Citation: Xiaofeng Tan, Jun Qin, Yan Li, Yuting Zeng, Jindi Gong, Gengxiu Zheng, Feng Feng, He Li. Intermetallic PdBi aerogels with improved catalytic performance for the degradation of organic pollutants in water[J]. Chinese Chemical Letters, ;2021, 32(4): 1451-1455. doi: 10.1016/j.cclet.2020.09.043 shu

Intermetallic PdBi aerogels with improved catalytic performance for the degradation of organic pollutants in water

Xiaofeng Tan ^{a, 1} ,
Jun Qin ^{b, 1} ,
Yan Li ^c ,
Yuting Zeng ^c ,
Jindi Gong ^c ,
Gengxiu Zheng ^{a, **,} ,
Feng Feng ^{b, **,} ,
He Li ^{a, c, *,}

a.
School of Chemistry and Chemical Engineering, University of Jinan, J'inan 250022, China
b.
College of Chemistry and Environmental Engineering, Shanxi Datong University, Datong 037009, China
c.
College of Optoelectronics Technology, Chengdu University of Information Technology, Chengdu 610225, China

^**

chm_zhenggx@ujn.edu.cn

feng-feng64@263.net

lihecd@gmail.com

Received Date: 27 June 2020
Revised Date: 27 July 2020
Accepted Date: 23 September 2020
Available Online: 24 September 2020

Figures(5)

It is always highly pursued to develop efficient and durable catalysts for catalytic applications. Herein, intermetallic PdBi aerogels with tunable activity were prepared successfully via a surfactant-free spontaneous gelation process. The prepared PdBi aerogels have a three-dimensional high porous structure and plentiful active sites pervaded on the ultrathin interlinked nanowires network. These unique structures, as well as the synergistic effect between Pd and Bi, can accelerate mass and electron transfer, and improve the atom utilization ratio of Pd atoms to promote the catalytic efficiency. As a proof-of-concept application, the optimized Pd₂Bi₁ aerogels exhibit 4.2 and 6.2 times higher catalytic activity for the reduction of 4-nitrophenol (4-NP) and methylene blue (MB) than those of commercial Pd/C, respectively. With the introduction of non-noble metal of Bi, the cost of the resulted PdBi aerogels can be dropped significantly while the catalytic capability of PdBi aerogel will be improved sharply. This strategy will bring good hints to rationally design fine catalysts for various applications.
- PdBi aerogels,
- Degradation,
- Organic micropollutants,
- Atom utilization ratio,
- Synergistic effect
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