Citation: Yangyi Gu, Ling Miao, Ying Yin, Mingxian Liu, Lihua Gan, Liangchun Li. Highly N/O co-doped ultramicroporous carbons derived from nonporous metal-organic framework for high performance supercapacitors[J]. Chinese Chemical Letters, ;2021, 32(4): 1491-1496. doi: 10.1016/j.cclet.2020.09.029 shu

Highly N/O co-doped ultramicroporous carbons derived from nonporous metal-organic framework for high performance supercapacitors

Shanghai Key Lab of Chemical Assessment and Sustainability, School of Chemical Science and Engineering, Tongji University, Shanghai 200092, China

lilc@tongji.edu.cn

Received Date: 10 August 2020
Revised Date: 15 September 2020
Accepted Date: 16 September 2020
Available Online: 19 September 2020

Figures(6)

A new nonporous Zn-based metal-organic framework (NPMOF) synthesized from a high nitrogen-containing rigid ligand was converted into porous carbon materials by direct carbonization without adding additional carbon sources. A series of NPMOF-derived porous carbons with very high N/O contents (24.1% for NPMOF-700, 20.2% for NPMOF-800, 15.1% for NPMOF-900) were prepared by adjusting the pyrolysis temperatures. The NPMOF-800 fabricated electrode exhibits a high capacitance of 220 F/g and extremely large surface area normalized capacitance of 57.7 μF/cm² compared to other reported MOF-derived porous carbon electrodes, which could be attributed to the abundant ultramicroporosity and high N/O co-doping. More importantly, symmetric supercapacitor assembled with the MOF-derived carbon manifests prominent stability, i.e., 99.1% capacitance retention after 10,000 cycles at 1.0 A/g. This simple preparation of MOF-derived porous carbon materials not only finds an application direction for a variety of porous or even nonporous MOFs, but also opens a way for the production of porous carbon materials for superior energy storage.
- N/O co-doped,
- Ultramicroporous,
- Metal-organic frameworks,
- Porous carbons,
- Supercapacitors
1. [1]
  X. Chen, R. Paul, L. Dai, Natl. Sci. Rev. 4(2017) 453-489. doi: 10.1093/nsr/nwx009
2. [2]
  E. Pomerantseva, F. Bonaccorso, X. Feng, Y. Cui, Y. Gogotsi, Science 366(2019) eaan 8285. doi: 10.1126/science.aan8285
3. [3]
  G. Wang, L. Zhang, J. Zhang, Chem. Soc. Rev. 41(2012) 797-828. doi: 10.1039/C1CS15060J
4. [4]
  W. Tian, H. Zhang, X. Duan, et al., Adv. Funct. Mater. 30(2020) 1909265. doi: 10.1002/adfm.201909265
5. [5]
  H. Peng, B. Yao, X. Wei, et al., Adv. Energy Mater. 9(2019) 1803665. doi: 10.1002/aenm.201803665
6. [6]
  R.R. Salunkhe, Y. Kamachi, N.L. Torad, et al., J. Mater. Chem. A 2(2014) 19848-19854. doi: 10.1039/C4TA04277H
7. [7]
  H. Cheng, J. Meng, G. Wu, S. Chen, Angew. Chem. Int. Ed. 58(2019) 17465-17473. doi: 10.1002/anie.201911023
8. [8]
  L. Miao, Z. Song, D. Zhu, et al., Mater. Adv. 1(2020) 945-966. doi: 10.1039/D0MA00384K
9. [9]
  J. Chmiola, G. Yushin, Y. Gogotsi, et al., Science 313(2006) 1760-1763. doi: 10.1126/science.1132195
10. [10]
  N. Jäckel, P. Simon, Y. Gogotsi, V. Presser, ACS Energy Lett. 1(2016) 1262-1265. doi: 10.1021/acsenergylett.6b00516
11. [11]
  X. Qian, L. Miao, J. Jiang, et al., Chem. Eng. J. 388(2020) 124208. doi: 10.1016/j.cej.2020.124208
12. [12]
  H. Jin, X. Feng, J. Li, et al., Angew. Chem. Int. Ed. 58(2019) 2397-2401. doi: 10.1002/anie.201813686
13. [13]
  H.F. Fei, W. Li, A. Bhardwaj, et al., J. Am. Chem. Soc. 141(2019) 17006-17014. doi: 10.1021/jacs.9b09572
14. [14]
  J. Liu, T. Yang, D.W. Wang, et al., Nat. Commun. 4(2013) 2798. doi: 10.1038/ncomms3798
15. [15]
  Z. Song, H. Duan, L. Miao, et al., Carbon 168(2020) 499-507. doi: 10.1016/j.carbon.2020.07.004
16. [16]
  Z. Yang, Y. Gu, B. Yuan, et al., J. Hazard. Mater. 403(2021) 123702. doi: 10.1016/j.jhazmat.2020.123702
17. [17]
  G. Yuan, S. Yu, J. Jie, et al., Chin. Chem. Lett. 31(2020) 1941. doi: 10.1016/j.cclet.2019.12.034
18. [18]
  H. Furukawa, K.E. Cordova, M. O'Keeffe, O.M. Yaghi, Science 341(2013) 1230444. doi: 10.1126/science.1230444
19. [19]
  Y. Tian, G. Liang, T. Fan, et al., Chem. Mater. 31(2019) 8494-8503. doi: 10.1021/acs.chemmater.9b02924
20. [20]
  S. Kitagawa, R. Kitaura, S. Noro, Angew. Chem. Int. Ed. 43(2004) 2334-2375. doi: 10.1002/anie.200300610
21. [21]
  L. Li, R. Matsuda, I. Tanaka, et al., J. Am. Chem. Soc. 136(2014) 7543-7546. doi: 10.1021/ja5019095
22. [22]
  X. Li, X. Yang, H. Xue, H. Pang, Q. Xu, EnergyChem 2(2020) 100027.
23. [23]
  M. Liu, F. Zhao, D. Zhu, et al., Mater. Chem. Phys. 211(2018) 234-241. doi: 10.1016/j.matchemphys.2018.02.030
24. [24]
  X. Li, X. Yang, H. Xue, H. Pang, Q. Xu, EnergyChem 2(2020) 100025. doi: 10.1016/j.enchem.2019.100025
25. [25]
  B. Liu, H. Shioyama, T. Akita, Q. Xu, J. Am. Chem. Soc. 130(2008) 5390-5391. doi: 10.1021/ja7106146
26. [26]
  X. Chen, D.D. Ma, B. Chen, et al., Appl. Catal. B 267(2020) 118720. doi: 10.1016/j.apcatb.2020.118720
27. [27]
  Y. Li, Y. Shan, H. Pang, Chin. Chem. Lett. 31(2020) 2280-2286. doi: 10.1016/j.cclet.2020.03.027
28. [28]
  X. Shi, S. Zhang, X. Chen, T. Tang, E. Mijowska, Carbon 157(2020) 55-63. doi: 10.1016/j.carbon.2019.10.004
29. [29]
  Q.L. Zhu, P. Pachfule, P. Strubel, et al., Energy Stor. Mater. 13(2018) 72-79. doi: 10.1016/j.ensm.2017.12.027
30. [30]
  L.D. Chen, Y.Q. Zheng, H.L. Zhu, J. Mater. Sci. 53(2017) 1346-1355.
31. [31]
  P. Pachfule, D. Shinde, M. Majumder, Q. Xu, Nat. Chem. 8(2016) 718-724. doi: 10.1038/nchem.2515
32. [32]
  S. Zheng, Q. Li, H. Xue, H. Pang, Q. Xu, Natl. Sci. Rev. 7(2020) 305-314. doi: 10.1093/nsr/nwz137
33. [33]
  Y. Liu, Y. Wang, C. Shi, et al., Carbon 165(2020) 129-138. doi: 10.1016/j.carbon.2020.04.084
34. [34]
  L. Wan, E. Shamsaei, C.D. Easton, et al., Carbon 121(2017) 330-336. doi: 10.1016/j.carbon.2017.06.017
35. [35]
  Z. Li, H. Mi, L. Liu, et al., Carbon 136(2018) 176-186. doi: 10.1016/j.carbon.2018.04.075
36. [36]
  W. Chaikittisilp, M. Hu, H. Wang, et al., Chem. Commun. 48(2012) 7159-7261.
37. [37]
  J. Yan, H. Duan, D. Zhu, et al., Electrochim. Acta 358(2020) 136899. doi: 10.1016/j.electacta.2020.136899
38. [38]
  W. Wang, Y. Ling, L.J. Yang, et al., Res. Chem. Intermed. 42(2015) 3157-3168.
39. [39]
  L.F. Chen, Y. Lu, L. Yu, X. Lou, Energy Environ. Sci. 10(2017) 1777-1783. doi: 10.1039/C7EE00488E
40. [40]
  K. Jayaramulu, D.P. Dubal, B. Nagar, et al., Adv. Mater. 30(2018) 1705789. doi: 10.1002/adma.201705789
41. [41]
  X. Li, C. Hao, B. Tang, et al., Nanoscale 9(2017) 2178-2187. doi: 10.1039/C6NR08987A
42. [42]
  G.W. Cong, W.Q. Peng, H.Y. Wei, et al., Appl. Phys. Lett. 88(2006) 062110. doi: 10.1063/1.2171804
43. [43]
  Y. Zhang, L. Liu, L. Zhang, et al., J. Mater. Sci. 54(2019) 6451-6460. doi: 10.1007/s10853-018-03290-x
44. [44]
  R. Zhao, Z. Liang, S. Gao, et al., Angew. Chem. Int. Ed. 58(2019) 1975-1979. doi: 10.1002/anie.201811126
45. [45]
  J.X. Sun, Y.P. Yuan, L.G. Qiu, et al., Dalton Trans. 41(2012) 6756-6763. doi: 10.1039/c2dt12474b
46. [46]
  Z. Song, L. Miao, L. Li, et al., J. Mater. Chem. A 8(2020) 3717-3725. doi: 10.1039/C9TA13520K
47. [47]
  Z. Zhou, L. Miao, H. Duan, et al., Chin. Chem. Lett. 31(2020) 1226-1230. doi: 10.1016/j.cclet.2020.02.026
48. [48]
  M. Li, J. Xue, J. Phys. Chem. C 118(2014) 2507-2517. doi: 10.1021/jp410198r
49. [49]
  F. Xu, N. Chen, Z. Fan, G. Du, Appl. Surf. Sci. 528(2020) 146920. doi: 10.1016/j.apsusc.2020.146920
50. [50]
  K. Fahsi, S.G. Dutremez, A. Vioux, L. Viau, J. Mater. Chem. A 1(2013) 4451-5561. doi: 10.1039/c3ta01154b
51. [51]
  N.L. Torad, R.R. Salunkhe, Y. Li, et al., Chem. Eur. J. 20(2014) 7895-7900. doi: 10.1002/chem.201400089
52. [52]
  J. Tang, R.R. Salunkhe, J. Liu, et al., J. Am. Chem. Soc. 137(2015) 1572-1580. doi: 10.1021/ja511539a
53. [53]
  P. Zhang, F. Sun, Z. Shen, D. Cao, J. Mater. Chem. A 2(2014) 12873-12880. doi: 10.1039/C4TA00475B
54. [54]
  M. Rose, Y. Korenblit, E. Kockrick, et al., Small 7(2011) 1108-1117. doi: 10.1002/smll.201001898
55. [55]
  J. Zhou, M. Wang, X. Li, J. Porous Mater. 26(2018) 99-108.
56. [56]
  H. Chen, J. Chen, D. Chen, et al., J. Mater. Sci. 54(2018) 5625-5640.
57. [57]
  S. Zhong, C. Zhan, D. Cao, Carbon 85(2015) 51-59. doi: 10.1016/j.carbon.2014.12.064
58. [58]
  J. Hu, H. Wang, Q. Gao, H. Guo, Carbon 48(2010) 3599-3606. doi: 10.1016/j.carbon.2010.06.008
59. [59]
  L. Yao, Q. Wu, P. Zhang, et al., Adv. Mater. 30(2018) 1706054. doi: 10.1002/adma.201706054
60. [60]
  A. Zhang, S. Cao, Y. Zhao, C. Zhang, A. Chen, New J. Chem. 42(2018) 6903-6909. doi: 10.1039/C8NJ00576A
61. [61]
  J. Hao, J. Wang, S. Qin, et al., J. Mater. Chem. A 6(2018) 8053-8058. doi: 10.1039/C8TA00683K
62. [62]
  Z. Hu, S. Li, P. Cheng, et al., J. Mater. Sci. 51(2016) 2627-2633. doi: 10.1007/s10853-015-9576-x
1. [1]
  Ruiying Liu , Li Zhao , Baishan Liu , Jiayuan Yu , Yujie Wang , Wanqiang Yu , Di Xin , Chaoqiong Fang , Xuchuan Jiang , Riming Hu , Hong Liu , Weijia Zhou . Modulating pollutant adsorption and peroxymonosulfate activation sites on Co3O4@N,O doped-carbon shell for boosting catalytic degradation activity. Chinese Journal of Structural Chemistry, 2024, 43(8): 100332-100332. doi: 10.1016/j.cjsc.2023.100332
2. [2]
  Jiayu Huang , Kuan Chang , Qi Liu , Yameng Xie , Zhijia Song , Zhiping Zheng , Qin Kuang . Fe-N-C nanostick derived from 1D Fe-ZIFs for Electrocatalytic oxygen reduction. Chinese Journal of Structural Chemistry, 2023, 42(10): 100097-100097. doi: 10.1016/j.cjsc.2023.100097
3. [3]
  Muhammad Riaz , Rakesh Kumar Gupta , Di Sun , Mohammad Azam , Ping Cui . Selective adsorption of organic dyes and iodine by a two-dimensional cobalt(II) metal-organic framework. Chinese Journal of Structural Chemistry, 2024, 43(12): 100427-100427. doi: 10.1016/j.cjsc.2024.100427
4. [4]
  Tengjia Ni , Xianbiao Hou , Huanlei Wang , Lei Chu , Shuixing Dai , Minghua Huang . Controllable defect engineering based on cobalt metal-organic framework for boosting oxygen evolution reaction. Chinese Journal of Structural Chemistry, 2024, 43(1): 100210-100210. doi: 10.1016/j.cjsc.2024.100210
5. [5]
  Uttam Pandurang Patil . Porous carbon catalysis in sustainable synthesis of functional heterocycles: An overview. Chinese Chemical Letters, 2024, 35(8): 109472-. doi: 10.1016/j.cclet.2023.109472
6. [6]
  Ze Liu , Xiaochen Zhang , Jinlong Luo , Yingjian Yu . Application of metal-organic frameworks to the anode interface in metal batteries. Chinese Chemical Letters, 2024, 35(11): 109500-. doi: 10.1016/j.cclet.2024.109500
7. [7]
  Longlong Geng , Huiling Liu , Wenfeng Zhou , Yong-Zheng Zhang , Hongliang Huang , Da-Shuai Zhang , Hui Hu , Chao Lv , Xiuling Zhang , Suijun Liu . Construction of metal-organic frameworks with unsaturated Cu sites for efficient and fast reduction of nitroaromatics: A combined experimental and theoretical study. Chinese Chemical Letters, 2024, 35(8): 109120-. doi: 10.1016/j.cclet.2023.109120
8. [8]
  Rui Wang , He Qi , Haijiao Zheng , Qiong Jia . Light/pH dual-responsive magnetic metal-organic frameworks composites for phosphorylated peptide enrichment. Chinese Chemical Letters, 2024, 35(7): 109215-. doi: 10.1016/j.cclet.2023.109215
9. [9]
  Fereshte Hassanzadeh-Afruzi , Mina Azizi , Iman Zare , Ehsan Nazarzadeh Zare , Anwarul Hasan , Siavash Iravani , Pooyan Makvandi , Yi Xu . Advanced metal-organic frameworks-polymer platforms for accelerated dermal wound healing. Chinese Chemical Letters, 2024, 35(11): 109564-. doi: 10.1016/j.cclet.2024.109564
10. [10]
  Xiao-Hong Yi , Chong-Chen Wang . Metal-organic frameworks on 3D interconnected macroporous sponge foams for large-scale water decontamination: A mini review. Chinese Chemical Letters, 2024, 35(5): 109094-. doi: 10.1016/j.cclet.2023.109094
11. [11]
  Wenbiao Zhang , Bolong Yang , Zhonghua Xiang . Atomically dispersed Cu-based metal-organic framework directly for alkaline polymer electrolyte fuel cells. Chinese Chemical Letters, 2025, 36(2): 109630-. doi: 10.1016/j.cclet.2024.109630
12. [12]
  Xudong Zhao , Yuxuan Wang , Xinxin Gao , Xinli Gao , Meihua Wang , Hongliang Huang , Baosheng Liu . Anchoring thiol-rich traps in 1D channel wall of metal-organic framework for efficient removal of mercury ions. Chinese Chemical Letters, 2025, 36(2): 109901-. doi: 10.1016/j.cclet.2024.109901
13. [13]
  Jingxuan Liu , Shiqi Zhao , Xiang Wu . Flexible electrochemical capacitor based NiMoSSe electrode material with superior cycling and structural stability. Chinese Chemical Letters, 2024, 35(7): 109059-. doi: 10.1016/j.cclet.2023.109059
14. [14]
  Jian Peng , Yue Jiang , Shuangyu Wu , Yanran Cheng , Jingyu Liang , Yixin Wang , Zhuo Li , Sijie Lin . A nonradical oxidation process initiated by Ti-peroxo complex showed high specificity toward the degradation of tetracycline antibiotics. Chinese Chemical Letters, 2024, 35(5): 108903-. doi: 10.1016/j.cclet.2023.108903
15. [15]
  Yuan Zhang , Shenghao Gong , A.R. Mahammed Shaheer , Rong Cao , Tianfu Liu . Plasmon-enhanced photocatalytic oxidative coupling of amines in the air using a delicate Ag nanowire@NH₂-UiO-66 core-shell nanostructures. Chinese Chemical Letters, 2024, 35(4): 108587-. doi: 10.1016/j.cclet.2023.108587
16. [16]
  Zhi Wang , Lingpeng Yan , Yelin Hao , Jingxia Zheng , Yongzhen Yang , Xuguang Liu . Highly efficient and photothermally stable CDs@ZIF-8 for laser illumination. Chinese Chemical Letters, 2024, 35(10): 109430-. doi: 10.1016/j.cclet.2023.109430
17. [17]
  Hao Wang , Meng-Qi Pan , Ya-Fei Wang , Chao Chen , Jian Xu , Yuan-Yuan Gao , Chuan-Song Qi , Wei Li , Xian-He Bu . Post-synthetic modifications of MOFs by different bolt ligands for controllable release of cargoes. Chinese Chemical Letters, 2024, 35(10): 109581-. doi: 10.1016/j.cclet.2024.109581
18. [18]
  Yan-Kai Zhang , Yong-Zheng Zhang , Chun-Xiao Jia , Fang Wang , Xiuling Zhang , Yuhang Wu , Zhongmin Liu , Hui Hu , Da-Shuai Zhang , Longlong Geng , Jing Xu , Hongliang Huang . A stable Zn-MOF with anthracene-based linker for Cr(VI) photocatalytic reduction under sunlight irradiation. Chinese Chemical Letters, 2024, 35(12): 109756-. doi: 10.1016/j.cclet.2024.109756
19. [19]
  Ziyi Zhu , Yang Cao , Jun Zhang . CO2-switched porous metal-organic framework magnets. Chinese Journal of Structural Chemistry, 2024, 43(2): 100241-100241. doi: 10.1016/j.cjsc.2024.100241
20. [20]
  Ting Shi , Ziyang Song , Yaokang Lv , Dazhang Zhu , Ling Miao , Lihua Gan , Mingxian Liu . Hierarchical porous carbon guided by constructing organic-inorganic interpenetrating polymer networks to facilitate performance of zinc hybrid supercapacitors. Chinese Chemical Letters, 2025, 36(1): 109559-. doi: 10.1016/j.cclet.2024.109559

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(610)
HTML views(72)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142