Citation: Qi Huang, Yizhong Zhang, Wei Zhou, Xiang Huang, Yiliang Chen, Xin Tan, Tao Yu. Amorphous molybdenum sulfide mediated EDTA with multiple active sites to boost heavy metal ions removal[J]. Chinese Chemical Letters, ;2021, 32(9): 2797-2802. doi: 10.1016/j.cclet.2020.12.020 shu

Amorphous molybdenum sulfide mediated EDTA with multiple active sites to boost heavy metal ions removal

Qi Huang ^{b, e, 1} ,
Yizhong Zhang ^{b, 1} ,
Wei Zhou ^d ,
Xiang Huang ^c ,
Yiliang Chen ^a ,
Xin Tan ^{b, c} ,
Tao Yu ^{a, *,}

a.
School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, China
b.
School of Environmental Science and Engineering, Tianjin University, Tianjin 300350, China
c.
School of Science, Tibet University, Lhasa 850000, China
d.
School of Science, Tianjin University, Tianjin 300350, China
e.
Research Center of Environmental Pollution Control Engineering Technology, Chinese Research Academy of Environmental Sciences, Beijing 100012, China

yutao@tju.edu.cn

Received Date: 14 October 2020
Revised Date: 16 November 2020
Accepted Date: 11 December 2020
Available Online: 16 December 2020

Figures(7)

The rational design of strong affinity adsorbents for heavy metal ions removal remains a critical challenge for water treatment. In this study, amorphous molybdenum sulfide composites (EDTA-MoS_x (x=2, 3)) were fabricated via a facile hydrothermal method mediated by EDTA, which was applied to heavy metal ions (Cu²⁺, Cd²⁺, Pb²⁺, Zn²⁺ and Ni²⁺) removal from aqueous solutions. A case study for Cu²⁺ ions showed that the adsorption capacity of EDTA-MoS_x (x=2, 3) was superior to crystalline phase MoS₂ at pH 6.0 with an initial concentration of 200 mg/L. Adsorption mechanisms of different sulfide groups and －COOH of EDTA-MoS_x (x=2, 3) were verified systematically via a series of experiments, characterizations, and density functional theory (DFT) calculations. Both bridging S₂²⁻ and －COOH covalently bonded with Cu²⁺ ions were ascribed to the critical factors for this enhanced removal efficiency on the surface of EDTA-MoS_x (x=2, 3). This work offers a new method to enhance the adsorption performance of molybdenum sulfide-based materials by controlling crystallinity mediated with an organic complex small molecule.
- Amorphous phase,
- MoS₂,
- MoS₃,
- Adsorption,
- Heavy metal ions,
- DFT calculations
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