Citation: Feihu Mu, Benlin Dai, Wei Zhao, Xiaofan Yang, Xiaolong Zhao, Xujing Guo. In-situ construction of amorphous/crystalline contact Bi₂S₃/Bi₄O₇ heterostructures for enhanced visible-light photocatalysis[J]. Chinese Chemical Letters, ;2021, 32(8): 2539-2543. doi: 10.1016/j.cclet.2020.12.016 shu

In-situ construction of amorphous/crystalline contact Bi₂S₃/Bi₄O₇ heterostructures for enhanced visible-light photocatalysis

Feihu Mu ^{a, 1} ,
Benlin Dai ^{a, 1} ,
Wei Zhao ^a ,
Xiaofan Yang ^a ,
Xiaolong Zhao ^b ,
Xujing Guo ^{c, *,}

a.
Jiangsu Key Laboratory for Chemistry of Low-Dimensional Materials, Jiangsu Collaborative Innovation Center of Regional Modern Agriculture and Environmental Protection, School of Chemistry and Chemical Engineering, Huaiyin Normal University, Huaian 223300, China
b.
Department of Mechanical Engineering, The University of Hong Kong, Hong Kong, China
c.
College of Resources and Environment, Chengdu University of Information Technology, Chengdu 610225, China

gxj530520@126.com

Received Date: 5 September 2020
Revised Date: 12 November 2020
Accepted Date: 10 December 2020
Available Online: 16 December 2020

Figures(4)

Constructing a heterojunction photocatalyst is a significant method to enhance photocatalytic activity because it can promote the separation of photogenerated carriers. Herein, amorphous/crystalline contact Bi₂S₃/Bi₄O₇ heterostructure was successfully synthesized by in-situ sulfidation of Bi₄O₇. The amorphous Bi₂S₃ is diffused on the surface of Bi₄O₇ rod, enhancing the visible light response and improving the transport of photogenerated carriers. Various characterizations confirm that the rapid separation of photogenerated carriers leads to increased photocatalytic performance. The optimized Bi₂S₃/Bi₄O₇ heterostructure photocatalyst (BiS-0.15) exhibits the highest Cr(VI) reduction (0.01350 min⁻¹) and RhB oxidation (0.08011 min⁻¹) activity, which is much higher than that of pure Bi₄O₇ and Bi₂S₃/Bi₄O₇ mixture under visible light irradiation. This work provides new insights into the construction of efficient novel photocatalysts.
- Photocatalysis,
- Cr(VI) reduction,
- Heterojunction,
- Bismuth-based oxide,
- Bismuth-based sulfide
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In-situ construction of amorphous/crystalline contact Bi2S3/Bi4O7 heterostructures for enhanced visible-light photocatalysis

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In-situ construction of amorphous/crystalline contact Bi₂S₃/Bi₄O₇ heterostructures for enhanced visible-light photocatalysis