Citation: Qishun Liu, Yufen Lv, Ruisheng Liu, Xiaohui Zhao, Jiawen Wang, Wei Wei. Catalyst- and additive-free selective sulfonylation/cyclization of 1,6-enynes with arylazo sulfones leading to sulfonylated γ-butyrolactams[J]. Chinese Chemical Letters, ;2021, 32(1): 136-139. doi: 10.1016/j.cclet.2020.11.059 shu

Catalyst- and additive-free selective sulfonylation/cyclization of 1,6-enynes with arylazo sulfones leading to sulfonylated γ-butyrolactams

Qishun Liu ^a ,
Yufen Lv ^a ,
Ruisheng Liu ^a ,
Xiaohui Zhao ^{b, **,} ,
Jiawen Wang ^c ,
Wei Wei ^{a, b, *,}

a.
School of Chemistry and Chemical Engineering, Qufu Normal University, Qufu 273165, China
b.
Qinghai Provincial Key Laboratory of Tibetan Medicine Research and Key Laboratory of Tibetan Medicine Research, Northwest Institute of Plateau Biology, Chinese Academy of Sciences, Qinghai 810008, China
c.
College of Chemistry and Chemical Engineering, Shenyang Normal University, Shenyang 110034, China

^**

xhzhao@nwipb.cas.cn

weiweiqfnu@163.com

Received Date: 2 October 2020
Revised Date: 18 November 2020
Accepted Date: 18 November 2020
Available Online: 30 November 2020

Figures(4)

A convenient and regioselective sulfonylation/cyclization of 1,6-enynes with arylazo sulfones has been developed to access a series of sulfonylated γ-butyrolactams. The present reaction could be efficiently conducted under catalyst- and additive-free conditions, in which C—S and C—C bonds were selectively constructed in one-pot procedure.
- Catalyst-free,
- Arylazo sulfones,
- 1,6-Enynes,
- Sulfonylated γ-butyrolactams
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