Citation: Guangze Nie, Shijun Qiu, Xiang Wang, Yan Du, Qingrui Zhang, Yang Zhang, Hengle Zhang. A millimeter-sized negatively charged polymer embedded with molybdenum disulfide nanosheets for efficient removal of Pb(Ⅱ) from aqueous solution[J]. Chinese Chemical Letters, ;2021, 32(7): 2342-2346. doi: 10.1016/j.cclet.2020.12.014 shu

A millimeter-sized negatively charged polymer embedded with molybdenum disulfide nanosheets for efficient removal of Pb(Ⅱ) from aqueous solution

Guangze Nie ^{a, *,} ,
Shijun Qiu ^a ,
Xiang Wang ^a ,
Yan Du ^a ,
Qingrui Zhang ^{b, *,} ,
Yang Zhang ^a ,
Hengle Zhang ^a

a.
School of Environmental Science and Engineering, Nanjing Tech University, Nanjing 211816, China
b.
Hebei Key Laboratory of Heavy Metal Deep-Remediation in Water and Resource Reuse, Yanshan University, Qinhuangdao 066004, China

gznie@njtech.edu.cn

zhangqr@ysu.edu.cn

Received Date: 3 October 2020
Revised Date: 6 November 2020
Accepted Date: 3 December 2020
Available Online: 15 December 2020

Figures(5)

Molybdenum disulfide (MoS₂) has excellent trapping ability for lead ions whereas its micro-/nanoscale size has greatly impeded its practical applications in the flow-through systems. Herein, a millimeter-sized nanocomposite MoS2−001 was synthesized for Pb²⁺ removal by loading MoS₂ nanosheets into a polystyrene cation exchanger D-001 by a facile hydrothermal method. The proposed structure and adsorption mechanism of MoS₂−001 was confirmed by the scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS) analysis. The nanocomposite showed outstanding adsorption capacity and rapid adsorption kinetic for Pb²⁺ removal, and the adsorption behavior followed the Langmuir adsorption model and pseudo-first-model kinetic model. Pb²⁺ uptake by MoS₂−001 still maintains a high level even in the presence of extremely highly competitive ions (Ca(Ⅱ) and Mg(Ⅱ)), suggesting its high selectivity for Pb²⁺ adsorption. Besides, the fixed-bed column experiments further certified that MoS₂−001 is of great potential for Pb²⁺ removal from the wastewater in practical engineering applications. Even more gratifying is that the exhausted MoS₂−001 can be regenerated by NaCl-EDTANa₂ solution without any significant adsorption capacity loss. Consequently, all the results indicated that MoS₂−001 is a promising candidate adsorbent for lead-containing wastewater treatment.
- Molybdenum disulfide,
- Polystyrene host,
- Lead removal,
- Nanocomposite,
- Adsorption
1. [1]
  W. Liu, J. Tian, L. Chen, Y. Guo, Environ. Pollut. 220 (2017) 696-703. doi: 10.1016/j.envpol.2016.10.031
2. [2]
  Y. Liu, T. Li, C. Ling, et al., Chin. Chem. Lett. 30 (2019) 2211-2215. doi: 10.1016/j.cclet.2019.05.020
3. [3]
  Q. Yang, Z. Li, X. Lu, et al., Sci. Total. Environ. 642 (2018) 690-700. doi: 10.1016/j.scitotenv.2018.06.068
4. [4]
  L.N. Hu, Z.G. Ren, Chin, Chem. Lett. 20 (2009) 334-338. doi: 10.1016/j.cclet.2008.12.006
5. [5]
  P. Zhang, S. Ouyang, P. Li, et al., J. Clean. Prod. 246 (2020) 118728. doi: 10.1016/j.jclepro.2019.118728
6. [6]
  S. Bao, K. Li, P. Ning, et al., Appl. Surf. Sci. 393 (2017) 457-466. doi: 10.1016/j.apsusc.2016.09.098
7. [7]
  A. Shahat, H.M.A. Hassan, H.M.E. Azzazy, et al., Chem. Eng. J. 332 (2018) 377-386. doi: 10.1016/j.cej.2017.09.040
8. [8]
  H.J. Mansoorian, A.H. Mahvi, A.J. Jafari., Sep. Purif. Technol. 135 (2014) 165-175. doi: 10.1016/j.seppur.2014.08.012
9. [9]
  P. Yenphan, A. Chanachai, R. Jiraratananon, Desalination 253 (2010) 30-37. doi: 10.1016/j.desal.2009.11.040
10. [10]
  Y. Li, M. Li, J. Zhang, X. Xu., Chin. Chem. Lett. 30 (2019) 762-766. doi: 10.1016/j.cclet.2018.11.005
11. [11]
  M.I. Shariful, S.B. Sharif, J.J.L. Lee, et al., Carbohydr. Polym. 157 (2017) 57-64. doi: 10.1016/j.carbpol.2016.09.063
12. [12]
  M. Zhang, F. Jia, M. Dai, S. Song, Appl. Surf. Sci. 455 (2018) 258-266. doi: 10.1016/j.apsusc.2018.05.207
13. [13]
  X. Sun, Z. Wang. Appl. Surf. Sci. 455 (2018) 911-918. doi: 10.1016/j.apsusc.2018.06.032
14. [14]
  F. Chen, L. Wu, Z. Zhou, et al., Chin. Chem. Lett. 30 (2019) 197-202. doi: 10.1016/j.cclet.2018.10.007
15. [15]
  S. Ridene, Superlattice. Microst. 114 (2018) 379-385. doi: 10.1016/j.spmi.2017.12.060
16. [16]
  U. Khan, T.H. Kim, M.A. Khan, et al., Nano Energy 75 (2020) 104936. doi: 10.1016/j.nanoen.2020.104936
17. [17]
  Z. Wang, A. Sim, J.J. Urban, B. Mi, Environ. Sci. Technol. 52 (2018) 9741-9748. doi: 10.1021/acs.est.8b01705
18. [18]
  C. Liu, Q. Wang, F. Jia, S. Song, J. Mol. Liq. 292 (2019) 111390. doi: 10.1016/j.molliq.2019.111390
19. [19]
  Q. Wang, L. Yang, F. Jia, Y. Li, S. Song, J. Mol. Liq. 263 (2018) 526-533. doi: 10.1016/j.molliq.2018.04.149
20. [20]
  H. Wang, F. Wen, X. Li, et al., Sep. Purif. Technol. 170 (2016) 190-198. doi: 10.1007/s10753-015-0238-6
21. [21]
  H. Tian, J. He, M. Hu, J Colloid Interface Sci. 551 (2019) 251-260. doi: 10.1016/j.jcis.2019.05.027
22. [22]
  C. Liu, S. Zeng, B. Yang, F. Jia, S. Song, J. Mol. Liq. 296 (2019) 111987. doi: 10.1016/j.molliq.2019.111987
23. [23]
  M.J. Aghagoli, M. Hossein Beyki, F. Shemirani, Food Chem. 223 (2017) 8-15. doi: 10.1016/j.foodchem.2016.12.023
24. [24]
  Z. Wang, B. Mi, Environ. Sci. Technol. 51 (2017) 8229-8244. doi: 10.1021/acs.est.7b01466
25. [25]
  L. Luo, M. Shi, S. Zhao, et al., J. Saudi. Chem. Soc. 23 (2019) 762-773. doi: 10.1016/j.jscs.2019.01.005
26. [26]
  R. Li, H. Deng, X. Zhang, et al., Bioresource. Technol. 273 (2019) 335-340. doi: 10.1016/j.biortech.2018.10.053
27. [27]
  Y. Song, M. Lu, B. Huang, et al., J. Alloy. Compd. 737 (2018) 113-121. doi: 10.1016/j.jallcom.2017.12.087
28. [28]
  J. Wang, W. Zhang, X. Yue, et al., J. Mater. Chem. A 4 (2016) 3893-3900. doi: 10.1039/C6TA00269B
29. [29]
  Z. Wang, J. Zhang, T. Wen, et al., Sci. Total. Environ. 699 (2019) 134341. doi: 10.1016/j.scitotenv.2019.134341
30. [30]
  J. Qian, X. Gao, B. Pan, Environ. Sci. Technol. 54 (2020) 8509-8526. doi: 10.1021/acs.est.0c01065
31. [31]
  B. Pan, X. Zhang, Z. Jiang, et al., Polymer and Polymer-Based Nanocomposite Adsorbents for Water Treatment, in: Das R. (Eds. ), Polymeric Materials for Clean Water, Springer, Cham. 2019, pp. 93-119.
32. [32]
  G. Nie, L. Wu, Y. Du, et al., Chem. Eng. J. 360 (2019) 1128-1136. doi: 10.1016/j.cej.2018.10.184
33. [33]
  H. Cao, Z. Bai, Y. Li, et al., ACS Sustain. Chem. Eng. 8 (2020) 7343-7352. doi: 10.1021/acssuschemeng.0c00736
34. [34]
  P. Afanasiev, C. Geantet, I. Llorens, O. Proux, J. Mater. Chem. 22 (2012) 9731– 9737. doi: 10.1039/c2jm30377a
35. [35]
  K. Ai, C. Ruan, M. Shen, L. Lu, Adv. Funct. Mater. 26 (2016) 5542-5549. doi: 10.1002/adfm.201601338
36. [36]
  R.S. Juang, S.H. Lin, T.Y. Wang, Chemosphere 53 (2003) 1221-1228. doi: 10.1016/S0045-6535(03)00578-2
37. [37]
  Y. Du, S. Qiu, X. Zhang, G. Nie, Chem. Eng. J. 400 (2020) 125907. doi: 10.1016/j.cej.2020.125907
38. [38]
  Y. Hu, Y. Du, G. Nie, et al., Sci. Total. Environ. 700 (2020) 134999. doi: 10.1016/j.scitotenv.2019.134999
39. [39]
  Q. Zhang, J. Teng, Z. Zhang, et al., RSC Adv. 5 (2015) 55445-55452. doi: 10.1039/C5RA09628F
40. [40]
  C.D. Shuang, F. Yang, F. Pan, et al. Chin. Chem. Lett. 22 (2011) 1091-1094. doi: 10.1016/j.cclet.2011.04.009
41. [41]
  Y.S. Ho, G. McKay. Process Biochem. 34 (1999) 451-465. doi: 10.1016/S0032-9592(98)00112-5
42. [42]
  S. Sarkar, P.K. Chatterjee, L.H. Cumbal, A.K. SenGupta, Chem. Eng. J. 166 (2011) 923-931. doi: 10.1016/j.cej.2010.11.075
43. [43]
  X. Luo, Z. Huang, J. Lin, et al. J. Clean. Prod. 258 (2020) 120991. doi: 10.1016/j.jclepro.2020.120991
44. [44]
  Y. Liu, J. Xu, Z. Cao, R. et al. J. Colloid. Inter. Sci. 559 (2020) 215-225. doi: 10.1016/j.jcis.2019.10.035
45. [45]
  A.A. Alqadami, M. Naushad, Z.A. Alothman, M. Alsuhybani, M. Algamdi. J. Hazard. Mater. 389 (2020) 121896. doi: 10.1016/j.jhazmat.2019.121896
46. [46]
  P.L. Yap, Y.L. Auyoong, K. Hassan, et al. Chem. Eng. J. 395 (2020) 124965. doi: 10.1016/j.cej.2020.124965
47. [47]
  C. Chen, Q. Chen, J. Kang, et al. J. Mol. Liq. 298 (2020) 112031. doi: 10.1016/j.molliq.2019.112031
48. [48]
  M. Dinari, S. Neamati. Colloid. Surface. A. 589 (2020) 124438. doi: 10.1016/j.colsurfa.2020.124438
49. [49]
  C.X. Li, J.M. Pan, J. Gao, Y.S. Yan, G.Q. Zhao. Chin. Chem. Lett. 20 (2009) 985-989. doi: 10.1016/j.cclet.2009.03.020
50. [50]
  F. Jia, Q. Wang, J. Wu, Y. Li, S. Song. ACS Sustain. Chem. Eng. 5 (2017) 7410-7419. doi: 10.1021/acssuschemeng.7b01880
51. [51]
  Q. Huang, J. Zhao, M. Liu, et al. J. Taiwan. Inst. Chem. E., 86 (2018) 174-184. doi: 10.1016/j.jtice.2017.12.027
52. [52]
  B. Pan, H. Qiu, B. Pan, G. et al. Water Res, 44 (2010) 815-824. doi: 10.1016/j.watres.2009.10.027
53. [53]
  N. Kumar, E. Fosso-Kankeu, S.S. Ray. ACS Appl. Mater. Inter. 11 (2019) 19141-19155. doi: 10.1021/acsami.9b03853
1. [1]
  Yue Li , Minghao Fan , Conghui Wang , Yanxun Li , Xiang Yu , Jun Ding , Lei Yan , Lele Qiu , Yongcai Zhang , Longlu Wang . 3D layer-by-layer amorphous MoS_x assembled from [Mo₃S₁₃]^2- clusters for efficient removal of tetracycline: Synergy of adsorption and photo-assisted PMS activation. Chinese Chemical Letters, 2024, 35(9): 109764-. doi: 10.1016/j.cclet.2024.109764
2. [2]
  Chong Liu , Nanthi Bolan , Anushka Upamali Rajapaksha , Hailong Wang , Paramasivan Balasubramanian , Pengyan Zhang , Xuan Cuong Nguyen , Fayong Li . Critical review of biochar for the removal of emerging inorganic pollutants from wastewater. Chinese Chemical Letters, 2025, 36(2): 109960-. doi: 10.1016/j.cclet.2024.109960
3. [3]
  Mengyuan Li , Xitong Ren , Yanmei Gao , Mengyao Mu , Shiping Zhu , Shufang Tian , Minghua Lu . Constructing bifunctional magnetic porous poly(divinylbenzene) polymer for high-efficient removal and sensitive detection of bisphenols. Chinese Chemical Letters, 2024, 35(12): 109699-. doi: 10.1016/j.cclet.2024.109699
4. [4]
  Xudong Zhao , Yuxuan Wang , Xinxin Gao , Xinli Gao , Meihua Wang , Hongliang Huang , Baosheng Liu . Anchoring thiol-rich traps in 1D channel wall of metal-organic framework for efficient removal of mercury ions. Chinese Chemical Letters, 2025, 36(2): 109901-. doi: 10.1016/j.cclet.2024.109901
5. [5]
  Jiaxuan Wang , Tonghe Liu , Bingxiang Wang , Ziwei Li , Yuzhong Niu , Hou Chen , Ying Zhang . Synthesis of polyhydroxyl-capped PAMAM dendrimer/silica composites for the adsorption of aqueous Hg(II) and Ag(I). Chinese Chemical Letters, 2024, 35(12): 109900-. doi: 10.1016/j.cclet.2024.109900
6. [6]
  Fengxing Liang , Yongzheng Zhu , Nannan Wang , Meiping Zhu , Huibing He , Yanqiu Zhu , Peikang Shen , Jinliang Zhu . Recent advances in copper-based materials for robust lithium polysulfides adsorption and catalytic conversion. Chinese Chemical Letters, 2024, 35(11): 109461-. doi: 10.1016/j.cclet.2023.109461
7. [7]
  Congyan Liu , Xueyao Zhou , Fei Ye , Bin Jiang , Bo Liu . Confined electric field in nano-sized channels of ionic porous framework towards unique adsorption selectivity. Chinese Chemical Letters, 2025, 36(2): 109969-. doi: 10.1016/j.cclet.2024.109969
8. [8]
  Zixuan Zhu , Xianjin Shi , Yongfang Rao , Yu Huang . Recent progress of MgO-based materials in CO₂ adsorption and conversion: Modification methods, reaction condition, and CO₂ hydrogenation. Chinese Chemical Letters, 2024, 35(5): 108954-. doi: 10.1016/j.cclet.2023.108954
9. [9]
  Ziyang Yin , Lingbin Xie , Weinan Yin , Ting Zhi , Kang Chen , Junan Pan , Yingbo Zhang , Jingwen Li , Longlu Wang . Advanced development of grain boundaries in TMDs from fundamentals to hydrogen evolution application. Chinese Chemical Letters, 2024, 35(5): 108628-. doi: 10.1016/j.cclet.2023.108628
10. [10]
  Fereshte Hassanzadeh-Afruzi , Mina Azizi , Iman Zare , Ehsan Nazarzadeh Zare , Anwarul Hasan , Siavash Iravani , Pooyan Makvandi , Yi Xu . Advanced metal-organic frameworks-polymer platforms for accelerated dermal wound healing. Chinese Chemical Letters, 2024, 35(11): 109564-. doi: 10.1016/j.cclet.2024.109564
11. [11]
  Linshan Peng , Qihang Peng , Tianxiang Jin , Zhirong Liu , Yong Qian . Highly efficient capture of thorium ion by citric acid-modified chitosan gels from aqueous solution. Chinese Chemical Letters, 2024, 35(5): 108891-. doi: 10.1016/j.cclet.2023.108891
12. [12]
  Xiao-Hong Yi , Chong-Chen Wang . Metal-organic frameworks on 3D interconnected macroporous sponge foams for large-scale water decontamination: A mini review. Chinese Chemical Letters, 2024, 35(5): 109094-. doi: 10.1016/j.cclet.2023.109094
13. [13]
  Haodong Wang , Xiaoxu Lai , Chi Chen , Pei Shi , Houzhao Wan , Hao Wang , Xingguang Chen , Dan Sun . Novel 2D bifunctional layered rare-earth hydroxides@GO catalyst as a functional interlayer for improved liquid-solid conversion of polysulfides in lithium-sulfur batteries. Chinese Chemical Letters, 2024, 35(5): 108473-. doi: 10.1016/j.cclet.2023.108473
14. [14]
  Dan Luo , Jinya Tian , Jianqiao Zhou , Xiaodong Chi . Anthracene-bridged "Texas-sized" box for the simultaneous detection and uptake of tryptophan. Chinese Chemical Letters, 2024, 35(9): 109444-. doi: 10.1016/j.cclet.2023.109444
15. [15]
  Hong-Rui Li , Xia Kang , Rui Gao , Miao-Miao Shi , Bo Bi , Ze-Yu Chen , Jun-Min Yan . Interfacial interactions of Cu/MnOOH enhance ammonia synthesis from electrochemical nitrate reduction. Chinese Chemical Letters, 2025, 36(2): 109958-. doi: 10.1016/j.cclet.2024.109958
16. [16]
  Ping Wang , Ting Wang , Ming Xu , Ze Gao , Hongyu Li , Bowen Li , Yuqi Wang , Chaoqun Qu , Ming Feng . Keplerate polyoxomolybdate nanoball mediated controllable preparation of metal-doped molybdenum disulfide for electrocatalytic hydrogen evolution in acidic and alkaline media. Chinese Chemical Letters, 2024, 35(7): 108930-. doi: 10.1016/j.cclet.2023.108930
17. [17]
  Shuqi Yu , Yu Yang , Keisuke Kuroda , Jian Pu , Rui Guo , Li-An Hou . Selective removal of Cr(Ⅵ) using polyvinylpyrrolidone and polyacrylamide co-modified MoS₂ composites by adsorption combined with reduction. Chinese Chemical Letters, 2024, 35(6): 109130-. doi: 10.1016/j.cclet.2023.109130
18. [18]
  Yan Wang , Huixin Chen , Fuda Yu , Shanyue Wei , Jinhui Song , Qianfeng He , Yiming Xie , Miaoliang Huang , Canzhong Lu . Oxygen self-doping pyrolyzed polyacrylic acid as sulfur host with physical/chemical adsorption dual function for lithium-sulfur batteries. Chinese Chemical Letters, 2024, 35(7): 109001-. doi: 10.1016/j.cclet.2023.109001
19. [19]
  Jing Wang , Pingping Li , Yuehui Wang , Yifan Xiu , Bingqian Zhang , Shuwen Wang , Hongtao Gao . Treatment and Discharge Evaluation of Phosphorus-Containing Wastewater. University Chemistry, 2024, 39(5): 52-62. doi: 10.3866/PKU.DXHX202309097
20. [20]
  Guang Huang , Lei Li , Dingyi Zhang , Xingze Wang , Yugai Huang , Wenhui Liang , Zhifen Guo , Wenmei Jiao . Cobalt’s Valor, Nickel’s Foe: A Comprehensive Chemical Experiment Utilizing a Cobalt-based Imidazolate Framework for Nickel Ion Removal. University Chemistry, 2024, 39(8): 174-183. doi: 10.3866/PKU.DXHX202311051

Get Citation

PDF

XML

Metrics

PDF Downloads(5)
Abstract views(1144)
HTML views(201)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142