Citation: Mingsheng Xu, Mingze Sun, Sajid ur Rehman, Kangkang Ge, Xiaolong Hu, Haizhen Ding, Jichang Liu, Hong Bi. One-pot synthesis of CoO-ZnO/rGO supported on Ni foam for high-performance hybrid supercapacitor with greatly enhanced cycling stability[J]. Chinese Chemical Letters, ;2021, 32(6): 2027-2032. doi: 10.1016/j.cclet.2020.12.011 shu

One-pot synthesis of CoO-ZnO/rGO supported on Ni foam for high-performance hybrid supercapacitor with greatly enhanced cycling stability

Mingsheng Xu ^{a, 1} ,
Mingze Sun ^{a, 1} ,
Sajid ur Rehman ^a ,
Kangkang Ge ^a ,
Xiaolong Hu ^a ,
Haizhen Ding ^a ,
Jichang Liu ^b ,
Hong Bi ^{a, *,}

a.
School of Chemistry and Chemical Engineering, Anhui University, Hefei 230601, China
b.
State Key Laboratory of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China

bihong@ahu.edu.cn

Received Date: 6 November 2020
Revised Date: 6 December 2020
Accepted Date: 7 December 2020
Available Online: 11 December 2020

Figures(4)

The high specific capacitance along with good cycling stability are crucial for practical applications of supercapacitors, which always demands high-performance and stable electrode materials. In this work, we report a series of ternary composites of CoO-ZnO with different fractions of reduced graphene oxide (rGO) synthesized by in-situ growth on nickel foam, named as CZG-1, 2 and 3, respectively. This sort of binder-free electrodes presents excellent electrochemical properties as well as large capacitance due to their low electrical resistance and high oxygen vacancies. Particularly, the sample of CZG-2 (CoO-ZnO/rGO 20 mg) in a nanoreticular structure shows the best electrochemical performance with a maximum specific capacitance of 1951.8 F/g (216.9 mAh/g) at a current intensity of 1 A/g. The CZG-2-based hybrid supercapacitor delivers a high energy density up to 45.9 Wh/kg at a high power density of 800 W/kg, and kept the capacitance retention of 90.1% over 5000 charge-discharge cycles.
- Supercapacitor,
- Metal oxide,
- Graphene oxide,
- Energy density,
- Cycling stability
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