Citation: Wenbo Li, Yucen Li, Wei Zhang, Difeng Yin, Ya Cheng, Wei Chu, Ming Hu. Size-controlled flow synthesis of metal-organic frameworks crystals monitored by in-situ ultraviolet–visible absorption spectroscopy[J]. Chinese Chemical Letters, ;2021, 32(3): 1131-1134. doi: 10.1016/j.cclet.2020.09.039 shu

Size-controlled flow synthesis of metal-organic frameworks crystals monitored by in-situ ultraviolet–visible absorption spectroscopy

Wenbo Li ^{a, b, e} ,
Yucen Li ^c ,
Wei Zhang ^c ,
Difeng Yin ^{a, b, e} ,
Ya Cheng ^{a, c, d, e} ,
Wei Chu ^{d, *,} ,
Ming Hu ^{c, *,}

a.
State Key Laboratory of High Field Laser Physics and CAS Center for Excellence in Ultra-Intense Laser Science, Shanghai Institute of Optics and Fine Mechanics (SIOM), Chinese Academy of Sciences (CAS), Shanghai 201800, China
b.
chool of Physical Science and Technology, ShanghaiTech University, Shanghai 200031, China
c.
State Key Laboratory of Precision Spectroscopy, School of Physics and Electronic Science, East China Normal University, Shanghai 200241, China
d.
XXL - The Extreme Optoelectromechanics Laboratory, School of Physics and Electronic Science, East China Normal University, Shanghai 200241, China
e.
University of Chinese Academy of Sciences, Beijing 100049, China

wchu@phy.ecnu.edu.cn

mhu@phy.ecnu.edu.cn

Received Date: 27 August 2020
Revised Date: 18 September 2020
Accepted Date: 23 September 2020
Available Online: 24 September 2020

Figures(4)

Size-controlled flow synthesis of nanoporous particles are of considerable interest for future industrial applications, however, is facing challenges due to lack of in-situ method for size-characterization in fluidic environment. We present that ultraviolet-visible (UV–vis) absorption spectroscopy can be integrated into a flow-synthesis system which was produced by femtosecond laser micromachining. The shift of the absorption peak position of the ex-situ and in-situ UV–vis spectra correlates to variation of size of porous metal-organic frameworks crystals. ZIF-67 crystals with a size in the range from 200 nm to 1025 nm are fabricated with the assistance of tri-ethylamine under monitoring of in-situ UV–vis spectra. The ZIF-67 crystals are converted into nanoporous carbons particles with controlled sizes. These materials show size-dependent performance in Na-ion battery and size-independent performance in metal/H₂O seawater battery.
- Nanoporous particles,
- Microfluidics,
- Flow synthesis,
- Metal-organic frameworks,
- UV–vis absorption spectrum,
- Femtosecond laser micromachining
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