Citation: Yanting Chu, Baojuan Xi, Shenglin Xiong. One-step construction of MoO₂ uniform nanoparticles on graphene with enhanced lithium storage[J]. Chinese Chemical Letters, ;2021, 32(6): 1983-1987. doi: 10.1016/j.cclet.2020.10.024 shu

One-step construction of MoO₂ uniform nanoparticles on graphene with enhanced lithium storage

Key Laboratory of Colloid and Interface Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, State Key Laboratory of Crystal Materials, Shandong University, Jionan 250100, China

chexsl@sdu.edu.cn

Received Date: 31 August 2020
Revised Date: 17 October 2020
Accepted Date: 20 October 2020
Available Online: 22 October 2020

Figures(4)

Transition-metal oxides are considered to be a promising anode material for lithium-ion batteries (LIBs) due to their high capacities, low cost, and ease of synthesis. Herein, a hybrid nanosheet composed of uniform MoO₂ nanoparticles (NPs) homogeneously immobilized on the reduced graphene oxide nanosheets (MoO₂ NP@rGO) is first synthesized by a self-templating and subsequent calcination treatment. The unique two-dimensional hybridnanosheets provides several merits. rGO can be used as a favorable support for the loading of electrochemically active MoO₂ NPs. Meanwhile, MoO₂ NPs can effectively prevent the stacking of the rGO. The effective combination of MoO₂ NPs and rGO nanosheets furnish additional electrochemically interfacial active sites for extra lithium ion storage. Noticeably, the as-fabricated hybrid nanosheets deliver a reversible capacity of 641 mAh/g after 350 cycles at a current density of 1000 mA/g with a good rate capability. The greatly enhanced lithium storage properties of MoO₂ NP@rGO indicate the importance of elaborate construction of novel hybrid hierarchical structures.
- MoO₂,
- Graphene,
- Two-dimensional hybrid nanostructure,
- Anode,
- Lithium-ion batteries
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One-step construction of MoO2 uniform nanoparticles on graphene with enhanced lithium storage

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通讯作者: 陈斌, bchen63@163.com

One-step construction of MoO₂ uniform nanoparticles on graphene with enhanced lithium storage