Citation: Yongrui He, Xiaohong Yang, Meiling Qi, Chuanfeng Chen. Triptycene-derived heterocalixarene: A new type of macrocycle-based stationary phases for gas chromatography[J]. Chinese Chemical Letters, ;2021, 32(6): 2043-2046. doi: 10.1016/j.cclet.2020.11.009 shu

Triptycene-derived heterocalixarene: A new type of macrocycle-based stationary phases for gas chromatography

Yongrui He ^a ,
Xiaohong Yang ^a ,
Meiling Qi ^{a, *,} ,
Chuanfeng Chen ^{b, *,}

a.
Key Laboratory of Cluster Science, Ministry of Education of China, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 100081, China
b.
CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China

mlqi@bit.edu.cn

cchen@iccas.ac.cn

Received Date: 22 August 2020
Revised Date: 26 September 2020
Accepted Date: 3 November 2020
Available Online: 4 November 2020

Figures(5)

This work reports the investigation of a new triptycene-derived oxacalixarene (TDOC) as the stationary phase for gas chromatography (GC) with high-resolution performance for a wide range of analytes and isomers. The TDOC scaffold is composed of triptycene and 1, 8-naphthyridine moieties, inherently differing from the conventional calixarenes in structures and properties. As a result, the TDOC column exhibited outstanding column efficiency of 5679 plates/m by n-dodecane at 120 ℃. It showed advantageous performance for separations of the mixtures with various analytes and achieved high resolution of diverse isomers (skeletal, positional andcis-/trans-isomers) from apolar to polar nature. Moreover, the TDOC column exhibited high thermal stability up to 310 ℃. To date, the TDOC-based materials have not been reported in chromatography. This work demonstrates the good potential of the triptycene-derived heterocalixarenes as a new class of stationary phases for chromatographic analyses.
- Triptycene-derived oxacalixarene,
- Stationary phase,
- Separation performance,
- Gas chromatography,
- Isomers
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