Citation: Liushan Jiang, Yu Xie, Fan He, Yun Ling, Jinsheng Zhao, Hao Ye, Shiqian Li, Jiangli Wang, Yang Hou. Facile synthesis of GO as middle carrier modified flower-like BiOBr and C₃N₄ nanosheets for simultaneous treatment of chromium(Ⅵ) and tetracycline[J]. Chinese Chemical Letters, ;2021, 32(7): 2187-2191. doi: 10.1016/j.cclet.2020.12.010 shu

Facile synthesis of GO as middle carrier modified flower-like BiOBr and C₃N₄ nanosheets for simultaneous treatment of chromium(Ⅵ) and tetracycline

Liushan Jiang ^a ,
Yu Xie ^{a, **,} ,
Fan He ^b ,
Yun Ling ^a ,
Jinsheng Zhao ^{c, **,} ,
Hao Ye ^a ,
Shiqian Li ^a ,
Jiangli Wang ^a ,
Yang Hou ^{b, d, *,}

a.
College of Environment and Chemical Engineering, Nanchang Hangkong University, Nanchang 330063, China
b.
Key Laboratory of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China
c.
College of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, China
d.
Ningbo Research Institute, Zhejiang University, Ningbo 315100, China

^**

xieyu_121@163.com

j.s.zhao@163.com

yhou@zju.edu.cn

Received Date: 18 September 2020
Revised Date: 6 November 2020
Accepted Date: 4 December 2020
Available Online: 11 December 2020

Figures(4)

A novel GO modified g-C₃N₄ nanosheets/flower-like BiOBr hybrid photocatalyst is fabricated by a facile method. The characterization results reveal that wrinkled GO is deposited between g-C₃N₄ nanosheets and flower-like BiOBr forming a Z-scheme heterojunction. As a mediator, plicate GO plays a positive role in prompting photogenerated electrons transferring through its sizeable 2D/2D contact surface area. The g-C₃N₄/GO/BiOBr hybrid displays a superior photocatalytic ability to g-C₃N₄ and BiOBr in photodegrading tetracycline (TC), whose removal efficiency could reach 96% within 2 h. Besides, g-C₃N₄/GO/BiOBr composite can reduce Cr(Ⅵ), and simultaneously treat TC and Cr(Ⅵ) combination contaminant under the visible light. The g-C₃N₄/GO/BiOBr ternary composite also exhibits satisfactory stability and reusability after four cycling experiments. Further, a feasible mechanism related to the photocatalytic process of g-C₃N₄/GO/BiOBr is put forward. This study offers a ternary hybrid photocatalyst with eco-friendliness and hopeful application in water pollution.
- Ternary heterojunction,
- Photocatalysis,
- Tetracycline degradation,
- Cr(Ⅵ) reduction
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沈阳化工大学材料科学与工程学院沈阳 110142

Facile synthesis of GO as middle carrier modified flower-like BiOBr and C3N4 nanosheets for simultaneous treatment of chromium(Ⅵ) and tetracycline

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通讯作者: 陈斌, bchen63@163.com

Facile synthesis of GO as middle carrier modified flower-like BiOBr and C₃N₄ nanosheets for simultaneous treatment of chromium(Ⅵ) and tetracycline