.2014.04.054
14. [14]
  S. Hu, Y. Yu, Y. Guan, et al., Chin. Chem. Lett. 31 (2020) 2839-2842. doi: 10.1016/j.cclet.2020.08.021
15. [15]
  H. Zhang, J. He, C. Zhai, M. Zhu, Chin. Chem. Lett. 30 (2019) 2338-2342. doi: 10.1016/j.cclet.2019.07.021
16. [16]
  S. Wacławek, H.V. Lutze, K. Grübel, et al., Chem. Eng. J. 330 (2017) 44-62. doi: 10.1016/j.cej.2017.07.132
17. [17]
  P. Hu, M. Long, Appl. Catal. B Environ. 181 (2016) 103-117. doi: 10.1016/j.apcatb.2015.07.024
18. [18]
  P. Shao, X. Duan, J. Xu, et al., J. Hazard. Mater. 322 (2017) 532-539. doi: 10.1016/j.jhazmat.2016.10.020
19. [19]
  M. Zhang, J. He, Y. Chen, et al., Chin. Chem. Lett. 31 (2020) 2721-2724. doi: 10.1016/j.cclet.2020.05.001
20. [20]
  Y. Pang, Y. Ruan, Y. Feng, et al., Chemosphere 228 (2019) 412-417. doi: 10.1016/j.chemosphere.2019.04.164
21. [21]
  X. Lin, Y. Ma, J. Wan, Y. Wang, Y. Li, Appl. Catal. A 589 (2020) 117307. doi: 10.1016/j.apcata.2019.117307
22. [22]
  Y. Zhao, G. Wang, L. Li, X. Dong, X. Zhang, Chemosphere 244 (2020) 125526. doi: 10.1016/j.chemosphere.2019.125526
23. [23]
  Y. Li, L. Pan, Y. Zhu, et al., Water Res. 163 (2019) 114912. doi: 10.1016/j.watres.2019.114912
24. [24]
  Z. Yang, Y. Li, X. Zhang, et al., Chem. Eng. J. 384 (2020) 123319. doi: 10.1016/j.cej.2019.123319
25. [25]
  J. Sharma, I.M. Mishra, D.D. Dionysiou, V. Kumar, Chem. Eng. J. 276 (2015) 193-204. doi: 10.1016/j.cej.2015.04.021
26. [26]
  X. Zhang, J. Yao, Z. Zhao, J. Liu, Chem. Eng. J. 364 (2019) 1-10. doi: 10.1145/3290605.3300242
27. [27]
  S. Su, W. Guo, C. Yi, Y. Leng, Z. Ma, Ultrason. Sonochem. 19 (2012) 469-474.
28. [28]
  C. Cai, H. Zhang, X. Zhong, L. Hou, J. Hazard. Mater. 283 (2015) 70-79.
29. [29]
  H. Liu, P. Sun, M. Feng, et al., Appl. Catal. B-Environ. 187 (2016) 1-10. doi: 10.1080/13607863.2016.1269148
30. [30]
  Y. Wang, S. Hui, S. Zhan, et al., Chem. Eng. J. 381 (2020).
31. [31]
  J. Zhou, W. Liu, W. Cai, Sci. Total Environ. 696 (2019) 133962.
32. [32]
  J. Li, M. Xu, G. Yao, B. Lai, Chem. Eng. J. 348 (2018) 1012-1024.
33. [33]
  Y. Ren, L. Lin, J. Ma, et al., Appl. Catal. B-Environ. 165 (2015) 572-578.
34. [34]
  W.D. Oh, V.W.C. Chang, Z.T. Hu, R. Goei, T.T. Lim, Chem. Eng. J. 323 (2017) 260-269.
35. [35]
  Z. Huang, Y. Yao, J. Lu, et al., J. Hazard. Mater. 301 (2016) 214-221.
36. [36]
  Y. Yao, Y. Cai, G. Wu, et al., J. Hazard. Mater. 296 (2015) 128-137.
37. [37]
  H. Zhang, C. Lu, H. Hou, Y. Ma, S. Yuan, Chem. Eng. J. 370 (2019) 400-408.
38. [38]
  T. Sharifi, C. Larsen, J. Wang, et al., Adv. Energy Mater. 6 (2016) 1600738. doi: 10.1002/aenm.201600738
39. [39]
  W. Zhang, Y. Su, X. Zhang, Y. Yang, X. Guo, RSC Adv. 6 (2016) 64626-64633. doi: 10.1039/C6RA12706A
40. [40]
  X. Tian, C. Tian, Y. Nie, et al., Chem. Eng. J. 331 (2018) 144-151.
41. [41]
  C. Jiang, Y. Ji, Y. Shi, J. Chen, T. Cai, Water Res. 106 (2016) 507-517.
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NiCo2O4 hollow microsphere–mediated ultrafast peroxymonosulfate activation for dye degradation

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通讯作者: 陈斌, bchen63@163.com

NiCo₂O₄ hollow microsphere–mediated ultrafast peroxymonosulfate activation for dye degradation