Citation: Xiran Zhu, Zheng Hu, Ming Huang, Yuxin Zhao, Jianqiang Qu, Shi Hu. Au nanowires with high aspect ratio and atomic shell of Pt-Ru alloy for enhanced methanol oxidation reaction[J]. Chinese Chemical Letters, ;2021, 32(6): 2033-2037. doi: 10.1016/j.cclet.2020.11.071 shu

Au nanowires with high aspect ratio and atomic shell of Pt-Ru alloy for enhanced methanol oxidation reaction

Xiran Zhu ^a ,
Zheng Hu ^a ,
Ming Huang ^c ,
Yuxin Zhao ^{d, *,} ,
Jianqiang Qu ^{a, **,} ,
Shi Hu ^{a, b, **,}

a.
Tianjin Key Laboratory of Molecular Optoelectronic Science, Department of Chemistry, School of Science, Tianjin University, Tianjin 300072, China
b.
Institute of Energy, Hefei Comprehensive National Science Center, Hefei 230026, China
c.
School of Materials Science and Engineering, Nanjing University of Science and Technology, Nanjing 210094, China
d.
School of Chemical Engineering and Technology, Xi'an Jiaotong University, Xi'an 710049, China

^**

yuxinzhao@xjtu.edu.cn

jqqu@tju.edu.cn

rychushi@gmail.com

Received Date: 8 October 2020
Revised Date: 16 November 2020
Accepted Date: 27 November 2020
Available Online: 4 December 2020

Figures(4)

The methanol oxidation reaction (MOR) is the limiting half-reaction in direct methanol fuel cell (DMFC). Although Pt is the most active single-metal electrocatalyst for MOR, it is hampered by high cost and CO poisoning. Constructing a Pt or Ru monolayer on a second metal substrate by means of galvanic replacement of underpotentially deposited (UPD) Cu monolayer has been shown as an efficient catalyst design strategy for the electrocatalysis of MOR because of the presumed 100% utilization of atoms and resistance to CO poisoning. Herein, we prepared one-dimensional surface-alloyed electrocatalyst from predominantly (111) faceted Au nanowires with high aspect ratio as the substrate of under-potential deposition. The electrocatalyst comprises a core of the Au nanowire and a shell of catalytically active Pt coated by Ru. Coverage-dependent electro-catalytic activity and stability is demonstrated on the Pt/Ru submonolayers on Au wires for MOR. Among all these catalysts, Au@Pt_ML@Ru_ML exhibits the best electrocatalytic activity and poisoning tolerance to CO. This presents a viable method for the rational catalyst design for achieving high noble-metal utilization efficiency and high catalytic performance.
- Au nanowires,
- Pt/Ru submonolayers,
- Underpotentially deposited,
- Core-shell nanostructure,
- Methanol oxidation reaction
1. [1]
  L. Yang, J.H. Chen, X.X. Zhong, et al., Colloids Surf. A:Physicochem. Eng. Asp. 295(2007) 21-26. doi: 10.1016/j.colsurfa.2006.08.023
2. [2]
  H. Tang, J.H. Chen, M.Y. Wang, et al., Appl. Catal. A Gen. 275(2004) 43-48. doi: 10.1016/j.apcata.2004.07.018
3. [3]
  Y.Q. Kang, Q. Xue, Y. Zhao, et al., Small (2018) e1801239.
4. [4]
  S.L. Yin, Z.Q. Wang, X.Q. Qian, et al., ACS Sustainable Chem. Eng. 7(2019) 7960-7968. doi: 10.1021/acssuschemeng.9b00872
5. [5]
  J.Q. Chang, L.T. Song, Y.Q. Xu, et al., Nano Res. 13(2019) 67-71.
6. [6]
  K. He, T.T. Tsega, X. Liu, et al., Angew. Chem. 131(2019) 12029-12035. doi: 10.1002/ange.201905281
7. [7]
  L.Y. Peng, L. Gan, Y.P. Wei, et al., J. Phys. Chem. C 120(2016) 28664-28671. doi: 10.1021/acs.jpcc.6b10445
8. [8]
  W.J. Lei, M.G. Li, L. He, et al., Nano Res. 13(2020) 638-645. doi: 10.1007/s12274-020-2666-3
9. [9]
  C. Luo, J.H. Yang, J.L. Li, et al., J. Electroanal. Chem. 873(2020) 114423. doi: 10.1016/j.jelechem.2020.114423
10. [10]
  A.M. Fathi, H.T. Handal, A.A. El-Kady, Carbon Lett. 31(2021) 253-267. doi: 10.1007/s42823-020-00160-y
11. [11]
  C.W. Zhang, L.B. Xu, J.F. Chen, Chin. Chem. Lett. 27(2016) 832-836. doi: 10.1016/j.cclet.2016.02.025
12. [12]
  D. Ma, B. Hu, W.D. Wu, et al., Nat. Commun. 10(2019) 3367. doi: 10.1038/s41467-019-11176-y
13. [13]
  X.Y. Zhao, H.C. Zhao, J.F. Sun, G. Li, R. Liu, Chin. Chem. Lett. 31(2020) 1782-1786. doi: 10.1016/j.cclet.2020.01.005
14. [14]
  F. Chang, S. Shan, V. Petkov, et al., J. Am. Chem. Soc. 138(2016) 12166-12175. doi: 10.1021/jacs.6b05187
15. [15]
  W. Hong, J. Wang, E. Wang, Small 10(2014) 3262-3265. doi: 10.1002/smll.201400059
16. [16]
  T. Zhang, Y. Sun, X. Li, et al., Small Methods 4(2019) 1900709.
17. [17]
  S. Chen, S. Thota, X. Wang, J. Zhao, J. Mater. Chem. A 4(2016) 9038-9043. doi: 10.1039/C6TA02914K
18. [18]
  L. Huang, X. Zhang, Q. Wang, et al., J. Am. Chem. Soc. 140(2018) 1142-1147. doi: 10.1021/jacs.7b12353
19. [19]
  F. Amouzad, K. Zarei, J. Electron. Mater. 49(2020) 3583-3590. doi: 10.1007/s11664-020-08054-5
20. [20]
  N. Dimitrova, M. Dhifallah, T. Mineva, et al., RSC Adv. 9(2019) 2073-2080. doi: 10.1039/C8RA08782B
21. [21]
  W. Guo, X. Yao, L. Peng, et al., Chin. Chem. Lett. 31(2020) 836-840. doi: 10.1016/j.cclet.2019.06.018
22. [22]
  N. Aoki, H. Inoue, T. Okawa, et al., Electrocatalysis 9(2017) 125-138.
23. [23]
  M. Li, Q. Ma, W. Zi, et al., Sci. Adv. 1(2015) e1400268. doi: 10.1126/sciadv.1400268
24. [24]
  R. Liu, J.F. Liu, Z.M. Zhang, et al., J. Phys. Chem. Lett. 5(2014) 969-975. doi: 10.1021/jz500238z
25. [25]
  Z.Q. Niu, S.P. Chen, Y. Yu, et al., Nano Res. 13(2020) 2564-2569. doi: 10.1007/s12274-020-2900-z
26. [26]
  Y. Zhang, J. Zhang, Z. Chen, et al., Sci. China Mater. 61(2018) 697-706. doi: 10.1007/s40843-017-9157-9
27. [27]
  T.V. Cleve, S. Moniri, G. Belok, K.L. More, S. Linic, ACS Catal. 7(2016) 17-24.
28. [28]
  E. Herrero, L.J. Buller, H.D. Abruña, Chem. Rev. 101(2001) 1897-1930. doi: 10.1021/cr9600363
29. [29]
  D. Gokcen, Q. Yuan, S.R. Brankovic, J. Electrochem. Soc. 161(2014) D3051-D3056. doi: 10.1149/2.007407jes
30. [30]
  A. Kuzume, E. Herrero, J.M. Feliu, R.J. Nichols, D.J. Schiffrin, J. Electroanal. Chem. 570(2004) 157-161. doi: 10.1016/j.jelechem.2004.02.012
31. [31]
  M. Li, P. Liu, R.R. Adzic, J. Phys. Chem. Lett. 3(2012) 3480-3485. doi: 10.1021/jz3016155
32. [32]
  A.I. Danilov, E.B. Molodkina, Y.M. Polukarov, V. Climent, J.M. Feliu, Electrochim. Acta 46(2001) 3137-3145. doi: 10.1016/S0013-4686(01)00605-3
33. [33]
  D. Chen, Q. Tao, L.W. Liao, et al., Electrocatalysis 2(2011) 207-219. doi: 10.1007/s12678-011-0054-1
34. [34]
  S. Moniri, T. Van Cleve, S. Linic, J. Catal. 345(2017) 1-10. doi: 10.1016/j.jcat.2016.11.018
35. [35]
  K. Sasaki, J.X. Wang, H. Naohara, et al., Electrochim. Acta 55(2010) 2645-2652. doi: 10.1016/j.electacta.2009.11.106
36. [36]
  J. Suntivich, Z. Xu, C.E. Carlton, et al., J. Am. Chem. Soc. 135(2013) 7985-7991. doi: 10.1021/ja402072r
37. [37]
  R. Loukrakpam, Q. Yuan, V. Petkov, et al., Phys. Chem. Chem. Phys. 16(2014) 18866-18876. doi: 10.1039/C4CP02791D
38. [38]
  Y. Ando, K. Sasaki, R. Adzic, Electrochem. Commun. 11(2009) 1135-1138. doi: 10.1016/j.elecom.2009.03.031
39. [39]
  W. Chrzanowski, A. Wieckowski, Langmuir 13(1997) 5974-5978. doi: 10.1021/la970193c
40. [40]
  J. Zou, M. Wu, S. Ning, et al., ACS Sustainable Chem. Eng. 7(2019) 9007-9016. doi: 10.1021/acssuschemeng.9b01270
41. [41]
  P. Ochal, J.L. Gomez de la Fuente, M. Tsypkin, et al., J. Electroanal. Chem. 655(2011) 140-146. doi: 10.1016/j.jelechem.2011.02.027
42. [42]
  Z. Tao, W. Chen, J. Yang, et al., Sci. China Mater. 62(2018) 273-282.
43. [43]
  T.T. Gebremariam, F. Chen, B. Kou, et al., Electrochim. Acta 354(2020) 136678. doi: 10.1016/j.electacta.2020.136678
44. [44]
  Q.L. Wang, R. Fang, L.L. He, et al., J. Alloys Compd. 684(2016) 379-388. doi: 10.1016/j.jallcom.2016.05.188
45. [45]
  I. Banerjee, V. Kumaran, V. Santhanam, J. Phys. Chem. C 119(2015) 5982-5987. doi: 10.1021/jp5113284
46. [46]
  X. Jiang, X.Y. Qiu, G.T. Fu, et al., J. Mater. Chem. A 6(2018) 17682-17687. doi: 10.1039/C8TA06676K
47. [47]
  Q. Xue, J. Bai, C. Han, et al., ACS Catal. 8(2018) 11287-11295. doi: 10.1021/acscatal.8b03447
48. [48]
  Y.H. Zhu, J.T. He, C. Shang, et al., J. Am. Chem. Soc. 136(2014) 12746-12752. doi: 10.1021/ja506554j
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