Citation: Yu-Pei Xia, Chen-Xue Wang, Mei-Hui Yu, Xian-He Bu. A unique 3D microporous MOF constructed by cross-linking 1D coordination polymer chains for effectively selective separation of CO₂/CH₄ and C₂H₂/CH₄[J]. Chinese Chemical Letters, ;2021, 32(3): 1153-1156. doi: 10.1016/j.cclet.2020.09.014 shu

A unique 3D microporous MOF constructed by cross-linking 1D coordination polymer chains for effectively selective separation of CO₂/CH₄ and C₂H₂/CH₄

Yu-Pei Xia ^a ,
Chen-Xue Wang ^a ,
Mei-Hui Yu ^{a, *,} ,
Xian-He Bu ^{a, b, *,}

a.
School of Materials Science and Engineering, National Institute for Advanced Materials, Nankai University, Tianjin 300350, China
b.
State Key Laboratory of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071, China

mh@nankai.edu.cn

buxh@nankai.edu.cn

Received Date: 7 August 2020
Revised Date: 2 September 2020
Accepted Date: 9 September 2020
Available Online: 10 September 2020

Figures(4)

Selective separation of CO₂/CH₄ and C₂H₂/CH₄ are promising for their high-purity industrial demand and scientific research on account of the similar molecular radius and physical properties. In this work, a unique 3D microporous MOF material [Cu(SiF₆)(sdi)₂] solvents (1, sdi = 1, 1'-sulfonyldiimidazole) was successfully constructed by cross-linking 1D coordination polymer chains. The dense functional active sites on the inner walls of the channel of 1a can provide strong binding affinities to CO₂, C₂H₂, and thus effectively improve the gas separation performance of CO₂/CH₄ and C₂H₂/CH₄.
- Metal-organic framework,
- Cross-linking,
- Selective separation,
- Dense functional active site
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沈阳化工大学材料科学与工程学院沈阳 110142

A unique 3D microporous MOF constructed by cross-linking 1D coordination polymer chains for effectively selective separation of CO2/CH4 and C2H2/CH4

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通讯作者: 陈斌, bchen63@163.com

A unique 3D microporous MOF constructed by cross-linking 1D coordination polymer chains for effectively selective separation of CO₂/CH₄ and C₂H₂/CH₄