Citation: Yanfei Li, Ruikang Zhang, Jianming Li, Jingchao Liu, Yucong Miao, Jian Guo, Mingfei Shao. TiO₂/CuPc/NiFe-LDH photoanode for efficient photoelectrochemical water splitting[J]. Chinese Chemical Letters, ;2021, 32(3): 1165-1168. doi: 10.1016/j.cclet.2020.09.037 shu

TiO₂/CuPc/NiFe-LDH photoanode for efficient photoelectrochemical water splitting

Yanfei Li ^a ,
Ruikang Zhang ^{b, *,} ,
Jianming Li ^c ,
Jingchao Liu ^a ,
Yucong Miao ^a ,
Jian Guo ^a ,
Mingfei Shao ^{a, *,}

a.
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
b.
College of Chemistry and Material Science, Hebei Normal University, Shijiazhuang 050024, China
c.
Petroleum Geology Research and Laboratory Center, Research Institute of Petroleum Exploration & Development (RIPED), PetroChina, Beijing 100083, China

zhangruikang@hebtu.edu.cn

shaomf@mail.buct.edu.cn

Received Date: 25 August 2020
Revised Date: 16 September 2020
Accepted Date: 22 September 2020
Available Online: 23 September 2020

Figures(5)

Photoelectrochemical (PEC) water splitting is a promising approach for renewable hydrogen production. However, the practical PEC solar-to-fuel conversion efficiency is still low owing to poor light absorption and rapid recombination of charge carriers in photoelectrode. In this work, we report a ternary photoanode with simultaneously enhancement of light absorption and water oxidation efficiency by introducing copper phthalocyanine (CuPc) and nickel iron-layered double hydroxide (NiFe-LDH) on TiO₂ (denoted as TiO₂/CuPc/NiFe-LDH). An experimental study reveals that CuPc loading on TiO₂ bring strong visible light absorption; NiFe-LDH as an oxygen evolution reaction catalyst efficiently accelerates the surface water oxidation reaction. This synergistic effect of CuPc and NiFe-LDH gives enhanced photocurrent density (2.10 mA/cm² at 0.6 V vs. SCE) and excellent stability in the ternary TiO₂/CuPc/NiFeLDH photoanode.
- Photoelectrochemical,
- Water splitting,
- TiO₂ photoanode,
- Layered double hydroxide,
- Photosensitizer
1. [1]
  R. Gao, D. Yan, Adv. Energy Mater. 11(2019) 1900954.
2. [2]
  J.H. Kim, J.S. Lee, Adv. Mater. 20(2019) 1806938.
3. [3]
  Z. Wei, B. Ding, H. Dou, et al., Chin. Chem. Lett. 30(2020) 2110-2122.
4. [4]
  J. Xiao, L. Fan, F. Zhao, et al., J. Catal. 381(2020) 139-149. doi: 10.1016/j.jcat.2019.10.033
5. [5]
  G. Liu, Y. Zhao, R. Yao, et al., Chem. Eng. J. 355(2019) 49-57. doi: 10.1016/j.cej.2018.08.100
6. [6]
  L. Cai, Y. Du, X. Guan, Chin. Chem. Lett. 30(2019) 2363-2367. doi: 10.1016/j.cclet.2019.07.020
7. [7]
  G. Žerjav, M.S. Arshad, P. Djinović, et al., Nanoscale 13(2017) 4578-4592.
8. [8]
  Y. Chen, J. Li, P. Liao, et al., Chin. Chem. Lett. 31(2020) 1516-1519. doi: 10.1016/j.cclet.2019.12.013
9. [9]
  R. Chen, S. Pang, H. An, et al., Nat. Energy 8(2018) 655-663.
10. [10]
  Y. Si, S. Cao, Z. Wu, et al., Nano Energy 41(2017) 488-493. doi: 10.1016/j.nanoen.2017.10.008
11. [11]
  W. Li, A. Elzatahry, D. Aldhayan, et al., Chem. Soc. Rev. 22(2018) 8203-8237.
12. [12]
  S. Feizpoor, A. Habibi-Yangjeh, Electrochim. Acta 262(2018) 82-96. doi: 10.1016/j.electacta.2018.01.001
13. [13]
  Y. Zhang, J. Huang, Y. Ding, Appl. Catal. B Environ. 198(2016) 447-456. doi: 10.1016/j.apcatb.2016.05.078
14. [14]
  S. Cao, C.J. Wang, W.F. Fu, et al., ChemSusChem 22(2017) 4306-4323.
15. [15]
  W. Chen, T. Wang, J. Xue, et al., Small 10(2017) 1602420.
16. [16]
  T. Li, X. Hao, S. Bai, et al., Acta Phys. Sin. 36(2020) 1912005.
17. [17]
  H. She, P. Yue, X. Ma, et al., Appl. Catal. B Environ. 263(2020) 118280. doi: 10.1016/j.apcatb.2019.118280
18. [18]
  T.S. Munonde, H. Zheng, P.N. Nomngongo, Ultrason. Sonochem. 59(2019) 104716. doi: 10.1016/j.ultsonch.2019.104716
19. [19]
  F. Ning, M. Shao, S. Xu, et al., Energy Environ. Sci. 8(2016) 263-2643.
20. [20]
  R. Zhang, M. Shao, S. Xu, et al., Nano Energy 33(2017) 21-28. doi: 10.1016/j.nanoen.2017.01.020
21. [21]
  X. Li, T. Zhang, Y. Chen, et al., Chem. Eng. J. 382(2020) 122783. doi: 10.1016/j.cej.2019.122783
22. [22]
  Y. Li, M. Yang, Z. Tian, et al., Front. Chem. 7(2019) 334. doi: 10.3389/fchem.2019.00334
23. [23]
  M. Ouyang, X. Hu, X. Shao, et al., RSC Adv. 59(2019) 34382-34388.
24. [24]
  W. He, Y. Yang, L. Wang, et al., ChemSusChem 9(2015) 1568-1576. doi: 10.1002/cssc.201403294
25. [25]
  S. Bai, X. Yang, C. Liu, et al., ACS Sustainable Chem. Eng. 10(2018) 12906-12913.
26. [26]
  M. Ye, D. Zheng, M. Wang, et al., ACS Appl. Mater. Interfaces 4(2014) 2893-2901. doi: 10.1021/am405442n
27. [27]
  M. Ludemann, I.E. Brumboiu, O.D. Gordan, et al., J. Nanopart. Res. 11(2011) 5855-5861. doi: 10.1007/s11051-011-0564-z
28. [28]
  Y. Wang, Y. -Y. Zhang, J. Tang, et al., ACS Nano 10(2013) 9375-9383.
29. [29]
  W. Li, P. Da, Y. Zhang, et al., ACS Nano 11(2014) 11770-11777. doi: 10.1021/nn5053684
30. [30]
  X. Huai, L. Girardi, R. Lu, et al., Nano Energy 65(2019) 104020. doi: 10.1016/j.nanoen.2019.104020
31. [31]
  D. Dridi, Y. Litaiem, M. Karyaoui, et al., Eur. Phys. J. Appl. Phys. 2(2019) 20401.
32. [32]
  J. Seo, N.J. Jeon, W.S. Yang, et al., Adv. Energy Mater. 20(2015) 1501320.
33. [33]
  Q. Wang, T. Niu, L. Wang, et al., Chin. J. Catal. 4(2018) 613-618.
1. [1]
  Kai Han , Guohui Dong , Ishaaq Saeed , Tingting Dong , Chenyang Xiao . Boosting bulk charge transport of CuWO4 photoanodes via Cs doping for solar water oxidation. Chinese Journal of Structural Chemistry, 2024, 43(2): 100207-100207. doi: 10.1016/j.cjsc.2023.100207
2. [2]
  Hongye Bai , Lihao Yu , Jinfu Xu , Xuliang Pang , Yajie Bai , Jianguo Cui , Weiqiang Fan . Controllable Decoration of Ni-MOF on TiO2: Understanding the Role of Coordination State on Photoelectrochemical Performance. Chinese Journal of Structural Chemistry, 2023, 42(10): 100096-100096. doi: 10.1016/j.cjsc.2023.100096
3. [3]
  Wenhao Chen , Jian Du , Hanbin Zhang , Hancheng Wang , Kaicheng Xu , Zhujun Gao , Jiaming Tong , Jin Wang , Junjun Xue , Ting Zhi , Longlu Wang . Surface treatment of GaN nanowires for enhanced photoelectrochemical water-splitting. Chinese Chemical Letters, 2024, 35(9): 109168-. doi: 10.1016/j.cclet.2023.109168
4. [4]
  Zhe Li , Ping-Zhao Liang , Li Xu , Fei-Yu Yang , Tian-Bing Ren , Lin Yuan , Xia Yin , Xiao-Bing Zhang . Three positive charge nonapoptotic-induced photosensitizer with excellent water solubility for tumor therapy. Chinese Chemical Letters, 2024, 35(8): 109190-. doi: 10.1016/j.cclet.2023.109190
5. [5]
  Chunru Liu , Ligang Feng . Advances in anode catalysts of methanol-assisted water-splitting reactions for hydrogen generation. Chinese Journal of Structural Chemistry, 2023, 42(10): 100136-100136. doi: 10.1016/j.cjsc.2023.100136
6. [6]
  Hualin Jiang , Wenxi Ye , Huitao Zhen , Xubiao Luo , Vyacheslav Fominski , Long Ye , Pinghua Chen . Novel 3D-on-2D g-C₃N₄/AgI._x._y heterojunction photocatalyst for simultaneous and stoichiometric production of H₂ and H₂O₂ from water splitting under visible light. Chinese Chemical Letters, 2025, 36(2): 109984-. doi: 10.1016/j.cclet.2024.109984
7. [7]
  Du Liu , Yuyan Li , Hankun Zhang , Benhua Wang , Chaoyi Yao , Minhuan Lan , Zhanhong Yang , Xiangzhi Song . Three-in-one erlotinib-modified NIR photosensitizer for fluorescence imaging and synergistic chemo-photodynamic therapy. Chinese Chemical Letters, 2025, 36(2): 109910-. doi: 10.1016/j.cclet.2024.109910
8. [8]
  Entian Cui , Yulian Lu , Zhaoxia Li , Zhilei Chen , Chengyan Ge , Jizhou Jiang . Interfacial B-O bonding modulated S-scheme B-doped N-deficient C₃N₄/O-doped-C₃N₅ for efficient photocatalytic overall water splitting. Chinese Chemical Letters, 2025, 36(1): 110288-. doi: 10.1016/j.cclet.2024.110288
9. [9]
  Sinong Wang , Shanshan Jin , Xue Yang , Yanyan Huang , Peng Liu , Yi Tang , Yuliang Yang . Development of Mg-Al LDH and LDO as novel protective materials for deacidification of paper-based relics. Chinese Chemical Letters, 2024, 35(9): 109890-. doi: 10.1016/j.cclet.2024.109890
10. [10]
  Xiaomeng Hu , Jie Yu , Lijie Sun , Linfeng Zhang , Wei Zhou , Dongpeng Yan , Xinrui Wang . Synthesis of an AVB@ZnTi-LDH composite with synergistically enhance UV blocking activity and high stability for potential application in sunscreen formulations. Chinese Chemical Letters, 2024, 35(11): 109466-. doi: 10.1016/j.cclet.2023.109466
11. [11]
  Qihang Wu , Hui Wen , Wenhai Lin , Tingting Sun , Zhigang Xie . Alkyl chain engineering of boron dipyrromethenes for efficient photodynamic antibacterial treatment. Chinese Chemical Letters, 2024, 35(12): 109692-. doi: 10.1016/j.cclet.2024.109692
12. [12]
  Jinglin CHENG , Xiaoming GUO , Tao MENG , Xu HU , Liang LI , Yanzhe WANG , Wenzhu HUANG . NiAlNd catalysts for CO₂ methanation derived from the layered double hydroxide precursor. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1592-1602. doi: 10.11862/CJIC.20240152
13. [13]
  Hailang Deng , Abebe Reda Woldu , Abdul Qayum , Zanling Huang , Weiwei Zhu , Xiang Peng , Paul K. Chu , Liangsheng Hu . Killing two birds with one stone: Enhancing the photoelectrochemical water splitting activity and stability of BiVO₄ by Fe ions association. Chinese Chemical Letters, 2024, 35(12): 109892-. doi: 10.1016/j.cclet.2024.109892
14. [14]
  Zhao Lu , Hu Lv , Qinzhuang Liu , Zhongliao Wang . Modulating NH₂ Lewis Basicity in CTF-NH₂ through Donor-Acceptor Groups for Optimizing Photocatalytic Water Splitting. Acta Physico-Chimica Sinica, 2024, 40(12): 2405005-. doi: 10.3866/PKU.WHXB202405005
15. [15]
  Lu Qi , Zhaoyang Chen , Xiaoyu Luan , Zhiqiang Zheng , Yurui Xue , Yuliang Li . Atomically dispersed Mn enhanced catalytic performance for overall water splitting on graphdiyne-coated copper hydroxide nanowire. Chinese Journal of Structural Chemistry, 2024, 43(1): 100197-100197. doi: 10.1016/j.cjsc.2024.100197
16. [16]
  Qinghong Pan , Huafang Zhang , Qiaoling Liu , Donghong Huang , Da-Peng Yang , Tianjia Jiang , Shuyang Sun , Xiangrong Chen . A self-powered cathodic molecular imprinting ultrasensitive photoelectrochemical tetracycline sensor via ZnO/C photoanode signal amplification. Chinese Chemical Letters, 2025, 36(1): 110169-. doi: 10.1016/j.cclet.2024.110169
17. [17]
  Yuchen Guo , Xiangyu Zou , Xueling Wei , Weiwei Bao , Junjun Zhang , Jie Han , Feihong Jia . Fe regulating Ni3S2/ZrCoFe-LDH@NF heterojunction catalysts for overall water splitting. Chinese Journal of Structural Chemistry, 2024, 43(2): 100206-100206. doi: 10.1016/j.cjsc.2023.100206
18. [18]
  Xin Lv , Hongxing Zhang , Kaibo Duan , Wenhui Dai , Zhihui Wen , Wei Guo , Junsheng Hao . Lighting the Way Against Cancer: Photodynamic Therapy. University Chemistry, 2024, 39(5): 70-79. doi: 10.3866/PKU.DXHX202309090
19. [19]
  Jinqiang Gao , Haifeng Yuan , Xinjuan Du , Feng Dong , Yu Zhou , Shengnan Na , Yanpeng Chen , Mingyu Hu , Mei Hong , Shihe Yang . Methanol steam mediated corrosion engineering towards high-entropy NiFe layered double hydroxide for ultra-stable oxygen evolution. Chinese Chemical Letters, 2025, 36(1): 110232-. doi: 10.1016/j.cclet.2024.110232
20. [20]
  Shuyuan Pan , Zehui Yang , Fang Luo . Ni-based electrocatalysts for urea assisted water splitting. Chinese Journal of Structural Chemistry, 2024, 43(8): 100373-100373. doi: 10.1016/j.cjsc.2024.100373

Get Citation

PDF

XML

Metrics

PDF Downloads(11)
Abstract views(1000)
HTML views(187)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

TiO2/CuPc/NiFe-LDH photoanode for efficient photoelectrochemical water splitting

Metrics

通讯作者: 陈斌, bchen63@163.com

TiO₂/CuPc/NiFe-LDH photoanode for efficient photoelectrochemical water splitting