Citation: Yue Jiang, Yao Qin, Tianyu Yu, Sijie Lin. Synthesis of sponge-like TiO₂ with surface-phase junctions for enhanced visible-light photocatalytic performance[J]. Chinese Chemical Letters, ;2021, 32(5): 1823-1826. doi: 10.1016/j.cclet.2020.11.010 shu

Synthesis of sponge-like TiO₂ with surface-phase junctions for enhanced visible-light photocatalytic performance

Yue Jiang ^{a, b} ,
Yao Qin ^c ,
Tianyu Yu ^{a, b} ,
Sijie Lin ^{a, b, *,}

a.
College of Environmental Science and Engineering, The Institute for Translational Nanomedicine, Shanghai East Hospital, Tongji University, Shanghai 200092, China
b.
Key Laboratory of Yangtze River Water Environment, Shanghai Institute of Pollution Control and Ecological Security, Tongji University, Shanghai 200092, China
c.
Institute for Regenerative Medicine, The Institute for Translational Nanomedicine, Shanghai East Hospital, Tongji University School of Medicine, Shanghai 200123, China

lin.sijie@tongji.edu.cn

Received Date: 8 August 2020
Revised Date: 30 September 2020
Accepted Date: 4 November 2020
Available Online: 4 November 2020

Figures(4)

Maximizing adsorption and catalytic active sites and promoting the photo-excited charge separation are two key factors to achieve excellent photocatalytic performance. In this study, we report a sol-gel synthesis approach to obtain non-metal doped TiO₂ with sponge-like structure and surface-phase junctions all at once. While doping of carbon and nitrogen shifted the activation wavelength to the visible-light region, the innovative use of perchloric acid as a pore-making agent led to the formation of three-dimensional lamellar and porous structure with surface-phase junctions. High surface area with catalytic active sites rendered by the sponge-like structure and surface-phase junctions contributed to the much improved photocatalytic degradation efficiency toward rhodamine B, tetracycline and Disperse Red 60 with excellent reusability and stability. The improved generation and separation efficiency of the photo-induced charge carriers of the as-prepared TiO₂ were supported by electrochemical impedance measurements and transient photocurrent responses. This method could also be applied to other photocatalysts to achieve structural alteration and element doping simultaneously.
- Structural alteration,
- Surface-phase junction,
- Photocatalytic degradation,
- Visible light,
- TiO₂
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis of sponge-like TiO2 with surface-phase junctions for enhanced visible-light photocatalytic performance

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通讯作者: 陈斌, bchen63@163.com

Synthesis of sponge-like TiO₂ with surface-phase junctions for enhanced visible-light photocatalytic performance