Citation: Yan Cai, Zhecheng Zhang, Yue Ding, Lanping Hu, Jin Wang, Tingting Chen, Yong Yao. Recent development of pillar[n]arene-based amphiphiles[J]. Chinese Chemical Letters, ;2021, 32(4): 1267-1279. doi: 10.1016/j.cclet.2020.10.036 shu

Recent development of pillar[n]arene-based amphiphiles

School of Chemistry and Chemical Engineering, Nantong University, Nantong 226019, China

wangjin107@ntu.edu.cn

ttchen1980@126.com

yaoyong1986@ntu.edu.cn

Received Date: 4 August 2020
Revised Date: 17 October 2020
Accepted Date: 23 October 2020
Available Online: 24 October 2020

Figures(28)

Pillar[n]arene-based amphiphiles, mainly including amphiphilic pillar[n]arenes and supra-amphiphilic pillar[n]arenes, have obtained considerable interests in recent years due to their fascinating chemical structures, various self-assembly behaviors, and widely applications. Thanks to the pillar-like frameworks and the rich host-guest recognitions of the cavities, these amphiphiles can be easily controlled to form dimensional and morphologic assemblies for multiple applications. Compared with traditional linear covalent amphiphiles, the introduction of host-guest recognitions facilitated the preparation and controllability of these supramolecular amphiphilic systems. Moreover, the host-guest recognitions endow the assemblies from pillar[n]arene-based amphiphiles with stimuli-responsive functions. In this mini-review, we summarized the chemical structures, self-assembly features, and the applications of pillar[n]arene-based amphiphiles. However, several research topics of pillar[n]arene-based amphiphiles can be further developed in the future, such as larger cavity amphiphilic pillar[n]arenes, co-assembly with 2D materials and utilization of the host-guest interactions.
- Pillar[5]arene,
- Supramolecular assemblies,
- Amphiphiles,
- Reversible conversion,
- Controlled release
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