Citation: Yao Xie, Yuling Chen, Xin Sun, Yang Wang, Yi Wang. Conducting polymer engineered covalent organic framework as a novel electrochemical amplifier for ultrasensitive detection of acetaminophen[J]. Chinese Chemical Letters, ;2021, 32(6): 2061-2065. doi: 10.1016/j.cclet.2020.10.001 shu

Conducting polymer engineered covalent organic framework as a novel electrochemical amplifier for ultrasensitive detection of acetaminophen

Yao Xie ^a ,
Yuling Chen ^a ,
Xin Sun ^a ,
Yang Wang ^{a, *,} ,
Yi Wang ^{b, *,}

a.
School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, China
b.
Engineering Research Center of Clinical Functional Materials and Diagnosis & Treatment Devices of Zhejiang Province, Wenzhou Institute, University of Chinese Academy of Sciences, Wenzhou 325001, China

wangy@yzu.edu.cn

wangyi@wibe.ac.cn

Received Date: 21 May 2020
Revised Date: 12 August 2020
Accepted Date: 3 October 2020
Available Online: 5 October 2020

Figures(3)

Two-dimensional covalent organic framework (COF) has distinctive properties that offer potential opportunities for developing advanced electrode materials. In this work, a core-shell material composed of TAPB-DMTP-COF (TAPB, 1, 3, 5-tris(4-aminophenyl)benzene; DMTP, 2, 5-dimethoxyterephaldehyde) core and conducting polymer shell, TAPB-DMTP-COF@PANI, was synthesized solvothermally using a polymerization method. The structural characteristics of the prepared composite were revealed by X-ray diffraction patterns (XRD), fourier transform infrared spectra (FTIR), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM). The electrochemical analyses were verified by subsequent monitoring of trace levels of acetaminophen. This resultant composite not only facilitated acetaminophen to interact with absorption sites by π-π stacking effect and hydrogen bonding but also overcame the poor conductivity of COF. Under the optimal conditions, a low limit of detection of 0.032 μmol/L and wide linear range of 0.10-500 μmol/L were obtained. The electrochemical platform was almost unaffected by other interfering substances, and successfully applied for the practical detection of acetaminophen in commercial tablet, human blood serum and urine. The enhanced performance makes this COF based core-shell composite a promising material in electrochemical sensor.
- Covalent organic frameworks,
- Conducting polymer,
- Electrochemical sensor,
- Ultrasensitive detection,
- Acetaminophen
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