Citation: Qian Zou, Jing-Cui Liu, Xin-Da Huang, Song-Song Bao, Li-Min Zheng. Thermo-induced structural transformation with synergistic optical and magnetic changes in ytterbium and erbium complexes[J]. Chinese Chemical Letters, ;2021, 32(4): 1519-1522. doi: 10.1016/j.cclet.2020.10.019 shu

Thermo-induced structural transformation with synergistic optical and magnetic changes in ytterbium and erbium complexes

State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, School of Chemistry and Chemical Engineering, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210023, China

lmzheng@nju.edu.cn

Received Date: 7 September 2020
Revised Date: 6 October 2020
Accepted Date: 16 October 2020
Available Online: 17 October 2020

Figures(4)

Dinuclear ytterbium and erbium based bifunction complexes Ln₂L₂(depma₂)Cl₂ (1-Ln, Ln=Yb and Er, H₂L=N¹, N³-bis(salicylideneimino)diethylenetriamine, depma₂ = dimerized 9-diethyl-phosphonomethylanthracene) are reported. They undergo thermo-induced consecutive phase transitions, first the dissociation of depma₂ ligand forming LnL(depma)Cl (2-Ln) and then the release of chloroethane forming LnL(epma) (3-Ln, epma=9-ethylphosphonomethylanthrancene). The structural transformations are accompanied with synergetic switch of the luminescence in visible and NIR regions and also magnetic dynamics.
- Phase transition,
- Lanthanide,
- Anthracene,
- Single molecule magnet,
- Luminescence
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