Citation: Junjie Yang, Junxian Qin, Ziyang Guo, Yun Hu, Xia Zhang. Zn-based metal organic framework derivative with uniform metal sites and hierarchical pores for efficient adsorption of formaldehyde[J]. Chinese Chemical Letters, ;2021, 32(5): 1819-1822. doi: 10.1016/j.cclet.2020.11.023 shu

Zn-based metal organic framework derivative with uniform metal sites and hierarchical pores for efficient adsorption of formaldehyde

Junjie Yang ^a ,
Junxian Qin ^a ,
Ziyang Guo ^a ,
Yun Hu ^{a, b, c, *,} ,
Xia Zhang ^d

a.
School of Environment and Energy, South China University of Technology, Guangzhou 510006, China
b.
Guangdong Provincial Key Laboratory of Atmospheric Environment and Pollution Control, Guangzhou 510006, China
c.
The Key Lab of Pollution Control and Ecosystem Restoration in Industry Clusters, Ministry of Education, Guangzhou 510006, China
d.
Zhejiang Tianchuan Environmental Science & Technology Co., Ltd., Hangzhou 310015, China

huyun@scut.edu.cn

Received Date: 15 August 2020
Revised Date: 10 October 2020
Accepted Date: 17 November 2020
Available Online: 20 November 2020

Figures(3)

A Zn-containing graphite carbon (Zn-GC) with uniform Zn metal sites and hierarchical pore structure was obtained by pyrolysis of Zn-based metal organic framework (MOF). Zn-GC exhibited excellent adsorption capacity and reproducibility for formaldehyde. The adsorption capacity of Zn-GC was 736 times that of commercial activated carbon and 5.6 times that of ZSM-5 adsorbents. The characterization and experimental results showed that the surface chemical characteristics of the adsorption material play an important role in the adsorption performance. The superior performance was attributed to Zn metal sites and oxygen-containing functional groups on the MOF derivative as well as hierarchical pore structure. The material showed a great potential in the field of organic pollutant removal.
- Formaldehyde,
- Adsorption,
- Hierarchical Pore,
- MOF-derivative,
- Carbon
1. [1]
  N. Aldag, J. Gunschera, T. Salthammer, Cellulose 24(2017) 4509-4518. doi: 10.1007/s10570-017-1393-8
2. [2]
  C. J. Na, M. J. Yoo, D. C. Tsang, et al., J. Hazard. Mater. 366(2019) 452-465. doi: 10.1016/j.jhazmat.2018.12.011
3. [3]
  C. He, J. Cheng, X. Zhang, et al., Chem. Rev. 119(2019) 4471-4568. doi: 10.1021/acs.chemrev.8b00408
4. [4]
  L. L. Zhu, D. K. Shen, K. H. Luo, J. Hazard. Mater. 389(2020) 122102. doi: 10.1016/j.jhazmat.2020.122102
5. [5]
  Y. Lv, J. Sun, G. Q. Yu, et al., Microporous Mesoporous Mater. 294(2019) 109869.
6. [6]
  K. J. Kim, H. G. Ahn, Carbon 48(2010) 2198-2202. doi: 10.1016/j.carbon.2010.02.021
7. [7]
  H. L. Chiang, P. C. Chiang, C. P. Huang, Chemosphere 47(2002) 267-275. doi: 10.1016/S0045-6535(01)00216-8
8. [8]
  S. S. Huang, W. Deng, L. Zhang, et al., Microporous Mesoporous Mater. 302(2020) 110204. doi: 10.1016/j.micromeso.2020.110204
9. [9]
  Y. Wang, K. Liu, J. Wu, et al., ACS Catal. 10(2020) 10021-10031. doi: 10.1021/acscatal.0c02310
10. [10]
  X. Q. Li, L. Zhang, Z. Q. Yang, et al., Sep. Purif. Technol. 235(2020) 116213. doi: 10.1016/j.seppur.2019.116213
11. [11]
  Q. Q. Huang, Y. Hu, Y. Pei, J. H. Zhang, M. L. Fu, Appl. Catal. B 259(2019) 118106. doi: 10.1016/j.apcatb.2019.118106
12. [12]
  J. H. Zhang, Y. Hu, J. X. Qin, Z. X. Yang, M. L. Fu, Chem. Eng. J. 385(2020) 123814. doi: 10.1016/j.cej.2019.123814
13. [13]
  X. Guan, Y. Wang, W. F. Cai, Chin. Chem. Lett. 30(2019) 1310-1314. doi: 10.1016/j.cclet.2019.02.029
14. [14]
  X. M. Zheng, S. Liu, S. Rehman, Z. H. Li, P. Y. Zhang, Chem. Eng. J. 389(2020) 123424. doi: 10.1016/j.cej.2019.123424
15. [15]
  N. Zhang, L. M. Yan, Y. Lu, et al., Chin. Chem. Lett. 31(2020) 2071-2076. doi: 10.1016/j.cclet.2019.12.014
16. [16]
  S. Jafari, F. Ghorbani-Shahna, A. Bahrami, H. Kazemian, Microporous Mesoporous Mater. 268(2018) 58-68. doi: 10.1016/j.micromeso.2018.04.013
17. [17]
  F. C. Chu, Y. Zheng, B. Y. Wen, et al., RSC Adv. 8(2018) 2426-2432. doi: 10.1039/C7RA12931A
18. [18]
  J. X. Qin, J. Wang, J. J. Yang, et al., Appl. Catal. B 267(2020) 118667. doi: 10.1016/j.apcatb.2020.118667
19. [19]
  L. C. Chen, W. Cui, J. Y. Li, et al., Appl. Catal. B 271(2020) 118948. doi: 10.1016/j.apcatb.2020.118948
20. [20]
  Y. Hu, H. Kazemian, S. Rohani, Y. N. Huang, Y. Song, Chem. Commun. 47(2011) 12694-12696. doi: 10.1039/c1cc15525c
21. [21]
  S. Xue, Y. J. Yu, S. S. Wei, et al., J. Taiwan Inst. Chem. Eng. 91(2018) 539-547. doi: 10.1016/j.jtice.2018.05.047
22. [22]
  Y. S. Luo, B. Q. Tan, X. H. Liang, et al., Microporous Mesoporous Mater. 297(2020) 110034. doi: 10.1016/j.micromeso.2020.110034
23. [23]
  J. Miao, X. J. Zhao, Y. T. Li, Z. H. Liu, Colloids Surf. A 602(2020) 124883. doi: 10.1016/j.colsurfa.2020.124883
24. [24]
  Y. L. Zhang, G. Z. Ji, C. J. Li, X. X. Wang, A. M. Li, Chem. Eng. J. 390(2020) 124398. doi: 10.1016/j.cej.2020.124398
25. [25]
  J. J. Wang, P. Y. Zhang, J. Li, et al., Environ. Sci. Technol. 49(2015) 12372-12379. doi: 10.1021/acs.est.5b02085
26. [26]
  J. Rodriguez-Mirasol, J. Bedia, T. Cordero, J. J. Rodríguez, Sep. Sci. Technol. 40(2005) 3113-3135. doi: 10.1080/01496390500385277
27. [27]
  M. Thommes, K. Kaneko, A. V. Neimark, et al., Pure Appl. Chem. 87(2016) 25-25.
28. [28]
  X. Chen, X. Jiang, C. J. Yin, B. L. Zhang, Q. Y. Zhang, J. Hazard. Mater. 367(2019) 194-204. doi: 10.1016/j.jhazmat.2018.12.080
29. [29]
  L. Feng, S. Yuan, L. L. Zhang, et al., J. Am. Chem. Soc. 140(2018) 2363-2372. doi: 10.1021/jacs.7b12916
30. [30]
  I. I. Laskar, Z. Hashisho, J. H. Phillips, J. E. Anderson, M. Nichols, Environ. Sci. Technol. 53(2019) 2647-2659. doi: 10.1021/acs.est.8b05664
31. [31]
  M. T. Drexler, M. D. Amiridis, J. Catal. 214(2003) 136-145. doi: 10.1016/S0021-9517(02)00013-1
32. [32]
  A. J. Van Hengstum, J. Pranger, S. M. Van Hengstum-Nijhuis, J. G. Van Ommen, P. J. Gellincs, J. Catal. 101(1986) 323-330. doi: 10.1016/0021-9517(86)90259-9
1. [1]
  Shiqi Peng , Yongfang Rao , Tan Li , Yufei Zhang , Jun-ji Cao , Shuncheng Lee , Yu Huang . Regulating the electronic structure of Ir single atoms by ZrO₂ nanoparticles for enhanced catalytic oxidation of formaldehyde at room temperature. Chinese Chemical Letters, 2024, 35(7): 109219-. doi: 10.1016/j.cclet.2023.109219
2. [2]
  Jiaxuan Wang , Tonghe Liu , Bingxiang Wang , Ziwei Li , Yuzhong Niu , Hou Chen , Ying Zhang . Synthesis of polyhydroxyl-capped PAMAM dendrimer/silica composites for the adsorption of aqueous Hg(II) and Ag(I). Chinese Chemical Letters, 2024, 35(12): 109900-. doi: 10.1016/j.cclet.2024.109900
3. [3]
  Fengxing Liang , Yongzheng Zhu , Nannan Wang , Meiping Zhu , Huibing He , Yanqiu Zhu , Peikang Shen , Jinliang Zhu . Recent advances in copper-based materials for robust lithium polysulfides adsorption and catalytic conversion. Chinese Chemical Letters, 2024, 35(11): 109461-. doi: 10.1016/j.cclet.2023.109461
4. [4]
  Congyan Liu , Xueyao Zhou , Fei Ye , Bin Jiang , Bo Liu . Confined electric field in nano-sized channels of ionic porous framework towards unique adsorption selectivity. Chinese Chemical Letters, 2025, 36(2): 109969-. doi: 10.1016/j.cclet.2024.109969
5. [5]
  Zixuan Zhu , Xianjin Shi , Yongfang Rao , Yu Huang . Recent progress of MgO-based materials in CO₂ adsorption and conversion: Modification methods, reaction condition, and CO₂ hydrogenation. Chinese Chemical Letters, 2024, 35(5): 108954-. doi: 10.1016/j.cclet.2023.108954
6. [6]
  Yihong Li , Zhong Qiu , Lei Huang , Shenghui Shen , Ping Liu , Haomiao Zhang , Feng Cao , Xinping He , Jun Zhang , Yang Xia , Xinqi Liang , Chen Wang , Wangjun Wan , Yongqi Zhang , Minghua Chen , Wenkui Zhang , Hui Huang , Yongping Gan , Xinhui Xia . Plasma enhanced reduction method for synthesis of reduced graphene oxide fiber/Si anode with improved performance. Chinese Chemical Letters, 2024, 35(11): 109510-. doi: 10.1016/j.cclet.2024.109510
7. [7]
  Yue Li , Minghao Fan , Conghui Wang , Yanxun Li , Xiang Yu , Jun Ding , Lei Yan , Lele Qiu , Yongcai Zhang , Longlu Wang . 3D layer-by-layer amorphous MoS_x assembled from [Mo₃S₁₃]^2- clusters for efficient removal of tetracycline: Synergy of adsorption and photo-assisted PMS activation. Chinese Chemical Letters, 2024, 35(9): 109764-. doi: 10.1016/j.cclet.2024.109764
8. [8]
  Chong Liu , Nanthi Bolan , Anushka Upamali Rajapaksha , Hailong Wang , Paramasivan Balasubramanian , Pengyan Zhang , Xuan Cuong Nguyen , Fayong Li . Critical review of biochar for the removal of emerging inorganic pollutants from wastewater. Chinese Chemical Letters, 2025, 36(2): 109960-. doi: 10.1016/j.cclet.2024.109960
9. [9]
  Linshan Peng , Qihang Peng , Tianxiang Jin , Zhirong Liu , Yong Qian . Highly efficient capture of thorium ion by citric acid-modified chitosan gels from aqueous solution. Chinese Chemical Letters, 2024, 35(5): 108891-. doi: 10.1016/j.cclet.2023.108891
10. [10]
  Xiao-Hong Yi , Chong-Chen Wang . Metal-organic frameworks on 3D interconnected macroporous sponge foams for large-scale water decontamination: A mini review. Chinese Chemical Letters, 2024, 35(5): 109094-. doi: 10.1016/j.cclet.2023.109094
11. [11]
  Haodong Wang , Xiaoxu Lai , Chi Chen , Pei Shi , Houzhao Wan , Hao Wang , Xingguang Chen , Dan Sun . Novel 2D bifunctional layered rare-earth hydroxides@GO catalyst as a functional interlayer for improved liquid-solid conversion of polysulfides in lithium-sulfur batteries. Chinese Chemical Letters, 2024, 35(5): 108473-. doi: 10.1016/j.cclet.2023.108473
12. [12]
  Dan Luo , Jinya Tian , Jianqiao Zhou , Xiaodong Chi . Anthracene-bridged "Texas-sized" box for the simultaneous detection and uptake of tryptophan. Chinese Chemical Letters, 2024, 35(9): 109444-. doi: 10.1016/j.cclet.2023.109444
13. [13]
  Mengyuan Li , Xitong Ren , Yanmei Gao , Mengyao Mu , Shiping Zhu , Shufang Tian , Minghua Lu . Constructing bifunctional magnetic porous poly(divinylbenzene) polymer for high-efficient removal and sensitive detection of bisphenols. Chinese Chemical Letters, 2024, 35(12): 109699-. doi: 10.1016/j.cclet.2024.109699
14. [14]
  Xudong Zhao , Yuxuan Wang , Xinxin Gao , Xinli Gao , Meihua Wang , Hongliang Huang , Baosheng Liu . Anchoring thiol-rich traps in 1D channel wall of metal-organic framework for efficient removal of mercury ions. Chinese Chemical Letters, 2025, 36(2): 109901-. doi: 10.1016/j.cclet.2024.109901
15. [15]
  Hong-Rui Li , Xia Kang , Rui Gao , Miao-Miao Shi , Bo Bi , Ze-Yu Chen , Jun-Min Yan . Interfacial interactions of Cu/MnOOH enhance ammonia synthesis from electrochemical nitrate reduction. Chinese Chemical Letters, 2025, 36(2): 109958-. doi: 10.1016/j.cclet.2024.109958
16. [16]
  Jie Ma , Jianxiang Wang , Jianhua Yuan , Xiao Liu , Yun Yang , Fei Yu . The regulating strategy of hierarchical structure and acidity in zeolites and application of gas adsorption: A review. Chinese Chemical Letters, 2024, 35(11): 109693-. doi: 10.1016/j.cclet.2024.109693
17. [17]
  Xianping Du , Ying Huang , Chen Chen , Zhenhe Feng , Meng Zong . Encapsulating Si particles in multiple carbon shells with pore-rich for constructing free-standing anodes of lithium storage. Chinese Chemical Letters, 2024, 35(12): 109990-. doi: 10.1016/j.cclet.2024.109990
18. [18]
  Xiao Li , Wanqiang Yu , Yujie Wang , Ruiying Liu , Qingquan Yu , Riming Hu , Xuchuan Jiang , Qingsheng Gao , Hong Liu , Jiayuan Yu , Weijia Zhou . Metal-encapsulated nitrogen-doped carbon nanotube arrays electrode for enhancing sulfion oxidation reaction and hydrogen evolution reaction by regulating of intermediate adsorption. Chinese Chemical Letters, 2024, 35(8): 109166-. doi: 10.1016/j.cclet.2023.109166
19. [19]
  Ting Shi , Ziyang Song , Yaokang Lv , Dazhang Zhu , Ling Miao , Lihua Gan , Mingxian Liu . Hierarchical porous carbon guided by constructing organic-inorganic interpenetrating polymer networks to facilitate performance of zinc hybrid supercapacitors. Chinese Chemical Letters, 2025, 36(1): 109559-. doi: 10.1016/j.cclet.2024.109559
20. [20]
  Ruiying Liu , Li Zhao , Baishan Liu , Jiayuan Yu , Yujie Wang , Wanqiang Yu , Di Xin , Chaoqiong Fang , Xuchuan Jiang , Riming Hu , Hong Liu , Weijia Zhou . Modulating pollutant adsorption and peroxymonosulfate activation sites on Co3O4@N,O doped-carbon shell for boosting catalytic degradation activity. Chinese Journal of Structural Chemistry, 2024, 43(8): 100332-100332. doi: 10.1016/j.cjsc.2023.100332

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(1036)
HTML views(186)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142